C01C3/02

PROCESS FOR THE CATALYTIC PREPARATION OF HYDROGEN CYANIDE FROM METHANE AND AMMONIA
20190091664 · 2019-03-28 ·

The invention relates to a catalyst material comprising a support, a first metal and a second metal on said support. The first and second metals are in the form of a chemical compound. The first metal is Fe, Co or Ni, and the second metal is selected from the group consisting of Sn, Zn and In. The invention also relates to a process for the preparation of hydrogen cyanide (HCN) from methane (CH.sub.4) and ammonia (NH.sub.3), wherein the methane and ammonia are contacted with a catalyst according to the invention.

Method for preparing alpha-hydroxycarboxylic acid esters in which ammonia is recycled

The present invention relates to a process for preparing alpha-hydroxycarboxylic esters proceeding from hydrogen cyanide, wherein the ammonia formed in the step of alcoholysis of the corresponding alpha-hydroxycarboxamide is recycled into a hydrogen cyanide preparation process after a purification step.

Activation energy reducers for catalytic oxidation of gaseous mixtures

The present invention provides materials for improving the ignition of gaseous reactants in metal catalyzed oxidation reactions comprising a metal catalyst gauze, preferably, a platinum/rhodium catalyst gauze, having in contact therewith, from 0.25 to 1.5 wt. %, based on the weight of the metal catalyst gauze, of one or more pieces of previously used metal catalyst gauze. Further, methods of making the metal catalyst materials comprise shaping the pieces of previously used metal catalyst gauze and placing them equidistant from each other in contact with or on the surface of the metal catalyst gauze. And methods of using the materials comprise feeding into the reactor a gas mixture of oxygen or air and one or more reactant gases, and igniting the gas mixture at the surface of one or more or all of the pieces of previously used metal catalyst.

INSTALLATION AND PROCESS FOR THE PREPARATION OF HYDROGEN CYANIDE
20180215626 · 2018-08-02 ·

Present invention relates to a process and an installation (100) for the preparation of hydrogen cyanide by the Andrussow process, and more precisely for improving the conditions of mixing the reactant gases before feeding the Andrussow type reactor (60), in order to improve safety, to avoid any risk of explosion and to produce HCN in safe and efficient manner. The installation is configured in such a manner that oxygen is pre-mixed with air with a ratio comprised between 20.95% and 32.5% by volume, preferably between 25% and 30.5% by volume; methane containing gas and ammonia are simultaneously added in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80 C. and 120 C., preferably between 95 C. and 115 C. for feeding the Andrussow type reactor (60).

HIGH PURITY HCN FROM ACRYLONITRILE CO-PRODUCTION

Disclosed is a process for co-manufacture of ACRN and HCN with improved HCN selectivity and reduced solids formation in a shared product recovery section.

METHOD FOR REMOVING NITRILES FROM HYDROGEN CYANIDE

Process for making purified hydrogen cyanide. The process includes feeding a reaction product including HCN, water, and organonitriles to a separation vessel; taking a liquid slip stream of HCN, water and organonitriles from the separation vessel; and feeding the liquid slipstream into a sidestream stripper to purge nitriles from the HCN reaction product.

PROCESS FOR THE PREPARATION OF SODIUM CYANIDE
20180155204 · 2018-06-07 ·

The invention relates to a process for the preparation of alkali metal cyanides as a solid substance, comprising the steps of: i) an absorption step in the form of an absorption of hydrogen cyanide from a hydrogen cyanide-containing synthesis gas in an aqueous alkali metal hydroxide solution; ii) a crystallization step in the form of introducing said alkali metal cyanide solution into an evaporative crystallizer; iii) a separation step; iv) a recycle step; v) a drying step.

Installation and process for the preparation of hydrogen cyanide

Present invention relates to a process and an installation (100) for the preparation of hydrogen cyanide by the Andrussow process, and more precisely for improving the conditions of mixing the reactant gases before feeding the Andrussow type reactor (60), in order to improve safety, to avoid any risk of explosion and to produce HCN in safe and efficient manner. The installation is configured in such a manner that oxygen is pre-mixed with air with a ratio comprised between 20.95% and 32.5% by volume, preferably between 25% and 30.5% by volume; methane containing gas and ammonia are simultaneously added in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80 C. and 120 C., preferably between 95 C. and 115 C. for feeding the Andrussow type reactor (60).

A STRUCTURED BODY FOR HEATING GAS

A structured body for heating system for carrying out heating of a pressurized feed gas is provided, where the heat is provided by resistance heating by means of electrical power.

Endothermic reactions heated by resistance heating

A reactor system for carrying out an endothermic reaction of a feed gas, including: a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 200 C. by passing an electrical current through the electrically conductive material. Also, a process for performing an endothermic reaction of a feed gas.