The present disclosure relates to a composition that includes a perovskite crystal, where the perovskite crystal is in the form of a powder, and the perovskite crystal is semiconducting and photovoltaically active.

A process for preparing doped-lithium lanthanum zirconium oxide (doped-LLZO) is described herein. The method involves dry doping of a co-precipitated lanthanum zirconium oxide (LZO) precursor. Dry doping is a process in which a dry powdered dopant is ground and mixed with a pre-prepared co-precipitated LZO precursor and a lithium salt to provide a LLZO precursor composition, which is subsequently calcined to form a doped-LLZO. The process described herein comprises calcining a dry, powdered (e.g., micron, sub-micron or nano-powdered) mixture of a co-precipitated LZO precursor, a dopant salt or oxide, and a lithium salt under an oxygen-containing atmosphere at a temperature in the range of about 500 to about 1100° C., and recovering the doped-LLZO after calcining.

A method for preparing artificial graphite includes (A) preparing heavy oil, and forming coke from the heavy oil through continuous coking reaction such that the coke has a plurality of mesophase domains, wherein a size of the mesophase domains ranges between 1 and 30 μm by polarizing microscope analysis; and (B) processing the coke formed by step (A) sequentially by pre-burning carbonization treatment, grinding classification, high-temperature carbonization treatment and graphitization treatment to form polycrystalline artificial graphite from the coke. The method for preparing artificial graphite of the present invention and the polycrystalline artificial graphite prepared thereby are applicable to batteries.

A silicon-based negative electrode active material, a method for preparing the silicon-based negative electrode active material, and a secondary battery including a negative electrode that includes the silicon-based negative electrode active material. The silicon-based negative electrode active material includes a silicate. The silicate contains an alkaline earth metal element, and the silicon-based negative electrode active material contains both the element K and the element Fe.

The present invention relates to silicon coated metal microparticles in which at least a part of a surface of a metal microparticle composed of at least one of metal elements or metalloid elements is coated with silicon, wherein the silicon coated metal microparticles are a product obtained by a reduction treatment of silicon compound coated precursor microparticles in which at least a part of a surface of a precursor microparticle containing a precursor of the metal microparticles is coated with a silicon compound, or silicon doped precursor microparticles containing a precursor of the metal microparticles. Because it is possible particularly to strictly control a particle diameter of the silicon compound coated metal microparticle by controlling conditions of the reduction treatment, design of a more appropriate composition can become facilitated, compared with a conventional composition, in terms of diversified usages and desired properties of silicon compound coated metal microparticles.

A method comprising reacting an aluminum mineral polymorph or a gallium mineral polymorph with an acid at an aluminum metal to acid molar ratio or gallium metal to acid molar ratio sufficient to produce M.sub.13 nanoscale clusters, M nano-agglomerates, or a M.sub.13 slurry, wherein M is Al or Ga.

The present invention discloses a spherical or spherical-like lithium battery cathode material, a battery and preparation methods and applications thereof. The chemical formula of the cathode material is: Li.sub.aNi.sub.xCo.sub.yMn.sub.zM.sub.bO.sub.2, wherein 1.0≤a≤1.2; 0.0<b≤0.05; 0.30≤x≤0.90; 0.05≤y≤0.40; 0.05≤z≤0.50; x+y+z+b=1; M is one or two or more of Mg, Ti, Al, Zr, Y, Co, Mn, Ni, Ba and a rare earth element. A single α-NaFeO.sub.2 type layered structure of the cathode material is shown by a powder X-ray diffraction pattern and full width at half maximum FWHM (110) of the (110) diffraction peak near a diffraction angle 2θ of 64.9° is in the range of 0.073 to 0.145; the morphology of the cathode material is spherical or spherical-like primary particles and a small amount of secondary particles; the cumulative percentage of the number of particles having a particle diameter of 5 μm or less is usually larger than 60% in the number-basis particle sizes of primary particles and secondary particles agglomerated by primary particles of the cathode material. The cathode material in the present invention has excellent circulating performance, storage performance and safety performance under high temperature and high voltage, and is suitable for digital product, electric vehicle, electric bicycle, fast charging bus, passenger car, communication product, electric power and energy storage system etc.

A method for manufacturing monocrystalline graphene, includes supplying an aromatic carbon gas onto a single-crystalline metal catalyst to manufacture the monocrystalline graphene.

A method of synthesizing a gel may include dissolving resorcinol and formaldehyde to form a homogenous medium. The method may also include subjecting the medium to nitrogen gas flow. The method may further include subjecting the medium to a vacuum procedure at a room temperature. Thus, the medium is subjected to the melting temperature of resorcinol. In addition, the method may include cooling the gel and subjecting the formed gel to the vacuum procedure at the temperature lower than the melting temperature of resorcinol.

A composite positive active material includes a lithium nickel cobalt aluminum composite oxide. A full width at half maximum (FWHM) of a peak of a (104) plane of the lithium nickel cobalt aluminum composite oxide is 0.15 or less and an FWHM of a peak of a (108) plane of the lithium nickel cobalt aluminum composite oxide is 0.15 or less, the peaks being obtained by X-ray diffraction analysis using a CuKα X-ray. A method of preparing the composite positive active material, and a lithium secondary battery including a positive electrode including the composite positive active material are disclosed.