Colored glass articles and methods for making the same are described herein. In embodiments, a colored glass article may include 50 mol. % to 70 mol. % SiO.sub.2; 10 mol. % to 20 mol. % Al.sub.2O.sub.3; 4 mol. % to 10 mol. % B.sub.2O.sub.3; 7 mol. % to 17 mol. % Li.sub.2O; 1 mol. % to 9 mol. % Na.sub.2O; 0.01 mol. % to 1 mol. % SnO.sub.2; and 0.01 mol. % to 5 mol. % Ag. The difference between R.sub.2O and Al.sub.2O.sub.3(R.sub.2O—Al.sub.2O.sub.3) may be greater than 0.2 mol. % and less than or equal to 5.00 mol. % where R.sub.2O is the sum of Li.sub.2O, Na.sub.2O, and K.sub.2O.

A method of producing glass using submerged combustion melting is disclosed. The method includes introducing a vitrifiable feed material into a glass melt contained within a submerged combustion melter. The glass melt contained in the melter has a redox ratio defined as a ratio of Fe.sup.2+ to total iron in the glass melt. The method further includes combusting a combustible gas mixture supplied to each of the submerged burners to produce combustion products, and discharging the combustion products directly into the glass melt. Still further, the method includes adjusting the redox ratio of the glass melt by controlling one or more operating conditions of the submerged combustion melter selected from (1) an oxygen-to-fuel ratio of the combustible gas mixture supplied to each of the submerged burners, (2) a residence time of the glass melt, and (3) a gas flux through the glass melt.

A method of producing glass using submerged combustion melting is disclosed. The method includes introducing a vitrifiable feed material into a glass melt contained within a submerged combustion melter. The glass melt contained in the melter has a redox ratio defined as a ratio of Fe.sup.2+ to total iron in the glass melt. The method further includes combusting a combustible gas mixture supplied to each of the submerged burners to produce combustion products, and discharging the combustion products directly into the glass melt. Still further, the method includes adjusting the redox ratio of the glass melt by controlling one or more operating conditions of the submerged combustion melter selected from (1) an oxygen-to-fuel ratio of the combustible gas mixture supplied to each of the submerged burners, (2) a residence time of the glass melt, and (3) a gas flux through the glass melt.

A glass has a basic soda-lime-silica glass portion, and a colorant portion including total iron as Fe.sub.2O.sub.3 selected from the group of total iron as Fe.sub.2O.sub.3 in the range of greater than zero to 0.02 weight percent; total iron as Fe.sub.2O.sub.3 in the range of greater than 0.02 weight percent to less than 0.10 weight percent and total iron as Fe.sub.2O.sub.3 in the range of 0.10 to 2.00 weight percent; redox ratio in the range of 0.2 to 0.8, and tin and/or fin compounds, e.g. SnO.sub.2 greater than 0.000 to 5.0 weight percent. In one embodiment of the invention, the glass has a fin side and an opposite air side, wherein the tin side of the glass is supported on a molten fin bath during forming of the glass. The tin concentration at the tin side of the glass is greater than, less than, or equal to the fin concentration hi “body portion” of the glass. The “body portion” of the glass extending from the air side of the glass toward the fin side and terminating short of the tin side of the glass.

A glass has a basic soda-lime-silica glass portion, and a colorant portion including total iron as Fe.sub.2O.sub.3 selected from the group of total iron as Fe.sub.2O.sub.3 in the range of greater than zero to 0.02 weight percent; total iron as Fe.sub.2O.sub.3 in the range of greater than 0.02 weight percent to less than 0.10 weight percent and total iron as Fe.sub.2O.sub.3 in the range of 0.10 to 2.00 weight percent; redox ratio in the range of 0.2 to 0.8, and tin and/or fin compounds, e.g. SnO.sub.2 greater than 0.000 to 5.0 weight percent. In one embodiment of the invention, the glass has a fin side and an opposite air side, wherein the tin side of the glass is supported on a molten fin bath during forming of the glass. The tin concentration at the tin side of the glass is greater than, less than, or equal to the fin concentration hi “body portion” of the glass. The “body portion” of the glass extending from the air side of the glass toward the fin side and terminating short of the tin side of the glass.

A glass article including at least about 40 mol % SiO.sub.2 and, optionally, a colorant imparting a preselected color is disclosed. In general, the glass includes, in mol %, from about 40-70 SiO.sub.2, 0-25 Al.sub.2O.sub.3, 0-10 B.sub.2O.sub.3; 5-35 Na.sub.2O, 0-2.5 K.sub.2O, 0-8.5 MgO, 0-2 ZnO, 0-10% P.sub.2O.sub.5 and 0-1.5 CaO. As a result of ion exchange, the glass includes a compressive stress (σ.sub.s) at at least one surface and, optionally, a color. In one method, communicating a colored glass with an ion exchange bath imparts σ.sub.s while in another; communicating imparts σ.sub.s and a preselected color. In the former, a colorant is part of the glass batch while in the latter; it is part of the bath. In each, the colorant includes one or more metal containing dopants formulated to impart to a preselected color. Examples of one or more metal containing dopants include one or more transition and/or rare earth metals.

A glass article including at least about 40 mol % SiO.sub.2 and, optionally, a colorant imparting a preselected color is disclosed. In general, the glass includes, in mol %, from about 40-70 SiO.sub.2, 0-25 Al.sub.2O.sub.3, 0-10 B.sub.2O.sub.3; 5-35 Na.sub.2O, 0-2.5 K.sub.2O, 0-8.5 MgO, 0-2 ZnO, 0-10% P.sub.2O.sub.5 and 0-1.5 CaO. As a result of ion exchange, the glass includes a compressive stress (σ.sub.s) at at least one surface and, optionally, a color. In one method, communicating a colored glass with an ion exchange bath imparts σ.sub.s while in another; communicating imparts σ.sub.s and a preselected color. In the former, a colorant is part of the glass batch while in the latter; it is part of the bath. In each, the colorant includes one or more metal containing dopants formulated to impart to a preselected color. Examples of one or more metal containing dopants include one or more transition and/or rare earth metals.

A transparent β-spodumene glass-ceramic is provided. The glass-ceramic includes a primary crystal phase including a β-spodumene solid solution, a secondary crystal phase including tetragonal ZrO.sub.2, and an amorphous phase. The glass-ceramic may be ion exchanged utilizing molten alkali nitrate salt baths. Methods for producing the glass-ceramic are also provided.

A method of forming a multi-colored glass substrate comprises: irradiating a first region of a glass substrate with a first high energy source to form a first irradiated glass substrate; and subjecting the irradiated glass substrate to a first heat treatment to form a first heat treated glass substrate, wherein the first heat treated glass substrate comprises a second region having a different transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.33 mm under F2 illumination and a 10° standard observer angle, than the first region.

A method of forming a multi-colored glass substrate comprises: irradiating a first region of a glass substrate with a first high energy source to form a first irradiated glass substrate; and subjecting the irradiated glass substrate to a first heat treatment to form a first heat treated glass substrate, wherein the first heat treated glass substrate comprises a second region having a different transmittance color coordinate in the CIELAB color space, as measured at an article thickness of 1.33 mm under F2 illumination and a 10° standard observer angle, than the first region.