A material capable of producing a sintered body of cubic system garnet type Li.sub.7La.sub.3Zr.sub.2O.sub.12 as a solid electrolyte having specified ion conductivity by firing at relatively low temperature in short time. The material for the solid electrolyte is an oxide containing Li, La, Zr and Bi, and the oxide has a cubic system garnet crystal structure where La sites are partly or entirely substituted by Bi.

A process for the synthesis of nanocrystals of metal chalcohalides is disclosed, where M is a metal, E is a chalcogen and X is a halogen, starting from a salt of M. The process includes the following steps: a) a precursor of metal M is mixed with a surfactant in a solvent having a boiling point higher than 180 C.; b) the mixture obtained in previous step a) is heated, in order to dissolve the components, until it becomes clear; c) the solution is heated up under inert atmosphere at the desired temperature; d) chalcogen and halogen precursors in 0 a solvent having a boiling point higher than 180 C. are added through injection, while heating the solution obtained in steps a) to c); e) after the reaction time has elapsed, the product is quenched down to room temperature.

A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.

The present disclosure is directed to methods of making Pb-free perovskites for short-wave IR (SWIR) devices and to various Pb-free perovskite materials disclosed herein. The perovskites disclosed herein have improved chemical stability and long-term stability, while the production methods disclosed herein have improved safety and lower cost.

A method of controlling the ionic conductivity of a polymer member, including providing a plurality of particles of bi-doped garnet, dispersing the plurality of particles of bi-doped garnet in a PEO matrix to yield a polymer member, nucleating spherulites at bi-doped garnet particle sites, and growing spherulites to a critical density to provide ionic conductivity pathways throughout the polymer member.

A lead-based alloy containing alloying additions of bismuth, antimony, arsenic, and tin is used for the production of doped leady oxides, lead-acid battery active materials, lead-acid battery electrodes, and lead-acid batteries.

The present invention provides a two-dimensional double perovskite nanomaterial represented by the formula Cs.sub.2ABX.sub.6 or L.sub.4[Cs.sub.2ABX.sub.6].sub.n-1ABX.sub.8, wherein A is a metal ion selected from Ag(I), Au(I), and Cu(I); B is a metal ion selected from In(III), Bi(III), Sb(III), Fe(III), and Tl(III); X is a halogen; L is a ligand; and n represents the number of metal-halide octahedral layers present in said nanomaterial. The invention further provides a light emitting material and electronic-, optic-, or optoelectronic device comprising said nanomaterial; as well as methods for the preparation of said nanomaterial.

The present invention relates to a method of preparing a buffer material composed of bentonite modified with a layered double hydroxide (LDH) as a buffer material used for deep geological disposal of radioactive waste, the method including a step (a) of producing a first mixture by adding a compound containing a divalent cationic material, aluminum nitrate (Al(NO.sub.3).sub.3), and bismuth nitrate (Bi(NO.sub.3).sub.3) to a reactor.