A method including reacting carbon dioxide from exhaust gas produced at a wellsite to produce a solid metal carbonate, and microwaving the solid metal carbonate to produce recovered carbon dioxide and solid metal alkaline. A system for carrying out the method is also provided.

In some embodiments the application pertains to processes comprising reacting a component comprising an alkaline earth weak acid with a component comprising an acid to form a component comprising an alkaline earth acid anion and a component comprising a weak acid derivative. At least a portion of the component comprising the alkaline earth acid anion is reacted with a component comprising an alkali sulfate to form a component comprising alkaline earth sulfate and a component comprising an alkali acid anion. At least a portion of the component comprising alkaline earth sulfate is decomposed to form a component comprising alkaline earth oxide, or alkaline earth hydroxide, or alkaline earth carbonate, or alkaline earth sulfide, or a derivative thereof, or any combination thereof, and a component comprising sulfur dioxide, or oxygen, or sulfur trioxide, or a derivative thereof, or any combination thereof.

In some embodiments the application pertains to processes comprising reacting a component comprising an alkaline earth weak acid with a component comprising an acid to form a component comprising an alkaline earth acid anion and a component comprising a weak acid derivative. At least a portion of the component comprising the alkaline earth acid anion is reacted with a component comprising an alkali sulfate to form a component comprising alkaline earth sulfate and a component comprising an alkali acid anion. At least a portion of the component comprising alkaline earth sulfate is decomposed to form a component comprising alkaline earth oxide, or alkaline earth hydroxide, or alkaline earth carbonate, or alkaline earth sulfide, or a derivative thereof, or any combination thereof, and a component comprising sulfur dioxide, or oxygen, or sulfur trioxide, or a derivative thereof, or any combination thereof.

In some embodiments the application pertains to processes comprising reacting a component comprising an alkaline earth weak acid with a component comprising an acid to form a component comprising an alkaline earth acid anion and a component comprising a weak acid derivative. At least a portion of the component comprising the alkaline earth acid anion is reacted with a component comprising an alkali sulfate to form a component comprising alkaline earth sulfate and a component comprising an alkali acid anion. At least a portion of the component comprising alkaline earth sulfate is decomposed to form a component comprising alkaline earth oxide, or alkaline earth hydroxide, or alkaline earth carbonate, or alkaline earth sulfide, or a derivative thereof, or any combination thereof, and a component comprising sulfur dioxide, or oxygen, or sulfur trioxide, or a derivative thereof, or any combination thereof.

In some embodiments the application pertains to processes comprising reacting a component comprising an alkaline earth weak acid with a component comprising an acid to form a component comprising an alkaline earth acid anion and a component comprising a weak acid derivative. At least a portion of the component comprising the alkaline earth acid anion is reacted with a component comprising an alkali sulfate to form a component comprising alkaline earth sulfate and a component comprising an alkali acid anion. At least a portion of the component comprising alkaline earth sulfate is decomposed to form a component comprising alkaline earth oxide, or alkaline earth hydroxide, or alkaline earth carbonate, or alkaline earth sulfide, or a derivative thereof, or any combination thereof, and a component comprising sulfur dioxide, or oxygen, or sulfur trioxide, or a derivative thereof, or any combination thereof.

Processes are provided in which successive steps of hydrometallurgical value extraction may be carried out using the products of carbon capture and an electrolytic reagent-generating process. The electrolytic process provides an acid leachant and an alkali hydroxide, with the alkali hydroxide then available for use either directly as a precipitant in the hydrometallurgical steps, or available for conversion by carbon capture to an alkali metal carbonate that can in turn be used as the precipitant in the selective hydrometallurgical steps.

A system for generating bicarbonate solution includes a reaction vessel having an inflow of water (H.sub.2O) and sodium hydroxide (NaOH). The water and the sodium hydroxide combine to form a solution in the reaction vessel. The system also includes a gas sparger in fluid communication with the reaction vessel. The gas sparger provides an inflow of gas comprising carbon dioxide (CO.sub.2) into the solution in the reaction vessel. The system also includes at least one flow regulating component upstream from the reaction vessel and in-line with at least one of the following: the inflow of the water, the inflow of the sodium hydroxide, the inflow of the gas comprising carbon dioxide, or any combination thereof. The system also includes a controller in communication with the at least one flow regulating component. The sodium hydroxide and the carbon dioxide react to form at least bicarbonate (HCO.sub.3.sup.) in the solution.

A system for generating bicarbonate solution includes a reaction vessel having an inflow of water (H.sub.2O) and sodium hydroxide (NaOH). The water and the sodium hydroxide combine to form a solution in the reaction vessel. The system also includes a gas sparger in fluid communication with the reaction vessel. The gas sparger provides an inflow of gas comprising carbon dioxide (CO.sub.2) into the solution in the reaction vessel. The system also includes at least one flow regulating component upstream from the reaction vessel and in-line with at least one of the following: the inflow of the water, the inflow of the sodium hydroxide, the inflow of the gas comprising carbon dioxide, or any combination thereof. The system also includes a controller in communication with the at least one flow regulating component. The sodium hydroxide and the carbon dioxide react to form at least bicarbonate (HCO.sub.3.sup.) in the solution.

Processes are provided in which successive steps of hydrometallurgical value extraction may be carried out using the products of carbon capture and an electrolytic reagent-generating process. The electrolytic process provides an acid leachant and an alkali hydroxide, with the alkali hydroxide then available for use either directly as a precipitant in the hydrometallurgical steps, or available for conversion by carbon capture to an alkali metal carbonate that can in turn be used as the precipitant in the selective hydrometallurgical steps.

Proposed is a carbon dioxide capture and carbon resource utilization system, for a fuel cell, using boil-off gas (BOG) generated from liquefied natural gas. The system includes a liquefied natural gas storage configured to store liquefied natural gas (LNG), a hydrocarbon reformer configured to react boil-off gas generated from liquefied natural gas storage with water input from outside, thereby generating a gas mixture containing hydrogen and carbon dioxide, a fuel cell configured to generate electric power by receiving hydrogen, a reactor configured to capture carbon dioxide by reacting carbon dioxide with a basic alkali mixture solution and to collect a reaction product containing the captured carbon dioxide and to separate a carbon dioxide reaction product and a waste solution from the reaction product, and a hydrogen generator configured to generate hydrogen and to supply the generated hydrogen to the fuel cell.