Provided is a method for separating impurities and cobalt without using an electrolysis process from a cobalt chloride solution containing impurities and producing a high purity cobalt sulfate. The production method for cobalt sulfate includes: a copper removal step (S1) of adding a sulfurizing agent to a cobalt chloride solution containing one or more impurities of copper, zinc, manganese, calcium, and magnesium and generating a precipitate of sulfide of copper to separate to remove copper; a neutralization step (S2) of adding a neutralizer or a carbonation agent to a cobalt chloride solution having undergone through the copper removal step (S1) and generating cobalt hydroxide or basic cobalt carbonate to separate magnesium; a leaching step (S3) of adding sulfuric acid to the cobalt hydroxide or the basic cobalt carbonate to obtain cobalt sulfate solution; and a solvent extraction step (S4) of bringing an organic solvent containing an alkyl phosphoric acid-based extractant to the cobalt sulfate solution and extracting zinc, manganese, and calcium into the organic solvent to separate to remove zinc, manganese, and calcium. These steps are sequentially executed.

An improved process is provided for forming a precursor to a lithium metal oxide. An improved lithium metal oxide formed by calcining the precursor is also provided. The process includes providing lithium bicarbonate in a first aqueous mixture. The lithium bicarbonate is then reacted with metal acetate thereby forming a second aqueous mixture comprising metal carbonate, lithium acetate, acetic acid and water wherein the acetic acid is neutralized with lithium hydroxide thereby forming a first mixture comprising metal carbonate and lithium acetate. The first mixture is separated into a second mixture and a third mixture wherein the second mixture comprises the metal carbonate and a first portion of lithium acetate with metal carbonate and lithium acetate being in a predetermined molar ratio. The third mixture comprises a second portion of lithium acetate. The second mixture is dried thereby forming the precursor comprising metal carbonate and lithium acetate in the predetermined molar ratio.

An improved process is provided for forming a precursor to a lithium metal oxide. An improved lithium metal oxide formed by calcining the precursor is also provided. The process includes providing lithium bicarbonate in a first aqueous mixture. The lithium bicarbonate is then reacted with metal acetate thereby forming a second aqueous mixture comprising metal carbonate, lithium acetate, acetic acid and water wherein the acetic acid is neutralized with lithium hydroxide thereby forming a first mixture comprising metal carbonate and lithium acetate. The first mixture is separated into a second mixture and a third mixture wherein the second mixture comprises the metal carbonate and a first portion of lithium acetate with metal carbonate and lithium acetate being in a predetermined molar ratio. The third mixture comprises a second portion of lithium acetate. The second mixture is dried thereby forming the precursor comprising metal carbonate and lithium acetate in the predetermined molar ratio.

A process for water removal and/or recycling of sodium sulfate and/or sodium dithionate containing liquors derived from processing cobalt resource material essentially free of lithium comprising the steps of precipitation of cobalt as cobaltous carbonate or cobaltous hydroxide followed by removal thereof from the liquor, crystallization of sodium sulfate and sodium dithionate and removal of the crystals, followed by heating of the crystals to anhydrous sodium sulfate, sulphur dioxide and water and then separating the anhydrous sodium sulfate.

A process for water removal and/or recycling of sodium sulfate and/or sodium dithionate containing liquors derived from processing cobalt resource material essentially free of lithium comprising the steps of precipitation of cobalt as cobaltous carbonate or cobaltous hydroxide followed by removal thereof from the liquor, crystallization of sodium sulfate and sodium dithionate and removal of the crystals, followed by heating of the crystals to anhydrous sodium sulfate, sulphur dioxide and water and then separating the anhydrous sodium sulfate.

A process is provided for recovering a heavy metal from a waste stream resulting from a process for producing aromatic carboxylic acid by liquid-phase oxidation of an aromatic feedstock compound in the presence of a heavy metal catalyst. The process comprises: (a) producing a carbonate salt precipitate of the heavy metal by adding a source of metal ions and carbonate or bicarbonate ions into the waste stream; (b) separating the precipitate from the waste stream; (c) washing the precipitate with an alkali solution having metal ions therein, wherein at least a portion of the metal ions in the alkali solution are the same as at least a portion of metal ions in the source of metal ions and carbonate or bicarbonate ions; and, (d) recovering the washed precipitate wherein the washed precipitate comprises the heavy metal ions. In one embodiment, the aromatic carboxylic acid comprises terephthalic acid.

A process is provided for recovering a heavy metal from a waste stream resulting from a process for producing aromatic carboxylic acid by liquid-phase oxidation of an aromatic feedstock compound in the presence of a heavy metal catalyst. The process comprises: (a) producing a carbonate salt precipitate of the heavy metal by adding a source of metal ions and carbonate or bicarbonate ions into the waste stream; (b) separating the precipitate from the waste stream; (c) washing the precipitate with an alkali solution having metal ions therein, wherein at least a portion of the metal ions in the alkali solution are the same as at least a portion of metal ions in the source of metal ions and carbonate or bicarbonate ions; and, (d) recovering the washed precipitate wherein the washed precipitate comprises the heavy metal ions. In one embodiment, the aromatic carboxylic acid comprises terephthalic acid.

Disclosed are a copper-doped lithium cobalt oxide precursor, a cathode material, a preparation method therefor and use thereof. The method comprises the following steps: (1) mixing a solution of soluble cobalt salt and copper salt, urea and a carbon source to perform a hydrothermal reaction to obtain a mixture; and (2) subjecting the mixture obtained in step (1) to solid-liquid separation, washing and drying the obtained solid product to obtain the copper-doped lithium cobalt oxide precursor. The cathode material prepared by the copper-doped lithium cobalt oxide precursor has better cycle performance and discharge capacity.

The present invention relates to a process for selectively capturing chemical elements from a polymetallic liquid sample.

The present invention relates to a process for selectively capturing chemical elements from a polymetallic liquid sample.