The present invention relates to an apparatus and method for bio-assisted treatment of spent caustic obtained from hydrocarbon and gas processing installations. The present invention also relates to method for recovery of caustic and recovery of sulfur from spent caustic. According to present invention, the sulfide removal is about 96% and the sulphur formation and deposition on the electrode lies in range of 72±8%.

The present invention relates to an apparatus and method for bio-assisted treatment of spent caustic obtained from hydrocarbon and gas processing installations. The present invention also relates to method for recovery of caustic and recovery of sulfur from spent caustic. According to present invention, the sulfide removal is about 96% and the sulphur formation and deposition on the electrode lies in range of 72±8%.

A system for treating printed circuit board wastewater (PCB) includes a production system, a pretreatment system, a biochemical system, a recovery system and a concentrated water treatment system. The production system is configured for producing process water and auxiliary water from tap water. The pretreatment system is configured to pretreat different wastewater samples separately. The biochemical system is configured to decompose the pretreated wastewater. The recovery system is configured to treat wastewater from the pretreatment system and the biochemical system to obtain process water and feed concentrated water to the concentrated water treatment system. The concentrated water treatment system is configured to treat the concentrated water to meet a discharge standard. A treatment method for the PCB wastewater is also provided.

In accordance with the present invention there is provided a method for treating a wastewater stream, comprising the steps of:—introducing O.sub.3 in the wastewater stream, thereby dissolving at least part of the O.sub.3 in the wastewater stream;—optionally irradiating the wastewater stream with ionizing radiation; and—optionally contacting the wastewater stream with a heterogeneous catalyst. In case the ozone treatment is combined with a heterogeneous catalyst, the wastewater treatment can be more effective than with ozone treatment alone, depending on the type of impurities in the wastewater stream. The type of heterogeneous catalyst can be chosen depending on the source of the wastewater and the specific pollutants associated with such wastewater sources. Advantageously, the ozone required for this process can be generated by electrolysis of water. In the current energy market, hydrogen (H.sub.2), which is also produced during electrolysis of water, is becoming increasingly important as a fuel, and therefore, increasing amounts of hydrogen are being produced, preferably using electricity generated using renewable resources. Therefore, oxygen (O.sub.2) and ozone (O.sub.3), which are produced alongside hydrogen during water electrolysis, and which are currently often discarded as an invaluable byproduct, can instead be used for wastewater treatment. Therefore, according to another aspect of the invention, there is also provided the use of O.sub.2 and/or O.sub.3 obtained by electrolysis of water for wastewater treatment.

In accordance with the present invention there is provided a method for treating a wastewater stream, comprising the steps of:—introducing O.sub.3 in the wastewater stream, thereby dissolving at least part of the O.sub.3 in the wastewater stream;—optionally irradiating the wastewater stream with ionizing radiation; and—optionally contacting the wastewater stream with a heterogeneous catalyst. In case the ozone treatment is combined with a heterogeneous catalyst, the wastewater treatment can be more effective than with ozone treatment alone, depending on the type of impurities in the wastewater stream. The type of heterogeneous catalyst can be chosen depending on the source of the wastewater and the specific pollutants associated with such wastewater sources. Advantageously, the ozone required for this process can be generated by electrolysis of water. In the current energy market, hydrogen (H.sub.2), which is also produced during electrolysis of water, is becoming increasingly important as a fuel, and therefore, increasing amounts of hydrogen are being produced, preferably using electricity generated using renewable resources. Therefore, oxygen (O.sub.2) and ozone (O.sub.3), which are produced alongside hydrogen during water electrolysis, and which are currently often discarded as an invaluable byproduct, can instead be used for wastewater treatment. Therefore, according to another aspect of the invention, there is also provided the use of O.sub.2 and/or O.sub.3 obtained by electrolysis of water for wastewater treatment.

These is provided a process and a system for treating a livestock waste and produce fertilizers. The process can include subjecting a livestock waste to a preparation treatment to produce a stabilized livestock waste, the preparation treatment including aerating the livestock waste with an oxygen-containing gas. The process can further include subjecting the stabilized livestock waste to a bioreaction treatment to produce an aerated livestock product. The bioreaction treatment can include aerating the stabilized livestock waste with an oxygen-containing gas that can be supplied by a distribution system to enable aerobic reactions to occur within the stabilized livestock waste. The aerated livestock product can include a solid component and a liquid component, and can be further separated in a solid-liquid separation treatment to produce respective fertilizers, or be used as is as a fertilizer.

A continuous flow granular/flocculent sludge wastewater process selects for granule biomass capable of nitrogen and phosphorus removal and controls granule size and concentration of granular and flocculent sludge for optimal nutrient, organic, and solids removal in a smaller footprint. A series of biological process zones lead to a secondary clarifier. Mixed liquor sludge, preferably from an aerobic zone, goes through a classifier or separator processing flow from the aerobic zone, to the secondary clarifier. In a sidestream process that can be included a portion of sludge preferably from an aerobic zone goes through a classifier or separator to selectively produce a granular-rich effluent, and the clarifier may also have a separator to further concentrate granular biomass, most of which is cycled back to an initial multi-stage anaerobic process zone. The anaerobic zone is structured and operated to encourage growth of granules in subsequent process zones.

A continuous flow granular/flocculent sludge wastewater process selects for granule biomass capable of nitrogen and phosphorus removal and controls granule size and concentration of granular and flocculent sludge for optimal nutrient, organic, and solids removal in a smaller footprint. A series of biological process zones lead to a secondary clarifier. Mixed liquor sludge, preferably from an aerobic zone, goes through a classifier or separator processing flow from the aerobic zone, to the secondary clarifier. In a sidestream process that can be included a portion of sludge preferably from an aerobic zone goes through a classifier or separator to selectively produce a granular-rich effluent, and the clarifier may also have a separator to further concentrate granular biomass, most of which is cycled back to an initial multi-stage anaerobic process zone. The anaerobic zone is structured and operated to encourage growth of granules in subsequent process zones.

The present invention provides a process for the treatment of sewage sludge with enzymes, which process comprises treating a sewage sludge resulting from the treatment of municipal or industrial waste water with a composition comprising a fermentation supernatant product from a Saccharomyces cerevisiae culture and a non-ionic surfactant, wherein said fermentation supernatant product is free of active enzymes, at conditions suitable for generating said active enzymes from said sewage sludge in situ.

The present invention provides a process for the treatment of sewage sludge with enzymes, which process comprises treating a sewage sludge resulting from the treatment of municipal or industrial waste water with a composition comprising a fermentation supernatant product from a Saccharomyces cerevisiae culture and a non-ionic surfactant, wherein said fermentation supernatant product is free of active enzymes, at conditions suitable for generating said active enzymes from said sewage sludge in situ.