A novel class of compounds is described here. The disclosed novel compounds have one hydrophilic group and two identical hydrophilic ionic groups. The two hydrophilic groups of the disclosed compounds contain or end with a cationic or anionic charged group. The disclosed novel compounds herein can be used as surfactants in an article, product, or composition, or for some other purposes. A method to synthesize the disclosed novel compounds is also described.

A desalination system (100) having an intake unit (110) providing seawater to a pre-treatment unit (120) connected to a reverse osmosis (RO) desalination unit (130) and a post treatment unit (150). The desalination system (100) is configured to operate without any external addition of chemicals to simplify logistics and regulation concerns. The units of the system are configured to prevent biofouling, scaling and corrosion by mechanical and biological means including high flow speeds, biological flocculation of colloids, and making the water entering the RO units inhospitable to bacteria and other organisms that cause biofouling, hence preventing their settlement and removing them with the brine. Recovery rate is lowered and energy is recovered to increase the energetic efficiency and minerals that are added to the product water are taken from the brine.

A composition and method of inhibiting corrosion, white rust, and scale formation on components in a water system. The composition preferably comprises an amino-acid based polymer (most preferably a polyaspartic acid or a salt thereof), hydroxyphosphonoacetic acid, and a second phosphonic acid (preferably a phosphonocarboxylic acid), and does not require the use of regulated metals. The composition is effective even in the presence of biocides. A preferred method of inhibiting white rust comprises adding an amino-acid based polymer or hydroxyphosphonoacetic acid or both to the water system. A preferred method of inhibiting corrosion, white rust, and scale formation comprises adding an amino-acid based polymer, hydroxyphosphonoacetic acid, and a phosphonocarboxylic acid to the water system. Preferably the active concentrations are at least 3 ppm each of the amino-acid based polymer and hydroxyphosphonoacetic acid when added to a volume of water in the water system.

A composition and method of inhibiting corrosion and white rust on metal components in a water system. The composition preferably comprises an amino-acid based polymer (most preferably a polyaspartic acid or a salt thereof), hydroxyphosphonoacetic acid, and a second phosphonic acid (preferably a phosphonocarboxylic acid), and does not require the use of regulated metals. The composition is effective even in the presence of biocides. A preferred method of inhibiting white rust comprises adding an amino-acid based polymer or hydroxyphosphonoacetic acid or both to the water system. A preferred method of inhibiting corrosion or white rust comprises adding an amino-acid based polymer, hydroxyphosphonoacetic acid, and a phosphonocarboxylic acid to the water system. Preferably the active concentrations are at least 3 ppm each of the amino-acid based polymer and hydroxyphosphonoacetic acid when added to a volume of water in the water system.

The present disclosure provides a method for relieving a corrosive environment of a boiling water reactor, the method including a step of injecting hydrogen and a noble metal compound into water to be replenished into the reactor pressure vessel during a period of a generating operation of a boiling water nuclear power plant including the reactor pressure vessel. In the method, the hydrogen is injected into water to be supplied into the reactor pressure vessel, and the noble metal compound is injected into water in a line of the boiling water nuclear power plant in which a concentration of oxygen or hydrogen peroxide is stoichiometrically higher than the concentration of hydrogen at which hydrogen undergoes a chemical reaction to turn to water. Thus, when a noble metal is injected into a boiling water reactor, the noble metal can be restrained from adhering onto a pipe for an injection and other pipes, and thereby can increase the amount of the noble metal to be injected into a cooling water in a reactor pressure vessel.

The present invention relates to inhibition of high temperature naphthenic acid corrosion occurring in hydrocarbon processing units. The invention provides an effective novel non-polymeric and non-fouling additive for inhibiting high-temperature naphthenic acid corrosion, comprising an effective corrosion-inhibiting amount of a second phosphate ester wherein said second phosphate ester is obtained by reacting a first phosphate ester with an oxirane compound selected from the group consisting of butylene oxide, ethylene oxide, propylene oxide or any other oxirane compound or a combination thereof, preferably with butylene oxide, capably yielding said second phosphate ester, having a structure A or B, ##STR00001##
wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of moieties having 1 to 20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different, X is H, CH.sub.3 or C.sub.2H.sub.5; and n may vary from 1 to 20,
wherein said first phosphate ester is having a structure I or II, ##STR00002##
wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of moieties having 1 to 20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different, said first phosphate ester being obtained as a reaction product of reaction of an alcohol with a phosphorous pentaoxide.

This invention relates to compositions and methods for the at least partial dissolution, disruption and/or removal of deposits, such as scale and other deposits, from heat exchanger components. The heat exchanger components can include pressurized water reactor steam generators. The pressurized water reactor steam generators can be in a wet layup condition. The compositions include elemental metal and complexing agent selected from the group consisting of sequestering agent, chelating agent, dispersant, and mixtures thereof. The methods include introducing the compositions into the heat exchanger components.

A corrosion-resistant cover system, having a corrosion-resistant cover structured and configured to be arrangeable around an object having one or more metallic surfaces that are susceptible to corrosion. The corrosion-resistant cover is operable to provide increased corrosion resistance to the object by preventing contact between the one or more metallic surfaces and ambient conditions exterior to the corrosion-resistant cover.

A system and method for monitoring process water treated with a biocide is provided. The system includes a biocide feeding unit and a dissolved oxygen sensor. The dissolved oxygen sensor works in two modes, a biocide feeding mode and a background mode, and alerts an operator when the dissolved oxygen value indicates a fault in the system. A drop in dissolved oxygen during feeding can indicate faulty production of biocide or biocide degradation, both of which can lead to unwanted disinfection by-products.

A system for separating a soluble solution includes a first freezer configured to receive a liquid feed stream and a refrigerant stream, and discharge a concentrated solution stream, wherein the first freezer is configured to exchange heat between the liquid feed stream and the refrigerant stream through direct contact within the first freezer and freeze a portion of the liquid feed stream, a first separator external to the first freezer and configured to separate ice particles from the concentrated solution stream and recirculate the concentrated solution stream to the first freezer, and a first ice washer coupled to the first separator and configured to receive the ice particles separated from the concentrated solution stream by the first separator and wash the separated ice particles to free the ice particles from contaminants.