A lithium transition metal oxide capable of minimizing a side reaction with an electrolyte, thereby suppressing the generation of gas during charging and discharging of a lithium secondary battery is provided. A lithium transition metal oxide is represented by Chemical Formula 1, wherein a lattice parameter of a unit lattice satisfies Equations 1 and 2. A positive electrode additive for a lithium secondary battery, and a lithium secondary battery are also provided.

The invention relates to a layered double hydroxide (LDH) material and methods for using the LDH material to catalyse the oxygen evolution reaction (OER) in a water-splitting process. The invention also provides a composition, a catalytic material, an electrode and an electrolyser including the LDH material. In particular, the LDH material includes a metal composite including cobalt, iron, chromium and optionally nickel species interspersed with a hydroxide layer.

A composite oxide powder including a composition formula (1), wherein the ratio α/β of a surface area value α(m.sup.2/g) calculated by a BET one-point method to a surface area value β(m.sup.2/g) calculated from a formula (2) is greater than 1.0 and equal to or less than 1.5 and the surface area value α is equal to or less than 20 m.sup.2/g. ABO.sub.3-δ (1) (wherein A is one or more types of elements (La, Sr, Sm, Ca and Ba), B is one or more types of elements (Fe, Co, Ni and Mn) and 0≤δ<1); and surface area value β(m.sup.2/g)=specific surface area value γ- surface area value ε(2) (the specific surface area value γ(m.sup.2/g) is a value in a total pore size range measured by a mercury intrusion method.The specific surface area value ε(m.sup.2/g) is a value in a range of pore sizes that are larger than a 50% cumulative particle size.

The invention relates to a process for preparing aluminates of the general formula (I)

A.sub.1B.sub.xAl.sub.12-xO.sub.19-y where A is at least one element from the group consisting of Sr, Ba and La, B is at least one element from the group consisting of Mn, Fe, Co, Ni, Rh, Cu and Zn, x=0.05-1.0, y is a value determined by the oxidation states of the other elements, which comprises the steps (i) provision of one or more solutions or suspensions comprising precursor compounds of the elements A and B and also a precursor compound of aluminum in a solvent, (ii) conversion of the solutions or suspensions or the solutions into an aerosol, (iii) introduction of the aerosol into a directly or indirectly heated pyrolysis zone, (iv) carrying out of the pyrolysis and (v) separation of the resulting particles comprising hexaaluminate of the general formula (I) from the pyrolysis gas.

A method of manufacturing lithium-metal nitride including suspending a lithium-metal-oxide-powder (LMOP) within a gaseous mixture, incrementally heating the suspended LMOP to a holding temperature of between 400 and 800 degrees Celsius such that the LMOP reaches the holding temperature, and maintaining the LMOP at the holding temperature for a time period in order for the gaseous mixture and the LMOP to react to form a lithium-metal nitride powder (LMNP).

The present invention relates to an anode active material for lithium secondary battery and a lithium secondary battery including the same, and more specifically it relates to an anode active material for lithium secondary battery in which the a lithium ion diffusion path in the primary particles is formed to exhibit specific directivity, and a lithium secondary battery including the same. The cathode active material for lithium secondary battery of the present invention has a lithium ion diffusion path exhibiting specific directivity in the primary particles and the secondary particles, thus not only the conduction velocity of the lithium ion is fast and the lithium ion conductivity is high but also the cycle characteristics are improved as the crystal structure hardly collapses despite repeated charging and discharging.

A process for preparing a stable Li.sub.xMn.sub.2-yMe.sub.yO.sub.4-zCl.sub.z material with a MO.sub.b or MMn.sub.aO.sub.b charge transfer catalyst coating is provided, where Me is Fe, Co, or Ni and M is Bi, As, or Sb. In addition, a Li.sub.xMn.sub.2-yMe.sub.yO.sub.4-zCl.sub.z material with a MO.sub.b or MMn.sub.aO.sub.b charge transfer catalyst coating is provided. Furthermore, a lithium or lithium ion rechargeable electrochemical cell is provided, which includes a cathode material (in a positive electrode) containing a Li.sub.xMn.sub.2-yMe.sub.yO.sub.4-zCl.sub.z material with a MO.sub.b or MMn.sub.aO.sub.b charge transfer catalyst coating.

A lithium-ion battery includes: a cathode; an anode; and a non-aqueous electrolyte solution, in which the cathode includes a current collector and a cathode mixture applied on at least one side of the current collector, the cathode mixture includes a lithium transition metal oxide as a cathode active material, the anode includes a lithium titanium complex oxide as an anode active material, and the non-aqueous electrolyte solution includes a fluorine-containing boric acid ester.

A positive electrode active material has a small difference in a crystal structure between the charged state and the discharged state. For example, the crystal structure and volume of the positive electrode active material, which has a layered rock-salt crystal structure in the discharged state and a pseudo-spinel crystal structure in the charged state at a high voltage of approximately 4.6 V, are less likely to be changed by charging and discharging as compared with those of a known positive electrode active material. In order to form the positive electrode active material having the pseudo-spinel crystal structure in the charged state, it is preferable that a halogen source such as a fluorine and a magnesium source be mixed with particles of a composite oxide containing lithium, a transition metal, and oxygen, which is synthesized in advance, and then the mixture be heated at an appropriate temperature for an appropriate time.

According to one embodiment, a positive electrode active material for a non-aqueous electrolyte secondary battery contains a lithium/transition metal composite oxide that contains 80 mol % or more, relative to the total mol number of metal elements other than Li, of Ni and at least one kind of metal element selected from among Co, Mn, Al, W, Mg, Mo, Nb, Ti, Si and Zr. When a filtrate of a suspension, said suspension being prepared by adding 250 mg of the positive electrode active material to 10 mL of a 17.5 mass % aqueous solution of hydrochloric acid, dissolving by heating at 90° C. for 2 hours and then diluting to 50 mL, is analyzed by inductively coupled plasma mass spectrometry, the elution amount of S in the filtrate is 0.002 mmol or greater.