Surface-treated fumed silica, with a tribo-electro static charge of −500 μC/g to +500 μC/g, a ratio of the tribo-electro static charge to BET surface area of −3.5 μC/m.sup.2 to +3.5 μC/m.sup.2, a methanol wettability of at least 20% by volume methanol in methanol/water mixture, a ratio of carbon content to BET surface area of at most 0.020 wt. %*g/m.sup.2, a process for its preparation and the use thereof.

A method suitable for mass production of nanoparticles with a uniform particle diameter is provided. It is an object to provide a powder of the nanoparticle obtained by this method, a dispersion containing the nanoparticles, and a paste containing the nanoparticles. There is provided a method for manufacturing silver particles including the step of reducing silver in a silver solution containing a protective agent composed of an organic material and a copper component in an amount of 1 to 1,000 ppm relative to the amount of silver to obtain particles having an average particle diameter (D.sub.TEM) of 5 to 100 nm as measured using a transmission electron microscope.

Methods and apparatus for predicting colorant usage by printing devices are provided. A prediction server can receive a request to predict colorant usage for a first printing device. The prediction server can determine first plurality of functions to predict colorant usage for the first printing device. The first plurality of functions can include at least one linear function and at least one non-linear function. The first plurality of functions can be based on colorant-usage rates indicating historical rates of change in colorant used by the first printing device. The prediction server can determine a prediction of colorant usage for the first printing device using the first plurality of functions. The prediction server can provide an output involving the prediction of colorant usage for the first printing device, where the prediction of colorant usage can include a confidence interval related to the prediction.

A method for preparing particles of alkali metal bicarbonate by crystallization from a solution of alkali metal carbonate and/or bicarbonate in the presence of an additive in the solution, selected from the sulfates, sulfonates, the polysulfonates, the mines, the hydroxysultaines, the polycarboxylates, the polysaccharides, the polyethers and the etherphenols, alkali metal hexametaphosphate, the phosphates such as the organophosphates or the phosphonates, the sulfosuccinates, the amido-sulfonates, the aminosulfonates, preferably selected from: the phosphates, the organophosphates or the phosphonates, and such that the additive is present in the solution at a concentration of at least 1 ppm and preferably of at most 200 ppm.

Provided is a nickel-containing composite hydroxide that is a precursor of a positive-electrode active material with which a nonaqueous-electrolyte secondary battery having a low irreversible capacity and a high energy density can be configured. An aqueous alkaline aqueous solution and a complexing agent are added to an mixed aqueous solution including at least nickel and cobalt to regulate the pH (measured at a reference liquid temperature of 25° C.) of this mixed aqueous solution to 11.0 to 13.0, the ammonium concentration to 4 to 15 g/L, and the reaction temperature to 20° C. to 45° C. Using stirring blades having an inclination angle of 20° to 60° with respect to a horizontal plane, the mixture is stirred to conduct a crystallization reaction under such conditions that when the nickel-containing composite hydroxide to be obtained is roasted in air at 800° C. for 2 hours, the roasted composite hydroxide has a BET value of 12 to 50 m.sup.2/g. Thus a nickel-containing composite hydroxide expressed by Ni.sub.1−x−yCo.sub.xAl.sub.yM.sub.t(OH).sub.2+α (where, 0<x≦0.20, 0<y≦0.15, 0≦t≦0.10, 0≦α 0.50, and M is one or more kind of element selected from among Mg, Ca, Ba, Nb, Mo, V, Ti, Zr and Y), or the general formula: Ni.sub.1−x−zCo.sub.xMn.sub.zM.sub.t(OH).sub.2+α (where 0<x≦0.50, 0<z≦0.50, x+z≦0.70, 0≦t≦0.10, 0≦α≦0.50, and M is one or more kind of element selected from among Mg, Ca, Ba, Nb, Mo, V, Ti, Zr and Y) is obtained.

There is provided a process for purifying aluminum ions comprising: reacting an aluminum-containing material with an acid so as to obtain a composition comprising aluminum ions; precipitating said aluminum ions in the form of AlCl.sub.3; optionally converting AlCl.sub.3 into Al(OH).sub.3; and heating said AlCl.sub.3 or said Al(OH).sub.3 under conditions effective for converting AlCl.sub.3 or Al(OH).sub.3 into Al.sub.2O.sub.3 and optionally recovering gaseous HCl so-produced. Aluminum ions so purified are thus useful for preparing various types of alumina.

Provided are a positive electrode active material with which a nonaqueous electrolyte secondary battery having a high energy density can be obtained, a nickel-manganese composite hydroxide suitable as a precursor of the positive electrode active material, and production methods capable of easily producing these in an industrial scale. Provided is a nickel-manganese composite hydroxide represented by General Formula (1): Ni.sub.xMn.sub.yM.sub.z(OH).sub.2+α and containing a secondary particle formed of a plurality of flocculated primary particles. The nickel-manganese composite hydroxide has a half width of a diffraction peak of a (001) plane obtained by X-ray diffraction measurement of at least 0.10° and up to 0.40° and has a degree of sparsity/density represented by [(void area within secondary particle/cross section of secondary particle)×100](%) of at least 0.5% and up to 10%. Also provided is a production method of the nickel-manganese composite hydroxide.

A lithium metal oxide powder comprises secondary particles comprised of agglomerated primary lithium metal oxide particles bonded together, the primary lithium metal oxide particles being comprised of Li, Ni, Mn, Co and oxygen and having a median primary particle size of 0.1 micrometer to 3 micrometers, wherein the secondary particles have a porosity that is at least about 10%. The lithium metal oxide powders are useful make lithium ion battery having improved performance particularly when the secondary particles deagglomerate when forming the cathode used in the lithium ion battery.

A positive electrode active material for a lithium ion secondary battery contains a lithium metal composite oxide. The lithium metal composite oxide includes lithium (Li), nickel (Ni), cobalt (Co), and an element M (M) in a mass ratio of Li:Ni:Co:M=1+a:1−x−y:x:y (wherein −0.05≤a≤0.50, 0≤x≤0.35, 0≤y≤0.35, and the element M is at least one element selected from Mg, Ca, Al, Si, Fe, Cr, Mn, V, Mo, W, Nb, Ti, Zr, and Ta), wherein a thickness of a NiO layer is 200 nm or less when a particle of the lithium metal composite oxide during charging at 4.3 V (vs. Li.sup.+/Li) is observed by STEM-EDS, and wherein a specific surface area is 0.7 m.sup.2/g or more and 2.0 m.sup.2/g or less.

A positive electrode active material for a lithium ion secondary battery contains a lithium metal composite oxide. The lithium metal composite oxide includes lithium (Li), nickel (Ni), cobalt (Co), and an element M (M) in a mass ratio of Li:Ni:Co:M=1+a:1−x−y:x:y (wherein −0.05≤a≤0.50, 0≤x≤0.35, 0≤y≤0.35, and the element M is at least one element selected from Mg, Ca, Al, Si, Fe, Cr, Mn, V, Mo, W, Nb, Ti, Zr, and Ta), wherein a thickness of a NiO layer is 200 nm or less when a particle of the lithium metal composite oxide during charging at 4.3 V (vs. Li.sup.+/Li) is observed by STEM-EDS, and wherein an index [(d90−d10)/mean volume particle diameter] of spread of a particle size distribution is 1.25 or less.