Methods for treating phosphogypsum-containing water are disclosed. The water may be treated so as to promote precipitation of one or more target constituents and to facilitate downstream membrane treatment. A coagulant may be added to promote phosphate recovery. Related systems are also disclosed.

This invention describes a novel recovery method of ammonia through the electrocoagulation process, which may be applied in the industrial as well as the environmental sectors. The present invention has a significant impact not only on recovering the ammonia content from the Solvay effluent, but also for recovering the ammonia from landfill leachate and different sources of wastewater where high concentrations of ammonia can be found. This invention has economic benefits in recovering ammonia and reducing the required energy in such processes. Another impact is the environmental one, where ammonia can cause problems such as toxicity to the organisms living in the soil or water bodies, and could also decrease the concentration of the dissolved oxygen.

A slag discharge system includes a slag bath at a bottom portion of a gasifier; a slag cooling water circulation line that discharges a mixture of slag and a slag cooling water from the slag bath; a coarse slag separator device that separates coarse slag contained in the slag cooling water; a fine slag separator device connected to the coarse slag separator device downstream side, the fine slag separator device separating fine slag; and a circulator pump connected to the fine slag separator device downstream side, the circulator pump creating a water flow in the slag cooling water circulation line; wherein the fine slag separator device includes a branch section where the slag cooling water circulation line branches into a plurality of branch lines and again joins together as one line, a fine slag filter portion, and a shutoff valve and disposed in each of the plurality of branch lines.

The present invention is directed to a ligated metal-organic framework (MOF) for use in removing both anionic and cationic species from a liquid or liquid stream. The present invention also provides methods for placing the MOF on a substrate to form a MOF-containing product that can be used in the removal of certain species from a given fluid. The MOF may be a Zr-based MOF, such as NU-1000, for removal of certain anions, such as oxy-anions, or having an attached thiosulfonyl-thiol (—SO.sub.2—S—R.sub.2—SH, where R.sub.2 is an alkyl group) ligand for complexation with certain cationic species in addition to the anions. The substrate may be any substrate to which a given MOF may be attached, including inert polypropylene polymer resin beads, a macroscopic fabric such as a mesh material or mesh filter, and a molecular fabric.

Provided is a method for providing an integrated system for water treatment energized by sustainable hydrogen, including the steps of: generating electrical power from at least two renewable power producing systems, wherein the renewable power producing systems comprise at least a solar photovoltaic cell and a wind turbine; converting the electrical power with a controller in electrical communication with the two renewable power producing systems and a power bus to power an electrolyzer.

Use of poly(alkylamine)-derived (PAD) cross-linked polymeric ammonium salts and ionomer hydrogels for adsorbing and desorbing organic contaminants, specifically per and polyfluoro alkyl substances (PFAS) from water.

Disclosed herein are a method for treating a water stream in a zero liquid discharge (ZLD) system and a ZLD system. The method includes contacting the water stream with a metal agent that reduces a nitrate contained therein to a nitrite, and introducing an amide into the water stream that reduces the nitrite to nitrogen to provide a treated water stream having a reduced nitrate concentration. The ZLD system includes a mix tank, an amide tank including an amide, and a crystallizer. The mix tank includes an inlet for receiving a water stream within the mix tank, and a container including a metal agent. The container is designed to allow the water stream to contact the metal agent. The amide tank is designed to direct the amide into the water stream, and the crystallizer is designed to receive the water stream from the mix tank.

Methods for processing pretreated phosphogypsum wastewater are disclosed. The pretreated wastewater may be subjected to electrodialysis involving at least one monovalent cation selective membrane. Further downstream membrane treatment may be applied. Upstream precipitation and air-stripping techniques may optionally also be employed. Related systems are also disclosed.

The present application relates to a method for removing a contaminant from wastewater from industrial fertilizer plant. The method comprises the steps of concentrating the wastewater, of electrolyzing the wastewater and of recirculating the electrolyzed wastewater to the fertilizer plant. The present application further relates to a system arranged to perform the method according to the present application.

A nano zero valent iron biological coupling device for organic wastewater includes a continuous flow stirred reactor, a flocculation sedimentation device and a membrane bioreactor arranged in series. A nano zero valent iron feeding device is arranged in the continuous flow stirred reactor, a flocculant and a coagulant aid are arranged in the flocculation sedimentation device, and a microbial reaction liquid is arranged in the membrane bioreactor. A nano iron biological coupling process includes: S1, placing the organic wastewater in the continuous flow stirred reactor, adding the nano zero valent iron, stirring and mixing; S2, placing the organic wastewater treated after S1 in the flocculation sedimentation device; S3, placing the organic wastewater treated after S2 in the membrane bioreactor and interacting with the microbial reaction liquid; S4, performing a membrane separation on the organic wastewater treated after S3 in the membrane bioreactor to obtain purified organic wastewater.