A method of removing barium, calcium, strontium, and magnesium from frac flowback. A sulfate reagent and carbonate reagent are mixed with the frac flowback, causing barium, calcium, strontium, and magnesium to precipitate. The precipitants are crystallized and the resulting frac flowback and crystals are separated into relatively heavy solids and a stream of relatively light solids. The stream of relatively light solids is subjected to a further separation process that produces sludge that is recycled to aid in the crystallization process and a treated effluent which is recycled to the fracking operation or collected and used in another fracking operation.

A disclosed subsea sediment separation and filtration system includes first and second separation devices, a spreader apparatus, and a storage device. The first separation device receives a water/sediment/oil mixture and from a subsea surface and separates the mixture into a first component containing cleaned sediment and a second component containing a water/oil mixture. The spreader apparatus disperses the cleaned sediment of the first component into a subsea environment of the spreader apparatus. The second separation device receives the second component from the first separation device and separates the second component into a cleaned water component and an oil component. The second separation device disperses the cleaned water component into a subsea environment of the second separation device and provides the oil component to the storage device. The first separation device may include a plurality of hydrocyclone devices, and the second separation device may include a high pressure hydrocyclone device.

A disclosed subsea sediment separation and filtration system includes first and second separation devices, a spreader apparatus, and a storage device. The first separation device receives a water/sediment/oil mixture and from a subsea surface and separates the mixture into a first component containing cleaned sediment and a second component containing a water/oil mixture. The spreader apparatus disperses the cleaned sediment of the first component into a subsea environment of the spreader apparatus. The second separation device receives the second component from the first separation device and separates the second component into a cleaned water component and an oil component. The second separation device disperses the cleaned water component into a subsea environment of the second separation device and provides the oil component to the storage device. The first separation device may include a plurality of hydrocyclone devices, and the second separation device may include a high pressure hydrocyclone device.

A SCWO reactor fouling prevention and mitigation system that includes at least one feedstock tee which provides a feedstock to the SCWO reactor, at least one feedstock tee pressure sensor, such that each of the at least one feedstock tee has one of the at least one feedstock tee pressure sensor, at least one pressure sensor proximate a SCWO reactor inlet, and at least one pressure sensor proximate a SCWO reactor outlet. Also included is a controller which triggers a Clean In Place (CIP) procedure when there is a pressure difference between any two of the following, the SCWO reactor inlet, the at least one feedstock tee, and the SCWO reactor outlet. The CIP procedure includes washing a portion of the SCWO reactor with a fluid supplied through the at least one feedstock tee.

A processing method for perennially and deeply polluted sludge containing oils and water, waste residues, or oil sands in natural oil mines, and a processing system thereof. In the method, a solid substance containing oils and water is in full contact with an organic liquid solvent with a low boiling point and a weak polarity or no polarity at room temperature under pressurized condition to extract oil and water from the solid substance to the liquid, the organic solvent with low boiling point and low latent heat is easily separated from oil and water in the liquid after solid-liquid separation by decompression or heating evaporation, the gas solvent is compressed and condensed for recycling, the extracted oil and water are subjected to oil-water separation, and the extracted oil may be used as fuel or used for refining.

The invention relates to a method of circular use of waste brine produced in the manufacture process of MDI, comprising the following steps: (1) the waste brine produced in the manufacture process of MDI is subjected to a high-gravity extraction and then to a column extraction, wherein said waste brine contains aniline, diaminodiphenylmethane and polyamine; (2) the waste brine from step (1) is transmitted to a stripping tower for steam stripping; (3) the waste brine from the stripping tower of step (2) and a chemical oxidant are transmitted to an oxidation reactor to which air is blown for aeration; (4) the waste brine after the treatment of step (3) is transmitted to an absorption tower for absorption. The invention makes the salt water have TOC of less than 8 ppm and TN of less than 2.5 ppm and achieves regeneration of resources in the waste brine such as sodium chloride and water and the like for circular use.

Chlorosilane-containing process streams are treated by vaporizing the process stream, contacting the vaporized process stream with an alkaline medium in a scrubber, the scrubbing liquid being maintained at a pH of 9-13 by introduction of alkaline medium, and feeding the scrubbing medium to a waste treatment plant containing at least one mixing tank in which the pH is adjusted to the range of 7-9 by addition of mineral acid, separating solids by means of a centrifuge, and isolating separated solids.

Chlorosilane-containing process streams are treated by vaporizing the process stream, contacting the vaporized process stream with an alkaline medium in a scrubber, the scrubbing liquid being maintained at a pH of 9-13 by introduction of alkaline medium, and feeding the scrubbing medium to a waste treatment plant containing at least one mixing tank in which the pH is adjusted to the range of 7-9 by addition of mineral acid, separating solids by means of a centrifuge, and isolating separated solids.

The present invention generally relates to a novel process in which thin stillage is processed to produce algae oil and protein rich biomass as well as other energy rich byproducts. In accordance with a preferred embodiment, thin stillage is removed from an evaporator during the evaporation process to produce mid-stillage. This mid-stillage is preferably routed to a new process where it is directed to a pre-treatment centrifuge to remove suspended solids, sludge and corn oil. Thereafter, the mid-stillage is preferably cooled and then directed to a fermentation tank where the mid-stillage is subject to a batch fermentation process with algae “seed” fed from an algae inoculation system. Once the batch is harvested, the oil-rich algae/mid-stillage is then preferably heated to rupture the cells and liberate the oil. Thereafter, the oil-rich algae/mid-stillage is preferably processed by a centrifuge which produces solids, a light phase oil and a “clean” mid-stillage stream that can be evaporated to a very high level of solids.

The present invention generally relates to a novel process in which thin stillage is processed to produce algae oil and protein rich biomass as well as other energy rich byproducts. In accordance with a preferred embodiment, thin stillage is removed from an evaporator during the evaporation process to produce mid-stillage. This mid-stillage is preferably routed to a new process where it is directed to a pre-treatment centrifuge to remove suspended solids, sludge and corn oil. Thereafter, the mid-stillage is preferably cooled and then directed to a fermentation tank where the mid-stillage is subject to a batch fermentation process with algae “seed” fed from an algae inoculation system. Once the batch is harvested, the oil-rich algae/mid-stillage is then preferably heated to rupture the cells and liberate the oil. Thereafter, the oil-rich algae/mid-stillage is preferably processed by a centrifuge which produces solids, a light phase oil and a “clean” mid-stillage stream that can be evaporated to a very high level of solids.