A method for treating wastewater, comprising: (i) injecting a hydrate-forming gas (e.g., propane) into the wastewater under conditions of elevated pressure and reduced temperature to form a solid hydrate composed of the hydrate-forming gas and water from the wastewater; and (ii) separating the solid hydrate from the wastewater to result in removal of water from the wastewater, thereby resulting in partially dewatered wastewater, and optionally, (iii) lowering the pressure and/or raising the temperature of the solid hydrate to decompose the solid hydrate into reformed hydrate-forming gas and reformed water, and further optionally, recycling the reformed hydrate-forming gas for use in step (i) and/or capturing the reformed water from step (iii) and further decontaminating until suitable for release into waterway or for use in a process. The invention is also directed to an apparatus for practicing the method described above.

A pond for cooling and/or recovering salt from a hot aqueous solution of a salt such as potassium chloride produced by solution mining. The pond comprises a plurality of channels arranged side-by-side, each of the channels being defined by a plurality of sides. An inlet is provided in a side of a channel for receiving the aqueous solution, and an outlet is provided in a side of another one of the channels for discharging the aqueous solution. The pond has at least one dike separating the channels from one another. A gap is formed in each dike to permit the aqueous solution to flow between the channels, the gap having a length which is about 10 to about 40 percent of the length of the sides of the channels. Salt is crystallized and the solution is cooled as it passes through the channels of the pond.

A method of activating and dewatering sludge through application of acoustic pressure shock waves to wastewater.

A method of activating and dewatering sludge through application of acoustic pressure shock waves to wastewater.

A hydrate production apparatus according to the present invention comprises: a main body unit having a reaction space in which a hydrate is produced therein; an inlet pipe unit connected to one side of the main body unit so as to introduce, into the reaction space, a host material and a guest material for producing the hydrate; an outlet pipe unit connected to the other side of the main body unit so as to discharge the hydrate produced in the reaction space to the outside; and a pulverizing device unit provided inside the reaction space so as to increase a reaction area for producing the hydrate by pulverizing, into fine-sized particles, an object to be pulverized, which is at least one of the introduced host material and guest material.

A hydrate production apparatus according to the present invention comprises: a main body unit having a reaction space in which a hydrate is produced therein; an inlet pipe unit connected to one side of the main body unit so as to introduce, into the reaction space, a host material and a guest material for producing the hydrate; an outlet pipe unit connected to the other side of the main body unit so as to discharge the hydrate produced in the reaction space to the outside; and a pulverizing device unit provided inside the reaction space so as to increase a reaction area for producing the hydrate by pulverizing, into fine-sized particles, an object to be pulverized, which is at least one of the introduced host material and guest material.

The present invention is a process, a method, and system for recovery and concentration of dissolved ammonium bicarbonate from a wastewater containing ammonia (NH3) using gas separation, condensation, and crystallization, each at controlled operating temperatures. The present invention includes 1) removal of ammonia from waste (sludges, semi-solids, and solids and liquids) without the use of chemicals at a temperature of at least 80 degrees Celsius, 2) condensing the gaseous containing ammonia, carbon dioxide and water vapor to remove water vapor concentrating the amount of gaseous ammonia and carbon dioxide, 3) concentrating the ammonia and carbon dioxide in the water by established means, such as concentrating the gas using partial condensation followed by passing the concentrated gas through an absorption column at a temperature of between about 20 and 50 degrees Celsius to form dissolved ammonium carbonate and ammonium bicarbonate, or total condensation followed by dewatering using reverse osmosis, and 4) crystallizing concentrated dissolved ammonium carbonate and ammonium bicarbonate at a temperature of less than about 35 degrees Celsius to form solid ammonium bicarbonate and ammonium carbonate.

A non-chemical apparatus and method to lower the surface tension of a solution of liquid water and gaseous oxygen. An apparatus of the present invention comprises a source of chilled purified water, and gaseous oxygen fed into a positive displacement pump, followed by a cylinder reduced at one end by means of a convergent cone, a section of a smaller diameter cylinder attached to a divergent cone tapering up to another cylinder of a diameter the same or larger than the original cylinder. A coil of refrigeration tubing is wrapped around the smaller center cylinder to control the temperature of the inner cylinder surface.

A non-chemical apparatus and method to lower the surface tension of a solution of liquid water and gaseous oxygen. An apparatus of the present invention comprises a source of chilled purified water, and gaseous oxygen fed into a positive displacement pump, followed by a cylinder reduced at one end by means of a convergent cone, a section of a smaller diameter cylinder attached to a divergent cone tapering up to another cylinder of a diameter the same or larger than the original cylinder. A coil of refrigeration tubing is wrapped around the smaller center cylinder to control the temperature of the inner cylinder surface.

A system for separating a soluble solution includes a first freezer configured to receive a liquid feed stream and a refrigerant stream, and discharge a concentrated solution stream, wherein the first freezer is configured to exchange heat between the liquid feed stream and the refrigerant stream through direct contact within the first freezer and freeze a portion of the liquid feed stream, a first separator external to the first freezer and configured to separate ice particles from the concentrated solution stream and recirculate the concentrated solution stream to the first freezer, and a first ice washer coupled to the first separator and configured to receive the ice particles separated from the concentrated solution stream by the first separator and wash the separated ice particles to free the ice particles from contaminants.