An advantage is to provide a non-aqueous electrolyte secondary battery with improved heat resistance. A positive electrode active material contains a lithium-transition metal composite oxide containing 80 mol % or more of Ni and 0.1 mol % to 1.5 mol % of B on the basis of the total number of moles of metal elements excluding Li, and B and at least one element (M1) selected from Groups 4 to 6 are present on at least the surfaces of particles of the composite oxide. When particles having a volume-based particle size larger than 70% particle size (D70) are first particles, and particles having a volume-based particle size smaller than 30% particle size (D30) are second particles, the molar fraction of M1 on the basis of the total number of moles of metallic elements excluding Li on the surfaces of the second particles is greater than that of the first particles.

Provided are particles for use as a precursor material for synthesis of Li-ion cathode active material of a lithium-ion cell comprising: a non-lithiated nickel oxide particle of the formula MO.sub.x wherein M comprises 80 at % Ni or greater and wherein x is 0.7 to 1.2, M optionally excluding boron in the MO.sub.x crystal structure; and a modifier oxide intermixed with, coated on, present within, or combinations thereof the non-lithiated nickel oxide particle, wherein the modifier oxide is associated with the non-lithiated nickel oxide such that a calcination at 500 degrees Celsius for 2 hours results in crystallite growth measured by XRD of 2 nanometers or less. Also provided are processes of forming electrochemically active particles using the precursors nickel oxides.

A positive electrode active material for a non-aqueous electrolyte secondary battery according to a configuration includes a lithium-transition metal composite oxide containing nickel (Ni) in an amount of greater than or equal to 80 mol %, in which boron (B) is present at least on a particle surface of the lithium-transition metal composite oxide. In the lithium-transition metal composite oxide, when particles having a larger particle size than a volume-based 70% particle size (D70) are first particles and particles having a smaller particle size than a volume-based 30% particle size (D30) are second particles, a coverage ratio of B on surfaces of the first particles is larger than a coverage ratio of B on surfaces of the second particles by 5% or greater.

The subject invention pertains to the synthesis and characterization of V.sub.2O.sub.5/CdE NW/QD heterostructures. The V.sub.2O.sub.5/CdE heterostructures are versatile new materials constructs for light harvesting, charge separation, and the photocatalytic production of solar fuels; polymorphism of V.sub.2O.sub.5 and compositional alloying of both components provides for a substantial design space for tuning of interfacial energy offsets. Also provided are a new class of type-II heterostructures composed of cadmium chalcogenide QDs (CdE where E=S, Se, or Te) and -V.sub.2O.sub.5 nanowires (NWs). The synthesis and characterization of V.sub.2O.sub.5/CdE NW/QD heterostructures, prepared via successive ionic layer adsorption and reaction (SILAR) and linker-assisted assembly (LAA), the characterization of their photoinduced charge-transfer reactivity using transient absorption spectroscopy, and their performance in the photocatalytic reduction of protons to hydrogen are also disclosed.

The present invention relates to a positive electrode active material, and a lithium secondary battery using a positive electrode including the same. More particularly, the present invention relates to a positive electrode active material that has increased efficiency in the diffusion of lithium ions and/or charges and increased structural stability by locally forming regions with different concentrations of an arbitrary transition metal in a primary particle, and a lithium secondary battery using a positive electrode including the same.

A positive electrode active material precursor, a method of preparing the same, and positive electrode active material prepared from the same are disclosed herein. In some embodiments, a positive electrode active material precursor includes a spherical secondary particle formed by aggregation of primary particles and includes a core portion composed of randomly oriented primary particles, a first shell portion which is formed on the first core portion and composed of the primary particles having a (001) plane oriented in a direction from a center of the secondary particle toward a surface thereof, and a second shell portion which is formed on the first shell portion and composed of randomly oriented primary particles.

A ceramic material, a component, and a method for producing a component are disclosed. In an embodiment a ceramic material includes a structure based on a system selected from the group consisting of NiCoMnO, NiMnO and CoMnO, and at least one dopant selected from lanthanides, wherein the ceramic material has a negative temperature coefficient of an electrical resistance.

The present disclosure relates to an anode electrode active material for a secondary battery containing nickel cobalt molybdenum oxide, an anode electrode for a secondary battery including the same, a secondary battery including the anode electrode for a secondary battery, and a method for manufacturing the same. The novel anode electrode material for a sodium secondary battery containing nickel cobalt molybdenum oxide according to the present disclosure allows intercalation/deintercalation reaction of sodium ion during charge/discharge and does not undergo significant volume change during the intercalation reaction because structure is maintained stably during repeated charge/discharge. As a result, electrode damage and electric short circuit are decreased and, thus, improved electrochemical characteristics can be achieved in long-life and high-rate capability.

In addition, the novel anode electrode material for a sodium secondary battery containing nickel cobalt molybdenum oxide is advantageous in that it can be synthesized easily via a simple process such as a one-pot reaction based on a hydrothermal synthesis process.

A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

A composition for forming an electrode. The composition includes a hybrid active material compound doped with a dopant. The hybrid active material comprises the reaction product of a metal fluoride compound and a metal complex. A method of making the composition is included.