Patent classifications
C01G53/003
METHOD FOR PRODUCING SOLUTIONS CONTAINING NICKEL OR COBALT
Provided is a method for producing solutions, by which two solutions, namely a high-purity nickel sulfate solution and a mixed solution of nickel sulfate and cobalt sulfate are able to be obtained at the same time from a sulfuric acid solution containing nickel, cobalt and calcium. A method for producing solutions according to the present invention uses a sulfuric acid solution containing nickel, cobalt and calcium and performs a first step S1 for producing a mixed solution of nickel sulfate and cobalt sulfate from the sulfuric acid solution and a second step S2 for producing a solution of nickel sulfate from the sulfuric acid solution in parallel. In the first step, the sulfuric acid solution is subjected to solvent extraction by an extractant, thereby obtaining a first organic solvent after extraction In the second step, the sulfuric acid solution is subjected to solvent extraction by means of an extractant.
Simple approach for preparing post-treatment-free solution processed non-stoichiometric niox nanoparticles as conductive hole transport materials
High-quality non-stoichiometric NiO.sub.x nanoparticles are synthesized by a facile chemical precipitation method. The NiO.sub.x film can function as an effective p-type semiconductor or hole transport layer (HTL) without any post-treatments, while offering wide temperature applicability from room-temperature to 150 C. For demonstrating the potential applications, high efficiency is achieved in organic solar cells using NiO.sub.x HTL. Better performance in NiO.sub.x based organic light emitting diodes is obtained as compared to devices using PEDOT:PSS. The solution-processed NiO.sub.x semiconductors at room temperature can favor a wide-range of applications of large-area and flexible optoelectronics.
Nickel-iron wet treatment method and application thereof
Disclosed are a nickel-iron wet treatment method and an application thereof. The treatment method comprises: in a high-pressure oxygen environment, mixing a crushed nickel-iron material, sulphuric acid and a corrosion aid, performing an acid leaching reaction, then performing solid-liquid separation on slurry subjected to acid leaching, adding an oxidant into the obtained filtrate, performing heating, removing the corrosion aid, adding a precipitating agent into the filtrate, controlling the pH value of the filtrate, and performing solid-liquid separation to obtain a ferric hydroxide precipitate and a nickel-containing filtrate; and performing extraction and back extraction on the nickel-containing filtrate to prepare battery-grade nickel sulphate. According to the present invention, the nickel-iron is subjected to oxidation acid dissolution in cooperation with the corrosion aid under the high-pressure oxygen and acidic conditions; the nickel-iron is extremely prone to oxidation in the high-pressure oxygen environment; and a strong oxidant is added into the filtrate subsequently, so that ferrous ions in the filtrate are completely converted into ferric ions, and the corrosion aid can be oxidized to generate pollution-free carbon dioxide and water, thereby avoiding the impact of the corrosion aid on the subsequent extraction process.
PROCESSING METHOD FOR LITHIUM ION BATTERY SCRAP
A method for processing lithium ion battery scrap according to this invention includes a leaching step of leaching lithium ion battery scrap to obtain a leached solution; an aluminum removal step of neutralizing the leached solution to a pH range of from 4.0 to 6.0, then performing solid-liquid separation and removing aluminum in the leached solution to obtain a first separated solution; and an iron removal step of adding an oxidizing agent to the first separated solution and adjusting the pH in a range of from 3.0 to 5.0, then performing solid-liquid separation and removing iron in the first separated solution to obtain a second separated solution.
Method for Regenerated Raw Materials from Waste Cadmium Nickel Battery Based on Solvent Extraction
A method for regenerating raw materials of waste Nickel-Cadmium batteries based on solvent extraction is disclosed. The method is used for disassembling, rinsing and shredding industrial waste from Nickel-Cadmium batteries. The solvent extraction technology is easy for large-scale and continuous production, and valuable metals such as cadmium, cobalt and nickel are extracted from the waste Nickel-Cadmium batteries to prepare products such as cadmium nitrate, cobalt nitrate, nickel nitrate which are directly used for producing raw materials for Nickel-Cadmium batteries. No new waste salt and waste residues are generated in the process. High-efficiency separation and purification of all valuable metals during the regeneration of waste Nickel-Cadmium batteries and the full-life cycle regeneration cycle of Nickel-Cadmium batteries are achieved.
Process to produce magnesium compounds, and various by-products using sulfuric acid in a HCl recovery loop
The present description relates to a process for extracting magnesium compounds from magnesium-bearing ores comprising leaching serpentine tailing with dilute HCl to dissolve the magnesium and other elements like iron and nickel. The residual silica is removed and the rich solution is further neutralized to eliminate impurities and recover nickel. Magnesium chloride is transformed in magnesium sulfate and hydrochloric acid by reaction with sulfuric acid. The magnesium sulfate can be further decomposed in magnesium oxyde and sulphur dioxyde by calcination. The sulphur gas can further be converted into sulfuric acid.
LITHIUM RECYCLING
A recycling method for generating purified lithium salts from a recycling stream of lithium-ion (Li-ion) batteries includes leaching black mass from the recycling stream in an aqueous solution of an oxidizing agent. Delithiated black mass is filtered from the aqueous solution to generate a Li-rich leach solution, which is subjected to nanofiltration to form a nanofiltration permeate from which the purified lithium salt is obtained.
Sulfonated aminomethylated chelate resins
The invention relates to sulfonated aminomethylated chelate resins, to a method for producing same, to the use thereof for obtaining and purifying metals, in particular rare earth metals, from aqueous solutions and organic liquids, and for producing highly pure silicon.
PROCESS FOR PREPARING A HIGH-PURITY NICKEL SULPHATE SOLUTION
The present invention provides a process for preparing a high-purity nickel sulphate solution, comprising the steps of: i. providing an aqueous feed solution comprising nickel. cobalt, calcium and magnesium: ii. extracting cobalt, calcium, and partly magnesium from said aqueous feed solution using a first solvent comprising a first alkylphosphorus-based acidic extractant, thereby obtaining an aqueous raffinate comprising nickel and magnesium: iii. extracting magnesium from said aqueous raffinate solution comprising nickel and magnesium using a second solvent comprising a second alkylphosphorus-based acidic extractant, thereby obtaining a high-purity aqueous nickel sulphate solution comprising nickel and magnesium: iv. stripping the first loaded solvent comprising cobalt, calcium and magnesium with an aqueous solution comprising a mineral acid.