Patent classifications
C01D15/02
HEAT TREATMENT METHOD OF WASTE CATHODE MATERIALS AND LITHIUM RECOVERY METHOD USING SAME
A method of heat-treating a waste cathode material to recover lithium carbonate from the waste cathode material, and a lithium carbonate recovery method using the waste cathode material heat treatment method are provided. The method of heat-treating the waste cathode material includes heating an interior of a heat treatment furnace by burning a hydrocarbon fluid in the heat treatment furnace and producing lithium carbonate (Li.sub.2CO.sub.3) and residual metal oxide by reacting a waste cathode material in the heat treatment furnace with CO.sub.2 generated during burning of the hydrocarbon fluid.
Heat treating apparatus for recovering lithume carbonate and an apparatus for recovering lithume carbonate using the same
A heat treatment apparatus used in a process of recovering lithium carbonate from a waste cathode material and a lithium carbonate recovery apparatus using the same are provided. The heat treatment apparatus includes a heat treatment furnace having an inlet through which an object to be treated is input and an outlet through which the heat-treated object is discharged, a support section rotatably supporting the heat treatment furnace, a burner provided in the heat treatment furnace to supply combustion gas to the heat treatment furnace, and an exhaust gas re-supply device re-supplying a portion of the combustion gas discharged from the heat treatment furnace to the heat treatment furnace, wherein the heat treatment furnace is divided into a first region in which the inlet is disposed, a second region connected to the first region, and a third region connected to the second region and in which the burner is disposed.
METHODS FOR TREATING LITHIUM-CONTAINING MATERIALS
The present disclosure relates to a method for treating an electromembrane process aqueous composition comprising sodium and/or potassium sulfate, said process comprising removing water from said electromembrane process aqueous composition under conditions suitable for substantially selectively precipitating sodium and/or potassium sulfate monohydrate.
METHODS FOR TREATING LITHIUM-CONTAINING MATERIALS
The present disclosure relates to a method for treating an electromembrane process aqueous composition comprising sodium and/or potassium sulfate, said process comprising removing water from said electromembrane process aqueous composition under conditions suitable for substantially selectively precipitating sodium and/or potassium sulfate monohydrate.
SELECTIVE EXTRACTION OF LITHIUM FROM LITHIUM SULFATE AQUEOUS SOLUTION
A method of selectively extracting lithium from a lithium sulfate aqueous solution, the method comprising: (i) mixing an aluminum-containing sorbent material into the lithium sulfate aqueous solution to form a precursor mixture, wherein the aluminum-containing sorbent material is an aluminum hydroxide, aluminum oxide, or combination thereof; and (ii) heating the precursor mixture to a temperature of 50-200° C. to result in selective formation of a solid lithium-aluminum complex and mother liquor; and wherein the method may further comprise: (iii) recovering isolated lithium salt from the solid lithium-aluminum complex by heating the solid lithium-aluminum complex in water or aqueous solution at a temperature of 50-100° C. to result in delithiation of the solid lithium-aluminum complex with transfer of the lithium salt from the solid lithium-aluminum complex to the water or aqueous solution, along with production of aluminum hydroxide solid.
SELECTIVE EXTRACTION OF LITHIUM FROM LITHIUM SULFATE AQUEOUS SOLUTION
A method of selectively extracting lithium from a lithium sulfate aqueous solution, the method comprising: (i) mixing an aluminum-containing sorbent material into the lithium sulfate aqueous solution to form a precursor mixture, wherein the aluminum-containing sorbent material is an aluminum hydroxide, aluminum oxide, or combination thereof; and (ii) heating the precursor mixture to a temperature of 50-200° C. to result in selective formation of a solid lithium-aluminum complex and mother liquor; and wherein the method may further comprise: (iii) recovering isolated lithium salt from the solid lithium-aluminum complex by heating the solid lithium-aluminum complex in water or aqueous solution at a temperature of 50-100° C. to result in delithiation of the solid lithium-aluminum complex with transfer of the lithium salt from the solid lithium-aluminum complex to the water or aqueous solution, along with production of aluminum hydroxide solid.
Explosive formulations of mixture of carbon dioxide and a reducing agent and methods of using same
The disclosure relates to embodiments of an explosive formulation comprising a detonable mixture of an oxidizing agent such as carbon dioxide, and a material that decomposes the oxidizing agent exothermically (a reducing agent), and additives that increase the mixture's shock sensitivity. The formulations may be used in a method to produce diamonds or nano oxides or in other applications that use traditional explosives such as, but not limited to: ammonium nitrate and fuel oil combinations (ANFO), watergel explosives, emulsion explosives and RDX.
Explosive formulations of mixture of carbon dioxide and a reducing agent and methods of using same
The disclosure relates to embodiments of an explosive formulation comprising a detonable mixture of an oxidizing agent such as carbon dioxide, and a material that decomposes the oxidizing agent exothermically (a reducing agent), and additives that increase the mixture's shock sensitivity. The formulations may be used in a method to produce diamonds or nano oxides or in other applications that use traditional explosives such as, but not limited to: ammonium nitrate and fuel oil combinations (ANFO), watergel explosives, emulsion explosives and RDX.
METHOD FOR PRODUCING LITHIUM HYDROXIDE
A method for producing lithium hydroxide that allows reducing a load of removing divalent or more ions with an ion-exchange resin is provided. The method for producing lithium hydroxide includes steps (1) to (3) below. (1) a neutralization step: a step of adding an alkali to a first lithium chloride containing liquid to obtain a post-neutralization liquid, (2) an ion-exchange step: a step of bringing the post-neutralization liquid into contact with an ion-exchange resin to obtain a second lithium chloride containing liquid, and (3) a conversion step: a step of electrodialyzing the second lithium chloride containing liquid to obtain a lithium hydroxide containing liquid. Since this producing method allows roughly removing divalent or more ions in the neutralization step, a load of metal removal with the ion-exchange resin is reducible.
METHOD FOR PRODUCING LITHIUM HYDROXIDE
A method for producing lithium hydroxide that allows reducing a load of removing divalent or more ions with an ion-exchange resin is provided. The method for producing lithium hydroxide includes steps (1) to (3) below. (1) a neutralization step: a step of adding an alkali to a first lithium chloride containing liquid to obtain a post-neutralization liquid, (2) an ion-exchange step: a step of bringing the post-neutralization liquid into contact with an ion-exchange resin to obtain a second lithium chloride containing liquid, and (3) a conversion step: a step of electrodialyzing the second lithium chloride containing liquid to obtain a lithium hydroxide containing liquid. Since this producing method allows roughly removing divalent or more ions in the neutralization step, a load of metal removal with the ion-exchange resin is reducible.