The present invention relates to a method for producing core-shell nanocrystals consisting of a metal-containing nanocrystal core and a shell layer comprising at least one metal oxide material having variable shell thicknesses, and use of the core-shell nanocrystals for different applications.

Provided is a method for recycling lead iodide and a substrate of a waste perovskite device. The method includes steps as follows: preparing an iodide solution having a set concentration; immersing the waste perovskite device in the iodide solution for dissolution until a perovskite substance of the waste perovskite device is not dissolved, and extracting supernatant; adding water to the supernatant for dilution, and obtaining lead iodide crystals containing a small quantity of impurities; washing the lead iodide crystals containing a small quantity of impurities, adding acid to treat the lead iodide crystals, washing the lead iodide crystals with isopropanol and ether to obtain lead iodide powder, and drying the lead iodide powder to obtain obtaining recycled lead iodide; and cleaning and recycling a substrate generated. The lead iodide is recycled according to Le Chatelier's principle, which achieves safe, environmentally friendly and low-cost recycling.

Provided is a method for recycling lead iodide and a substrate of a waste perovskite device. The method includes steps as follows: preparing an iodide solution having a set concentration; immersing the waste perovskite device in the iodide solution for dissolution until a perovskite substance of the waste perovskite device is not dissolved, and extracting supernatant; adding water to the supernatant for dilution, and obtaining lead iodide crystals containing a small quantity of impurities; washing the lead iodide crystals containing a small quantity of impurities, adding acid to treat the lead iodide crystals, washing the lead iodide crystals with isopropanol and ether to obtain lead iodide powder, and drying the lead iodide powder to obtain obtaining recycled lead iodide; and cleaning and recycling a substrate generated. The lead iodide is recycled according to Le Chatelier's principle, which achieves safe, environmentally friendly and low-cost recycling.

There is provided a method of preparing formamidinium lead halide perovskite quantum dots having a photoluminescence quantum yield higher than before. The disclosed method comprises steps of: preparing a lead halide solution by dissolving lead halide (II), oleic acid and oleylamine in a nonpolar solvent; preparing a formamidinium solution by dissolving formamidine acetate salt and oleic acid in a nonpolar solvent; mixing the formamidinium solution and the lead halide solution to form quantum dots; and centrifuging the mixed solution to obtain sediment; dispersing the sediment in a nonpolar solvent to prepare a crude quantum dot solution; mixing the crude quantum dot solution with methyl acetate; and centrifuging the crude quantum dot solution mixed with the methyl acetate to obtain sediment as purified quantum dots. The durable quantum dots are stably formed by injecting the lead halide solution into the formamidinium solution heated at 60 C.-90 C.

A perovskite quantum dot preparation method and a perovskite quantum dot solution are provided. The preparation method may include: providing a first solution including caesium oleate, a second solution including lead halide and a third solution including DDAB; adding the first solution, the second solution and the third solution into a non-polar alkyl solution at a preset proportion and stifling to obtain a perovskite quantum dot solution; the perovskite quantum dot solution may include caesium-lead-halogen of pure phase. In this way, the present disclosure can easily obtain the perovskite quantum dot solution including caesium-lead-halogen of pure phase.

A perovskite quantum dot preparation method and a perovskite quantum dot solution are provided. The preparation method may include: providing a first solution including caesium oleate, a second solution including lead halide and a third solution including DDAB; adding the first solution, the second solution and the third solution into a non-polar alkyl solution at a preset proportion and stifling to obtain a perovskite quantum dot solution; the perovskite quantum dot solution may include caesium-lead-halogen of pure phase. In this way, the present disclosure can easily obtain the perovskite quantum dot solution including caesium-lead-halogen of pure phase.

A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.

A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.

A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.

A method for preparing photoactive perovskite materials. The method comprises the steps of: introducing a lead halide and a first solvent to a first vessel and contacting the lead halide with the first solvent to dissolve the lead halide to form a lead halide solution, introducing a Group 1 metal halide a second solvent into a second vessel and contacting the Group 1 metal halide with the second solvent to dissolve the Group 1 metal halide to form a Group 1 metal halide solution, and contacting the lead halide solution with the Group 1 metal halide solution to form a thin-film precursor ink. The method further comprises depositing the thin-film precursor ink onto a substrate, drying the thin-film precursor ink to form a thin film, annealing the thin film; and rinsing the thin film with a salt solution.