This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

This application pertains to methods of recovering metals from metal sulfides that involve contacting the metal sulfide with an acidic sulfate solution containing ferric sulfate and a reagent that has a thiocarbonyl functional group, wherein the concentration of reagent in the acidic sulfate solution is sufficient to increase the rate of metal ion extraction relative to an acidic sulfate solution that does not contain the reagent, to produce a pregnant solution containing the metal ions.

Copper sulfate which includes a Fe with a concentration of 0.08 ppm by mass or less.

The present invention provides a method for treating a copper-containing waste etching solution, which includes: preparing basic copper chloride nanometer seed crystals and synthesizing basic copper chloride mono-crystals; making an acidic waste etching solution subjected to agglomeration reaction with an ammonium-containing solution and slurry containing the basic copper chloride mono-crystals to obtain basic copper chloride crystal particles and copper-removed waste solution; making an alkaline waste etching solution react with sulfuric acid to obtain a copper sulfate mixed solution; and then evaporating, concentrating, cooling and crystallizing the copper sulfate mixed solution obtained by the reaction of the alkaline waste etching solution and the sulfuric acid in sequence to obtain copper sulfate pentahydrate solids. In a case of low investment, the present invention not only can realize the recycling of copper in the copper-containing waste etching solution, but also can obtain various high-value products, and can achieve both environmental and economic benefits.

The present invention provides a method for treating a copper-containing waste etching solution, which includes: preparing basic copper chloride nanometer seed crystals and synthesizing basic copper chloride mono-crystals; making an acidic waste etching solution subjected to agglomeration reaction with an ammonium-containing solution and slurry containing the basic copper chloride mono-crystals to obtain basic copper chloride crystal particles and copper-removed waste solution; making an alkaline waste etching solution react with sulfuric acid to obtain a copper sulfate mixed solution; and then evaporating, concentrating, cooling and crystallizing the copper sulfate mixed solution obtained by the reaction of the alkaline waste etching solution and the sulfuric acid in sequence to obtain copper sulfate pentahydrate solids. In a case of low investment, the present invention not only can realize the recycling of copper in the copper-containing waste etching solution, but also can obtain various high-value products, and can achieve both environmental and economic benefits.

Disclosed in the present invention is a method for extracting nickel from a high matte nickel leaching residue. The method comprises: firstly, adding a crushed material of a high matte nickel leaching residue to an organic solvent in which sulfur is dissolved, heating same for reaction, and carrying out solid-liquid separation to obtain a first filtrate and a first filter residue; adding the first filter residue to a copper sulfate solution, heating same for reaction, and carrying out solid-liquid separation to obtain a second filtrate and a second filter residue; and evaporating, condensing and concentrating the second filtrate, and filtering same to obtain copper sulfate crystals and a nickel-containing filtrate. Throughout the whole reaction, only a small amount of sulfur and copper sulfate are consumed, and the organic solvent can be recycled.

Disclosed in the present invention is a method for extracting nickel from a high matte nickel leaching residue. The method comprises: firstly, adding a crushed material of a high matte nickel leaching residue to an organic solvent in which sulfur is dissolved, heating same for reaction, and carrying out solid-liquid separation to obtain a first filtrate and a first filter residue; adding the first filter residue to a copper sulfate solution, heating same for reaction, and carrying out solid-liquid separation to obtain a second filtrate and a second filter residue; and evaporating, condensing and concentrating the second filtrate, and filtering same to obtain copper sulfate crystals and a nickel-containing filtrate. Throughout the whole reaction, only a small amount of sulfur and copper sulfate are consumed, and the organic solvent can be recycled.

A copper microparticle with antibacterial and/or biocidal activity, wherein each microparticle has a regular, crystalline and microstructured composition that comprises 5 different copper compounds: Antlerite Cu.sub.3.sup.+2(SO.sub.4)(OH).sub.4, Brochantite Cu.sub.4.sup.+2SO.sub.4(OH).sub.6, Chalcantite Cu.sup.+2SO.sub.4.5H.sub.2O, Natrochalcite NaCu.sub.2.sup.+2(SO.sub.4).sub.2OH.H.sub.2O and Hydrated copper sulfate hydroxide Cu.sub.3(SO.sub.4).sub.2(OH).sub.2.4H.sub.2O/2CuSO.sub.4.Cu(OH).sub.2, with the microparticle having a size of between 5 and 50 m. A process for preparing copper microparticles with antibacterial and/or biocidal activity. A concentrated polymeric composition (masterbatch) with antibacterial and/or biocidal activity that is incorporated during the extrusion process to molten polymers for forming rigid or flexible products such as fibers, filaments, and sheets. A use of a copper microparticle with antibacterial and/or biocidal activity. A use of a concentrated polymeric composition (masterbatch) with antibacterial and/or biocidal activity.

A copper microparticle with antibacterial and/or biocidal activity, wherein each microparticle has a regular, crystalline and microstructured composition that comprises 5 different copper compounds: Antlerite Cu.sub.3.sup.+2(SO.sub.4)(OH).sub.4, Brochantite Cu.sub.4.sup.+2SO.sub.4(OH).sub.6, Chalcantite Cu.sup.+2SO.sub.4.5H.sub.2O, Natrochalcite NaCu.sub.2.sup.+2(SO.sub.4).sub.2OH.H.sub.2O and Hydrated copper sulfate hydroxide Cu.sub.3(SO.sub.4).sub.2(OH).sub.2.4H.sub.2O/2CuSO.sub.4.Cu(OH).sub.2, with the microparticle having a size of between 5 and 50 m. A process for preparing copper microparticles with antibacterial and/or biocidal activity. A concentrated polymeric composition (masterbatch) with antibacterial and/or biocidal activity that is incorporated during the extrusion process to molten polymers for forming rigid or flexible products such as fibers, filaments, and sheets. A use of a copper microparticle with antibacterial and/or biocidal activity. A use of a concentrated polymeric composition (masterbatch) with antibacterial and/or biocidal activity.

Process to decrease silicon content of metal powder produced by hydrogen reduction from ammoniacal ammonium sulphate solutions containing metal ammine complexes, wherein metal (Me) is Ni, Co, or Cu. The process controls the precipitation of metal hydroxide, which is found to be an effective scavenger for silicon. Silicon is preferentially removed from metal diammine sulphate-containing solutions by precipitating with a small amount of a metal hydroxide, and then separating the silicon-bearing metal hydroxide precipitate from the solution. This solution, from which the silicon impurity has been removed with the metal hydroxide precipitate, can then be reduced in one or more densification cycles with a reducing gas to produce an elemental metal powder having a decreased silicon content. Alternatively, the solution is reduced to produce a low silicon metal powder seed material for the first of the one or more densification cycles.