The present application relates to a cathode material and an electrochemical device comprising the same. In particular, the present application relates to a cathode material having a surface heterophasic structure, wherein the cathode material includes a lithium cobalt oxide and an oxide of cobalt, wherein a Raman spectrum of the cathode material has characteristic peaks in the range of about 470 cm.sup.−1 to about 530 cm.sup.−1, about 560 cm.sup.−1 to about 630 cm.sup.−1 and about 650 cm.sup.−1 to about 750 cm.sup.−1, and wherein the surface heterophasic structure of the cathode material includes the lithium cobalt oxide and the oxide of cobalt. The electrochemical device using the cathode material having a surface heterophasic structure of the present application can exhibit excellent cycle performance and thermal stability.

This application provides a silicon-based material, a preparation method thereof, and a secondary battery, a battery module, a battery pack, and an apparatus associated therewith. The silicon-based material includes a core structure and a coating layer provided on at least partial surface of the core structure, where the core structure includes both a silicon phase and a lithium metasilicate phase, and a particle size P of the lithium metasilicate phase is ≥30 nm. The silicon-based material of this application can not only increase energy density of a secondary battery with the silicon phase, but also improve structural stability and chemical stability of the silicon-based material, so that the secondary battery can deliver satisfactory and balanced cycling performance and first-cycle coulombic efficiency in overall.

To provide a method for producing lanthanum hexaboride-containing composite particles which are capable of forming a formed product having sufficiently high transparency and which are excellent in weather resistance, by a simple operation without calcination treatment at high temperature, and a method for producing a formed product using it. Also provided is a method for producing composite particles, which involves: reacting at least one silica precursor selected from a tetraalkoxysilane, its hydrolysate and its condensate, in the presence of lanthanum hexaboride particles, a volatile base, water and an organic solvent to obtain a first reaction mixture, and reacting the first reaction mixture with at least one silicon compound selected from an amino-modified silicone, an alkylsilane and an aminosilane, or the silicon compound and the silica precursor added, to obtain a second reaction mixture containing lanthanum hexaboride-containing composite particles.

A method is provided for manufacturing a nanoparticle material having an ionic conductivity as a battery material for Fluoride ion Batteries, thus, being capable for overcoming high resistances at the surfaces, grain-boundaries of nanoparticles or compartments of the nanoparticles by a material treatment selected from: (i) a ball-mill procedure under aerosol and/or vapour-pressure atmosphere, (ii) excess-synthesis, (iii) ball-milling with surface stabilizing and conductivity enhancing solid or/and gel/liquid additives or (iv) functionalizing the material to obtain functionalized nanoparticles (GSNP) comprising a dispersion of graphene, nanotubes and/or a further additive selected from carbon-black, graphite, Si and/or CF.sub.X, Herein, fluorides (Em.sub.mF.sub.h), fluorides composites (Em1.sub.m1Em2.sub.m2 . . . F.sub.h1) are synthesized, wherein a first metal, metalloid or non-metal Em or Em1 and a second metal, metalloid or non-metal Em2 are dissimilarly selected from various elements in a manner that a battery material having an increased ionic conductivity is obtained.

There is provided a method for collecting and reusing an active material from positive electrode scrap. The method of reusing a positive electrode active material of the present disclosure includes (a) thermally treating a positive electrode scrap comprising an active material layer comprising nickel, cobalt and manganese on a current collector in air for thermal decomposition of a binder and a conductive material in the active material layer, to separate the current collector from the active material layer, and collecting an active material in the active material layer, (b) washing the active material collected form the step (a) with a lithium compound solution which is basic in an aqueous solution and drying, and (c) annealing the active material washed from the step (b) with an addition of a lithium precursor to obtain a reusable active material.

Provided are: composite particles having excellent oxidation resistance; and a method for producing composite particles. The composite particles are obtained by forming a composite of TiN and at least one of Al, Cr, and Nb. In the method for producing composite particles, a titanium powder and a powder of at least one of Al, Cr, and Nb are used as raw material powders and composite particles are produced using a gas phase method.

Provided is a method of preparing composite nanoparticles, which includes: a) preparing a metal nanocore having a nano-star shape from a first reaction solution in which a first metal precursor is mixed with a first buffer solution; b) fixing a Raman reporter in the metal nanocore; and c) forming a metal shell, which surrounds the nanocore in which the Raman reporter is fixed, from a second reaction solution in which the nanocore in which the Raman reporter is fixed, and a second metal precursor are mixed with a second buffer solution.

The present application provides a high-nickel ternary positive electrode active material, which comprises a core Li.sub.1+a[LixCoyMn.sub.zM.sub.b]O.sub.2, a fast ionic conductor Li.sub.αAl.sub.XSi.sub.YO.sub.4 of a first shell layer, an oxide of an element R of a second shell layer, and a transition layer Li.sub.pR.sub.qO.sub.w formed between the first shell layer and the second shell layer. In the high-nickel ternary positive electrode active material of the present application, the surface impurity lithium amount is significantly reduced, and by creatively converting the surface impurity lithium into effective components in the fast ionic conductors Li.sub.αAl.sub.XSi.sub.YO.sub.4 and Li.sub.pR.sub.qO.sub.w which accelerate the intercalation/deintercalation of lithium ions in the core material, the decomposition and gas production of an electrolyte solution caused by the surface impurity lithium is greatly improved, such that a high-nickel ternary lithium-ion battery has high energy density as well as good cycle performance and safety performance.

A negative electrode material for a lithium ion battery, the material comprising: particles comprising a core, with the core containing silicon, the particles having one or more coating layers disposed around the core, at least one of the coating layers comprising a porous semi-conducting metal oxide.

A coated particle having excellent thermal expansion control and electrical insulation properties includes a core of a first inorganic compound containing a metal or semimetal element P; and a shell of a second inorganic compound containing a metal or semimetal element Q. The first inorganic compound satisfies 1, and the coated particles satisfy 2 and 3. 1: |dA(T)/dT| is ≥10 ppm/°C at T1 of -200° C. to 1,200° C. A is (an a-axis lattice constant of a crystal in the first inorganic compound)/(a c-axis lattice constant of a crystal in the first inorganic compound). 2: in XPS of a surface of each of the coated particles, a ratio of a number of atoms of Q contained in the shell to a number of atoms of P contained in the core t is 45 to 300. 3: an average particle diameter of each coated particle is 0.1 to 100 .Math.m.