Reflective luminescent markings on a road or sign surface are formed by applying onto the surface a base material which is liquid in an initial state for application and sets or cures to form a solid layer after application where the base material contains a fine/medium filler material of glass ground from recycled materials in a rotary mill. Coarse material from the grinder is separated out and supplied as a separate material to be applied onto the surface of the layer of base material and fine ground glass. The base material is connected or impregnated with a luminescent material such as photo luminescent 2 4 6 trichlorophenyl in a binder such as polyurea.

Reflective luminescent markings on a road or sign surface are formed by applying onto the surface a base material which is liquid in an initial state for application and sets or cures to form a solid layer after application where the base material contains a fine/medium filler material of glass ground from recycled materials in a rotary mill. Coarse material from the grinder is separated out and supplied as a separate material to be applied onto the surface of the layer of base material and fine ground glass. The base material is connected or impregnated with a luminescent material such as photo luminescent 2 4 6 trichlorophenyl in a binder such as polyurea.

A glass-ceramic article comprises a petalite crystalline phase and a lithium silicate crystalline phase. The weight percentage of each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article are greater than each of the weight percentages of other crystalline phases present in the glass-ceramic article. The glass-ceramic article has a transmittance color coordinate in the CIELAB color space of: L*=from 20 to 90; a*=from 20 to 40; and b*=from 60 to 60 for a CIE illuminant F02 under SCI UVC conditions. In some embodiments, the colorant is selected from the group consisting of TiO.sub.2, Fe.sub.2O.sub.3, NiO, Co.sub.3O.sub.4, MnO.sub.2, Cr.sub.2O.sub.3, CuO, Au, Ag, and V.sub.2O.sub.5.

A glass-ceramic article comprises a petalite crystalline phase and a lithium silicate crystalline phase. The weight percentage of each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article are greater than each of the weight percentages of other crystalline phases present in the glass-ceramic article. The glass-ceramic article has a transmittance color coordinate in the CIELAB color space of: L*=from 20 to 90; a*=from 20 to 40; and b*=from 60 to 60 for a CIE illuminant F02 under SCI UVC conditions. In some embodiments, the colorant is selected from the group consisting of TiO.sub.2, Fe.sub.2O.sub.3, NiO, Co.sub.3O.sub.4, MnO.sub.2, Cr.sub.2O.sub.3, CuO, Au, Ag, and V.sub.2O.sub.5.

To provide a dental porcelain paste which can maintain maintaining the paste state and have excellent application property for a long period of time and hardly causes carbonization or bubbles due to the influence of an organic component or a polymer component during firing. The present invention provides a dental porcelain paste for preparing a dental prosthesis device, comprising: 50.0 to 80.0 wt. % of a glass powder (a) having a maximum particle diameter of 100 m or less and an average particle diameter of 1 to 20 m, 0.5 to 10.0 wt. % of a hydrophobized fine particle silica (b) having an average primary particle diameter of 1 to 50 nm, and 10.0 to 49.5 wt. % of an organic solvent (c) having a boiling point it is within (bp) of 100 to 300 C.

The present invention relates to a particle mixture comprising particles of glass frit and particles of a crystalline oxide material, wherein the glass frit comprises silicon oxide (SiO.sub.2), zinc oxide (ZnO) and sulfur (S) and wherein the D90 particle size of the particle mixture is less than 5 microns. The particle mixture may be used to apply an enamel to a substrate. The present invention further relates to the use of the particle mixture to form an enamel on a substrate, to a glass sheet and to an automotive window pane.

The present invention relates to a particle mixture comprising particles of glass frit and particles of a crystalline oxide material, wherein the glass frit comprises silicon oxide (SiO.sub.2), zinc oxide (ZnO) and sulfur (S) and wherein the D90 particle size of the particle mixture is less than 5 microns. The particle mixture may be used to apply an enamel to a substrate. The present invention further relates to the use of the particle mixture to form an enamel on a substrate, to a glass sheet and to an automotive window pane.

The present application provides transparent glass-ceramics of -quartz of composition containing a small content of lithium, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics, and also a method of preparing said articles. Said glass-ceramics have a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 62% to 68% of SiO.sub.2; 17% to 21% of AI.sub.2O.sub.3; 1% to <2% of Li.sub.20; 1% to 4% of MgO; 1% to 6% of ZnO; 0 to 4% of BaO; 0 to 4% of SrO; 0 to 1% of CaO; 1% to 5% of TiO.sub.2; 0 to 2% of ZrO.sub.2; 0 to 1% of Na.sub.2O; 0 to 1% of K.sub.2O; with Na.sub.2O+K.sub.2O+BaO+SrO+CaO <6%; optionally up to 2% of at least one fining agent comprising SnO.sub.2; and optionally up to 2% of at least one coloring agent.

The present application provides transparent glass-ceramics of -quartz of composition containing a small content of lithium, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics, and also a method of preparing said articles. Said glass-ceramics have a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 62% to 68% of SiO.sub.2; 17% to 21% of AI.sub.2O.sub.3; 1% to <2% of Li.sub.20; 1% to 4% of MgO; 1% to 6% of ZnO; 0 to 4% of BaO; 0 to 4% of SrO; 0 to 1% of CaO; 1% to 5% of TiO.sub.2; 0 to 2% of ZrO.sub.2; 0 to 1% of Na.sub.2O; 0 to 1% of K.sub.2O; with Na.sub.2O+K.sub.2O+BaO+SrO+CaO <6%; optionally up to 2% of at least one fining agent comprising SnO.sub.2; and optionally up to 2% of at least one coloring agent.

A glass composition includes greater than or equal to 60 mol % and less than or equal to 85 mol % SiO.sub.2; greater than or equal to 0.5 mol % and less than or equal to 20 mol % Al.sub.2O.sub.3; greater than or equal to 0 mol % and less than or equal to 15 mol % Li.sub.2O; greater than or equal to 0.5 mol % and less than or equal to 25 mol % Na.sub.2O; greater than or equal to 0.1 mol % and less than or equal to 20 mol % K.sub.2O; greater than or equal to 0 mol % and less than or equal to 10 mol % CaO; greater than or equal to 0 mol % and less than or equal to 10 mol % MgO; and greater than or equal to 0.005 mol % and less than or equal to 0.5 mol % Au.