The present invention is directed to a ligated metal-organic framework (MOF) for use in removing both anionic and cationic species from a liquid or liquid stream. The present invention also provides methods for placing the MOF on a substrate to form a MOF-containing product that can be used in the removal of certain species from a given fluid. The MOF may be a Zr-based MOF, such as NU-1000, for removal of certain anions, such as oxy-anions, or having an attached thiosulfonyl-thiol (—SO.sub.2—S—R.sub.2—SH, where R.sub.2 is an alkyl group) ligand for complexation with certain cationic species in addition to the anions. The substrate may be any substrate to which a given MOF may be attached, including inert polypropylene polymer resin beads, a macroscopic fabric such as a mesh material or mesh filter, and a molecular fabric.

A treatment process for preparing a remediated liquid from a contaminated liquid originally containing more than 5 ppm hydrogen sulfide (H.sub.2S) and substantially without formation of precipitate, includes steps of steps of adding an aqueous solution containing at least one hydroxide compound at a collective concentration of 35-55 wt % to the contaminated liquid to achieve a concentration of 125-5000 ppm of the hydroxide compounds in the contaminated liquid, adding a fulvic acid and/or a humic acid to the contaminated liquid to achieve a concentration of 0.01-10 ppm of the acid(s) in the contaminated liquid, and dispersing the aqueous solution and the at least one organic acid in the contaminated liquid and allowing the aqueous solution and the at least one organic acid to react with the contaminated liquid for a period of time until a concentration of hydrogen sulfide in the contaminated liquid is reduced to ≤5 ppm.

The invention relates to a process for treating a waste lye of a lye scrub using an oxidation reactor (100), the waste lye and oxygen or an oxygen-containing gas mixture being introduced into the oxidation reactor (100) and steam being introduced into the oxidation reactor (100). It is provided that the steam is at least partially introduced by means of a steam feeding device (10), which has a cylindrical section (11) with a centre axis (12) and a wall (13), the centre axis (12) being aligned perpendicularly, a number of groups of openings (14) being formed in the wall, each of the groups comprising a number of the openings (14), and the number of openings (14) of each of the groups being arranged in one or more planes (15) that is or are in each case aligned perpendicularly to the centre axis (12). A corresponding installation and also a corresponding oxidation reactor (100) are likewise the subject of the present invention.

In one embodiment, a system includes first anoxic moving bed biofilm reactor (MBBR) configured to receive a fluid containing selenium and to process the fluid via a first biofilm disposed on a first media to produce a first MBBR fluid by removing nitrogen from the fluid. The system further includes a second anoxic MBBR fluidly coupled to the first MBBR to receive the first MBBR fluid and to process the first MBBR fluid via a second biofilm disposed on a second media to produce a selenium enriched fluid, followed by a solid-liquid separation system to remove selenium in solid form as sludge and produce a treated effluent containing equal to or less than 5 micrograms of selenium per liter. The system includes a plurality of first sensors and first actuators disposed on the first MBBR, and a plurality of second sensors and second actuators disposed on the second MBBR.

The combined acid gas removal and water filtration system (10) removes sour gases, such as hydrogen sulfide (H2S) and carbon dioxide (CO2), from an input gaseous hydrocarbon stream (FG), as well as producing purified water (TW). The acid gas removal system (10) has a contactor (12) for contacting the input gaseous stream (FG) with an absorption liquid solvent (ALS), and a stripper (24) for recycling the absorption liquid solvent (ALS) and removing acidic gases (AG) therefrom. A first heat exchanger (22) heats used absorption liquid solvent (UALS) output from the contactor (12) prior to injection into the stripper (24). A second heat exchanger (26) cools recycled absorption liquid solvent (RALS) using a refrigerant (R) before injection back into the contactor (12). The refrigerant (R) is coupled with an absorber (84), which receives a dilute ethanolic draw solution (DDS) from a forward osmosis filtration system (72), producing purified water (TW).

Provided herein are methods of removing carbon dioxide from an aqueous stream or gaseous stream by: contacting the gaseous stream comprising carbon dioxide, when present, with an aqueous solution comprising ions capable of forming an insoluble carbonate salt; contacting the aqueous solution comprising carbon dioxide with an electroactive mesh that induces its alkalinization thereby forcing the precipitation of a carbonate solid from the solution and thereby the removal of dissolved inorganic carbon by electrolysis; and removing the precipitated carbonate solids from the solution, or the surface of the mesh where they may deposit. Also provided herein are flow-through electrolytic reactors comprising an intake device in fluid connection with a rotating cylinder comprising an electroactive mesh, and a scraping device and/or liquid-spray based device for separating a solid from the mesh surface.

Shippable modular units configured for use in sequestering CO.sub.2 are provided. Aspects of the units include a support having one or more of: a CO.sub.2 gas/liquid contactor subunit, a carbonate production subunit and an alkali enrichment subunit; associated therewith. Also provided are systems made up of one or more such modular units, and methods for using the units/systems in CO.sub.2 sequestration protocols.

A system includes: an intake tube operably connected to a power plant, the intake tube configured to transport exhaust from the power plant; a drill configured to create a hole in the side of the plant usable to receive exhaust generated by the plant, the drill configured to remain in place and function as the intake tube, the system further comprising a cooling tube operably connected to the intake tube, the cooling tube configured to receive the exhaust from the intake tube; a U-shaped tube operably connected to the cooling tube, the U-shaped tube comprising a mister configured to generate a mist; and a vacuum tube fan operably connected to the U-shaped tube, the mister configured to cause the cooled exhaust and the heated liquid to bond so as to create a sludge, the sludge falling to a bottom of the system, the sludge being removed from the system.

A method and device for removing chloride ions in desulfurized wastewater by electrochemical coupling in which the device comprises: an electrolyte tank having a top and a bottom wherein the tank is used as a separator in a separation process and as an electrode regenerator in an electrode regeneration process; two electrodes comprising a hydrogen evolution electrocatalysis function electrode and an electrochemically switched ion exchange (ESIX) function electrode respectively, wherein the electrodes are connected with each other by a wire; two DC circuits having opposite electric field directions and used alternately in the separation process and the electrode regeneration process respectively; the bottom of the electrolyte tank is provided with a purified high-concentration chloride ion wastewater inlet and a flocculation product outlet; the top of the tank is provided with a dechlorination treatment water outlet and a hydrogen collecting port; and, in the electrode regeneration process, the electrolyte tank is connected to an electrode regeneration liquid storage tank through a pump and a pipeline.

A novel process for treatment of low quality or brackish water that allows increased recovery of high quality water, recovers commodity minerals and reduces the volume of water and mass of solids that are disposed from the process.