An anode material for a secondary battery is provided. The anode material for the secondary battery includes a metal oxide containing four or more than four elements, or an oxide mixture containing four or more than four elements. The metal oxide includes cobalt-copper-tin oxide, silicon-tin-iron oxide, copper-manganese-silicon oxide, tin-manganese-nickel oxide, manganese-copper-nickel oxide, or nickel-copper-tin oxide. The oxide mixture includes the oxide mixture containing cobalt, copper and tin, the oxide mixture containing silicon, tin and iron, the oxide mixture containing copper, manganese and silicon, the oxide mixture containing tin, manganese and nickel, the oxide mixture containing manganese, copper and nickel, or the oxide mixture containing nickel, copper and tin.

Provided is an apparatus for producing a positive electrode active material precursor. The apparatus includes: a reactor into which a reaction solution is introduced; a stirrer being inserted into the reactor and stirring the reaction solution; and a filter type baffle being inserted into the reactor and including a filter.

When manufacturing a magnetic body whose primary component is Ni—Zn ferrite, an iron oxide powder whose Mn content is 0.20 to 0.85 percent by mass is used as a raw material powder, or, in addition to using an iron oxide powder whose Mn content is 0.20 percent by mass or higher as a raw material powder, a mol ratio of Ni to Zn (Ni/Zn) in the ferrite material is determined based on the Mn content in the iron oxide powder and the raw material powders are compounded in such a way that the mol ratio is achieved. The magnetic body does not contain any additives as essential components other than the primary components of the Ni—Zn ferrite material. A coil component using the magnetic body has excellent direct-current superimposition property and magnetic permeability.

The present invention provides a powdered ferrite having high dispersibility in a resin and high electromagnetic shielding characteristics. The powdered ferrite comprises platy ferrite particles having a spinel crystal structure. The powdered ferrite comprises at least 50 number % platy ferrite particles each having at least one protrusion on a surface of the particle, and the protrusion has a shape selected from the group consisting of a rectangular pyramid, a truncated rectangular pyramid, an elongated rectangular pyramid, and combinations thereof.

A method of preparing hollow molybdate composite microspheres includes steps of: (1) dissolving 1-4 mmol of MCl.sub.2 in 20 ml of water to obtain a solution A and dissolving 1-4 mmol. of molybdic acid in 20 ml of water to obtain a solution B, followed by mixing the solution A and the solution B, in which M is Co, Ni, or Cu; (2) dissolving 10-40 mmol of urea in 40 ml of water, adding the mixed solution of step (1) and stirring uniformly; (3) placing the mixed solution of step (2) into a reaction vessel and reacting at 120-160° C. for 6-12 hours; (4) suction filtrating and water washing, followed by drying in a vacuum oven at 40-60° C.; (5) calcination at 350-500° C. for 2-4 hours in a Muffle furnace.

The present invention provides a method for producing a manganese-doped nickel molybdate electrode material including mixing a nickel salt solution with a manganese salt solution to form a mixture; adding a molybdate solution into the mixture and being subject to a thermal reaction; and obtaining the manganese-doped nickel molybdate electrode material after washing and drying of the reaction product. The nickel salt includes one or more of nickel nitrate, nickel chloride, and nickel acetate; the manganese salt includes one or more of manganese chloride, manganese nitrate, and manganese sulfate; and the molybdate includes one or more of sodium molybdate or ammonium molybdate. The present method utilizes a single reaction to produce a Mn-doped NiMoO.sub.4 electrode material, which does not require using nickel molybdate as an intermediate product. The method simplifies the preparation process and makes it easy to be adjusted, thereby improving the electrochemical properties of the electrode material.

A magnetic nanoparticle, and composites thereof, comprising a ternary host compound comprising a transition metal oxide of size 2-30 nm having two transition metal dopants atom incorporated therein, such that the nanoparticle is converted from superparamagnetic or weak ferromagnetic to strong ferromagnetic material. The strong permanent magnets are formed from non-rare earth materials. The composite material can also include undoped nanoparticles.

The invention relates to doped nickelate-containing compounds comprising A.sub.aM.sup.1.sub.VM.sup.2.sub.WM.sup.3.sub.XM.sup.4.sub.yM.sup.5.sub.ZO.sub.2-c wherein A comprises either sodium or a mixed alkali metal in which sodium is the major constituent; M.sup.1 is nickel in oxidation state greater than 0 to less than or equal to 4+, M.sup.2 comprises a metal in oxidation state greater than 0 to less than or equal to 4+, M.sup.3 comprises a metal in oxidation state 2+, M.sup.4 comprises a metal in oxidation state greater than 0 to less than or equal to 4+, and M.sup.5 comprises a metal in oxidation state 3+ wherein 0≤a<1, v>0, at least one of w and y is >0 x≥0, z≥0 wherein c is determined by a range selected from 0<c≤0.1 and wherein (a, v, w, x, y, z and c) are chosen to maintain electroneutrality.

A lithium-containing complex transition metal oxide forming the positive electrode active material of a non-aqueous electrolyte secondary cell in one embodiment is a secondary particle obtained by aggregating primary particles. Ion chromatography analysis of a sample obtained by adding the positive electrode active material to an alkali solution and absorbing a distillate thereof in sulfuric acid results in detection of 2-200 pm of ammonia relative to the mass of the positive electrode active material. When a filtrate of an aqueous dispersion in which 1 g of the positive electrode active material is dispersed in 70 ml of pure water is titrated with hydrochloric acid, the value of Y−X is 50-300 mol/g and the value of X−(Y−X) is no higher than 150 mol/g, with X mol/g being the acid consumption until a first inflection point on the pH curve and Y mol/g being the acid consumption until a second inflection point.

A positive electrode active material includes a composite particle. The composite particle includes a core particle and a covering layer. The core particle includes a nickel composite hydroxide. The nickel composite hydroxide is represented by the following formula: Ni.sub.x1Zn.sub.1-x1-y1Co.sub.y1(OH).sub.2 (where x1 and y1 satisfy 0.90≤x1<1.00, 0≤y1≤0.01, and 0<(1−x1−y1)). The covering layer covers at least a part of a surface of the core particle. The covering layer includes a cobalt compound. In an X-ray absorption fine structure obtainable through measurement by a total electron yield method with soft X-ray, cobalt L.sub.3 absorption edge has a peak top in a range not less than 780.5 eV.