Patent classifications
C01P2006/14
Iron-loaded small pore aluminosilicate zeolites and method of making metal loaded small pore aluminosilicate zeolites
The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2. The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.
Ceramic powder material, sintered body, and battery
A ceramic powder material containing: a first garnet-type compound containing Li, La, and Zr; and a second garnet-type compound containing Li, La, and Zr and having a composition different from a composition of the first garnet-type compound, in which the first garnet-type compound and the second garnet-type compound are represented by Formula [1] Li.sub.7-(3x+y)M1.sub.xLa.sub.3Zr.sub.2-yM2.sub.yO.sub.12, where M1 is Al or Ga, M2 is Nb or Ta, the first garnet-type compound satisfies 0≤(3x+y)≤0.5, and the second garnet-type compound satisfies 0.5<(3x+y)≤1.5.
Method and device for producing a product containing amorphous silica and amorphous carbon
The proposed method relates to the processing of carbon-containing raw material and may be used to obtain products containing amorphous silica and amorphous carbon of varying degrees of purity. The technical result consists in simplifying the production of a product containing amorphous silica and increasing the yield efficiency for such a product by decreasing the temperature to which the carbon-containing raw material is exposed. The method of producing a product containing amorphous silica and amorphous carbon includes the steps in which a carbon-containing raw material is dried at a temperature of 150-200° C. and the dried raw material is subjected to heat treatment at a temperature of 400-600° C., wherein the heat treatment is performed in the presence of an activator made of a readily fusible alloy. A device for carrying out the method is also proposed.
METHODS FOR PRODUCING HIERARCHICAL MESOPOROUS BETA ZEOLITE
A method for producing a hierarchical mesoporous beta includes mixing a beta zeolite with an aqueous metal hydroxide solution and heating the beta zeolite and the aqueous metal hydroxide mixture to produce a desilicated beta zeolite, contacting the desilicated beta zeolite with an ammonium salt solution to produce an intermediate hierarchical mesoporous beta zeolite, and treating the intermediate hierarchical mesoporous beta zeolite with an acidic solution to produce the hierarchical mesoporous beta zeolite. The hierarchical mesoporous beta zeolite includes a molar ratio of silicon to aluminum of greater than 12.5, a total pore volume of greater than or equal to the total pore volume of the intermediate hierarchical mesoporous beta zeolite, and an average mesopore size of greater than or equal to the average mesopore size of the hierarchical mesoporous beta zeolite. The method may also include calcining the intermediate hierarchical mesoporous beta zeolite.
FUMED SILICA WITH MODIFIED SURFACE ACTIVITY
Fumed silica powder, surface treated with a surface treatment agent selected from the group consisting of organosilanes, silazanes, acyclic polysiloxanes, cyclic polysiloxanes, and mixtures thereof, wherein the powder has: a) a number of silanol groups relative to BET surface area d.sub.SiOH of at least 0.85 SiOH/nm.sup.2, as determined by reaction with lithium aluminium hydride; b) a methanol wettability of more than 40% by volume of methanol in methanol-water mixture; c) a tamped density of not more than 200 g/L.
CARBONACEOUS MATERIAL AND METHOD FOR PRODUCING SAME, WATER PURIFICATION FILTER, AND WATER PURIFIER
One aspect of the present invention relates to a carbonaceous material having a BET specific surface area calculated from a nitrogen adsorption isotherm by a BET method, of 750 m.sup.2/g or more and 1000 m.sup.2/g or less, a ratio of a pore volume of pores of 0.3875 to 0.9125 nm calculated from the nitrogen adsorption isotherm by a HK method to a total pore volume calculated from the nitrogen adsorption isotherm by the HK method, of 80% or more, and an average pore diameter obtained by the following formula using the BET specific surface area and the total pore volume calculated from the nitrogen adsorption isotherm by the HK method, of 1.614 nm or less: D=4000×V/S (wherein D represents the average pore diameter (nm), V represents the total pore volume (mL/g), and S represents the specific surface area (m.sup.2/g)).
Powdered titanium oxide, method for the production thereof, and use thereof
A powdered catalyst material on a titanium oxide basis. The powdered catalyst material includes a combined content of at least 90 wt.-% of a hydrated titanium oxide having the general formula TiO.sub.(2-x)(OH).sub.2x, with 0<x≤1, (calculated as TiO.sub.2), and a silicon dioxide and hydrated precursors of the silicon dioxide (calculated as SiO.sub.2). A weight ratio of TiO.sub.2/SiO.sub.2, determined for TiO.sub.2 and SiO.sub.2 respectively, is at least 3 and less than 30. The wt.-% is based on a total weight of the catalyst material after the catalyst material has been dried at 105° C. for at least 2 hours. The powdered catalyst material has a specific surface area of >300 m.sup.2/g and an isoelectric point of from 4.0 to 7.0.
Porous carbon, and positive electrode and lithium secondary battery comprising same
Porous carbon particles, and a positive electrode active material and a lithium secondary battery including the same. This may improve the energy density of the lithium secondary battery by applying a porous electrode containing micropores and mesopores and having a uniform size distribution and shape as a positive electrode material.
Ceramic powder material, method for producing ceramic powder material, molded body, sintered body, and battery
A ceramic powder material containing a garnet-type compound containing Li, wherein the ceramic powder material has a pore volume of 0.4 mL/g or more and 1.0 mL/g or less.
Methods for sol-gel polymerization in absence of solvent and creation of tunable carbon structure from same
The present application is directed to methods for solvent-free preparation of polymers and their subsequent processing into activated carbon materials. These methods unexpectedly demonstrate ability to tune pore structure in the polymer gel and carbon produced there from, while also providing distinct advantages over the current art.