Shippable modular units configured for use in sequestering CO.sub.2 are provided. Aspects of the units include a support having one or more of: a CO.sub.2 gas/liquid contactor subunit, a carbonate production subunit and an alkali enrichment subunit; associated therewith. Also provided are systems made up of one or more such modular units, and methods for using the units/systems in CO.sub.2 sequestration protocols.

The present invention is directed to a ligated metal-organic framework (MOF) for use in removing both anionic and cationic species from a liquid or liquid stream. The present invention also provides methods for placing the MOF on a substrate to form a MOF-containing product that can be used in the removal of certain species from a given fluid. The MOF may be a Zr-based MOF, such as NU-1000, for removal of certain anions, such as oxy-anions, or having an attached thiosulfonyl-thiol (—SO.sub.2—S—R.sub.2—SH, where R.sub.2 is an alkyl group) ligand for complexation with certain cationic species in addition to the anions. The substrate may be any substrate to which a given MOF may be attached, including inert polypropylene polymer resin beads, a macroscopic fabric such as a mesh material or mesh filter, and a molecular fabric.

A waste water processing system includes an upflow contacting column having a flue gas input for receiving flue gas having a temperature of at least 500 degrees F., a waste water input, and a flue gas output. The waste water input is coupled to a fluid injector, e.g., atomizing nozzles, positioned in the throat of a Venturi portion of the upflow contacting column or in a sidewall of the throat of the Venturi portion of the upflow contacting column. The flue gas in the upflow contacting column has a high velocity, e.g., a gas velocity exceeding 65 fps in the throat of the Venturi portion of the upflow contacting column at a position where the fluid injector is located. Drying additives such as recycled ash, lime, and/or cement may be, and sometimes are, input into the upflow contacting column downstream of the waste water input.

A process for removing hydrogen sulfide from sour water is provided. The process comprises obtaining sour water; adjusting the pH of the sour water to a pH of less than about 6 by addition of a first acid to form acidified sour water; sparging the acidified sour water with a first hydrocarbon gas in a first vessel to produce a first sour gas and a sweetened water; and separating the first sour gas from the sweetened water.

Methods and systems for sequestering carbon dioxide and growing algae can include: producing fluids from a subsurface formation; separating the fluids into hydrocarbons and produced water; transferring the produced water to a treatment pond; transferring the hydrocarbons to a gas fractionation plant; separating the hydrocarbons resulting in a carbon dioxide side stream; and discharging the carbon dioxide side stream into the treatment pond.

A method and system are provided to recover water and carbon dioxide from combustion emissions. The recovery includes, among other things, electrolysis and carbon dioxide capture in a suitable solvent. The recovered water and carbon dioxide are subject to reaction, such as a catalytic methanation reaction, to generate at least methane.

A waste water processing system includes an upflow contacting column having a flue gas input for receiving flue gas having a temperature of at least 500 degrees F., a waste water input, and a flue gas output. The waste water input is coupled to a fluid injector, e.g., atomizing nozzles, positioned in the throat of a Venturi portion of the upflow contacting column or in a sidewall of the throat of the Venturi portion of the upflow contacting column. The flue gas in the upflow contacting column has a high velocity, e.g., a gas velocity exceeding 65 fps in the throat of the Venturi portion of the upflow contacting column at a position where the fluid injector is located. Drying additives such as recycled ash, lime, and/or cement may be, and sometimes are, input into the upflow contacting column downstream of the waste water input.

An efficient, cost-effective, and efficacious technique for removing coal ash and other pollutants from waterways, ponds, marshes, holding tanks and other water sources and supplies. An apparatus comprising an open cage including electromagnets and/or permanent magnets and/or electrodes is supplied with electrical power to extract materials such as rare earth elements and/or heavy metals. The materials levitate to the surface, forming a slurry while leaving water substantially free of such materials. Rare earth magnets electrically connect electrolysis electrode structures and serve as electrolysis electrode segments.

A system includes: an intake tube operably connected to a power plant, the intake tube configured to transport exhaust from the power plant; a drill configured to create a hole in the side of the plant usable to receive exhaust generated by the plant, the drill configured to remain in place and function as the intake tube, the system further comprising a cooling tube operably connected to the intake tube, the cooling tube configured to receive the exhaust from the intake tube; a U-shaped tube operably connected to the cooling tube, the U-shaped tube comprising a mister configured to generate a mist; and a vacuum tube fan operably connected to the U-shaped tube, the mister configured to cause the cooled exhaust and the heated liquid to bond so as to create a sludge, the sludge falling to a bottom of the system, the sludge being removed from the system.

A method of recovering ammonia bicarbonate from a biogas and digestate liquor uses an arrangement of equipment in an operational arrangement that requires relatively modest capital investment and that operates with simplicity to provide solid ammonia bicarbonate. In a specific form the method achieves this by upgrading of biogas to produce a rejected stream having a high mole fraction of CO.sub.2 at an elevated pressure that eliminates the need for further compression when using the CO.sub.2 for recovery of ammonia bicarbonate. The method operates can operate at a high pH produced inherently in a digestate stripper by concurrently stripping dissolved CO.sub.2 from solution to improve the simplicity of solid AB recovery.