A photocatalytic reaction unit for removing dissolved metals from a wastewater stream, including a photocatalytic reaction vessel having an inlet and an outlet for providing passage of the wastewater stream into and out of the photocatalytic reaction vessel; a photocatalyst for mixing with the wastewater stream; and an ultraviolet light source for emitting ultraviolet light into the photocatalytic reaction vessel.

The invention discloses a method for degrading phenol in industrial wastewater by a dual-frequency composite ultrasound, which belongs to the technical field of phenol degradation. The method adopts the dual-frequency composite ultrasound to perform ultrasonic treatment to a phenol solution to be degraded for 10-30 minutes. Degradation rate of phenol by the dual-frequency composite ultrasound can reach 83.74%, which is 45.23% and 51.11% higher than the degradation rates of a probe-type ultrasound alone and a tank-type ultrasound alone. Therefore, it can be clearly seen that the degradation effect of dual-frequency composite ultrasonic synergistic degradation of phenol in water is ideal.

Methods and systems are provided for industrial wastewater treatment that yields zero liquid discharge (ZLD). These include pre-treating provided industrial wastewater to remove heavy metals, ultra-filtering the pre-treated wastewater to remove suspended and colloidal solids, nano-filtering the ultra-filtered wastewater to yield treated water (with monovalent ions) and a concentrate, treating the concentrate to remove di- and tri-valent elements and other compounds from the concentrate, and to reduce a level of sulfates to a specified level which is above a solubility level of sulfatesto yield returned water, and sludge, mixing the returned water with the provided industrial wastewater before or at the first treatment stage and/or with the pre-treated wastewater before the ultrafiltration, and removing residual water from the sludge to yield removed solids with ZLD. Advantageously, disclosed processes and systems are efficient, cheaper and more sustainable than prior art systems.

A method including contacting a stream including water with a coated porous substrate including a porous substrate coated with a hydrophilic and oleophobic coating to produce a treated water including water that passes through the coated porous substrate; and utilizing at least a portion of the treated water as a component of a hydraulic fracturing fluid.

In a method for treating waste water containing ammonium salts, sodium sulfate crystal is obtained by freezing crystallization, then the pH value of the waste water is adjusted to a specific range, and next sodium chloride crystal and ammonia water is obtained by evaporation. Alternatively, the pH value of the waste water is adjusted to a specific range, then sodium chloride crystal and ammonia water is obtained by evaporation, and next sodium sulfate crystal is obtained by freezing crystallization. This method can recover ammonia, sodium sulfate, and sodium chloride from the waste water.

The invention in at least one embodiment includes a system for treating water having an intake module, a vortex module, a disk-pack module, and a motor module. In at least one embodiment, a water system includes vortex housing having an interior wall defining a vortex chamber in fluid communication with the expansion chamber of said disk-pack turbine and inlets into the vortex chamber, and the vortex chamber having an upper section with a bowl or modified concave hyperbolic shape into which fluid is received from said inlets and a lower section with a conical or funnel shape with a steep vertical angle of change that opens into expansion chamber. In at least one further embodiment, the disk-pack module includes a disk-pack turbine having a plurality of disks having at least one waveform present on at least one of the disks.

A method of producing treated ion exchange resin material includes exposing an enclosed vessel containing ion exchange resin and a pre-treatment solution to high energy radiation. The treated ion exchange resin material has reduced organic impurities or total organic carbon (TOC).

A nucleophilic substitution reaction to crosslink cyclodextrin (CD) polymer with rigid aromatic groups, providing a high surface area, mesoporous CD-containing polymers (P-CDPs). The P-CDPs can be used for removing organic contaminants from water. By encapsulating pollutants to form well-defined host-guest complexes with complementary selectivities to activated carbon (AC) sorbents. The P-CDPs can rapidly sequester pharmaceuticals, pesticides, and other organic micropollutants, achieving equilibrium binding capacity in seconds with adsorption rate constants 15-200 times greater than ACs and nonporous CD sorbents. The CD polymer can be regenerated several times, through a room temperature washing procedure, with no loss in performance.

A water treatment apparatus, system and method including introducing an aqueous fluid into a chamber, the aqueous fluid having a pH below 7 and having an oxidizing agent. Contacting, within the chamber, the aqueous fluid with a corrodible sacrificial material which oxidizes in the presence of the oxidizing agent also reducing the oxidizing agent. Thereafter, adjusting, subsequent contacting the corroding particulate, the pH of the aqueous fluid to above 7.

Disclosed herein is an electrostatic precipitation method using an electrostatic precipitator including a collection module having a collection electrode and a discharge electrode, a housing having an internal partition wall formed therein, an inlet-side passage switching member, and an outlet-side passage switching member. The electrostatic precipitation method includes collecting dust by applying a voltage to the discharge electrode while gas flows, closing some of the flow spaces, divided by the internal partition wall using the passage switching members, and performing dust collection for one of the opened flow spaces by applying a voltage to the discharge electrode therein, and performing washing for at least one of the closed flow spaces by supplying washing water to the collection electrode therein.