A glass ceramic contains the following components by wt %: 60 to 80% of SiO.sub.2; 4 to 20% of Al.sub.2O.sub.3; 0 to 15% of Li.sub.2O; more than 0 but less than or equal to 12% of Na.sub.2O; 0 to 5% of K.sub.2O; more than 0 but less than or equal to 5% of ZrO.sub.2; 0 to 5% of P.sub.2O.sub.5; and 0 to 10% of TiO.sub.2. A crystalline phase contains at least one of R.sub.2SiO.sub.3, R.sub.2Si.sub.2O.sub.5, R.sub.2TiO.sub.3, R.sub.4Ti.sub.5O.sub.12, R.sub.3PO.sub.3, RAlSi.sub.2O.sub.6, RAlSiO.sub.4O.sub.10, R.sub.2Al.sub.2Si.sub.2O.sub.5, R.sub.4Al.sub.4Si.sub.5O.sub.18, quartz and quartz solid solution. With a liquidus temperature below 1,450° C., a thermal conductivity above 2 w/m.Math.k, and a Vickers hardness above 600 kgf/mm2, the glass ceramic is applicable to portable electronic devices and optical devices.

Coating film-attached glass includes: glass containing a coloring component; and a colored coating film formed on one major surface of the glass, wherein at least one of an absolute value of a difference between (Δa*(D65−F2)) of the glass and (Δa*(D65−F2)) of the coating film and an absolute value of a difference between (Δa*(A−F2)) of the glass and (Δa*(A−F2)) of the coating film is 0.2 or more, where (Δa*(D65−F2)) is a difference between a chromaticity a* value of reflected light by a D65 light source and a chromaticity a* value of reflected light by an F2 light source in an L*a*b* color system and (Δa*(A−F2)) is a difference between a chromaticity a* value of reflected light by an A light source and the chromaticity a* value of the reflected light by the F2 light source in the L*a*b* color system.

Coating film-attached glass includes: glass containing a coloring component; and a colored coating film formed on one major surface of the glass, wherein at least one of an absolute value of a difference between (Δa*(D65−F2)) of the glass and (Δa*(D65−F2)) of the coating film and an absolute value of a difference between (Δa*(A−F2)) of the glass and (Δa*(A−F2)) of the coating film is 0.2 or more, where (Δa*(D65−F2)) is a difference between a chromaticity a* value of reflected light by a D65 light source and a chromaticity a* value of reflected light by an F2 light source in an L*a*b* color system and (Δa*(A−F2)) is a difference between a chromaticity a* value of reflected light by an A light source and the chromaticity a* value of the reflected light by the F2 light source in the L*a*b* color system.

The invention relates to a composition for producing a solar absorber coating, comprising a silicone resin formulated with: (i) at least one compound selected from the group consisting of black ruthenium oxides and black spinel; and (ii) a glass powder. A method of applying the composition and coatings formed are also provided.

The invention relates to a composition for producing a solar absorber coating, comprising a silicone resin formulated with: (i) at least one compound selected from the group consisting of black ruthenium oxides and black spinel; and (ii) a glass powder. A method of applying the composition and coatings formed are also provided.

A method is provided for producing a glass or glass ceramic article that includes: providing a sheet-like glass or glass ceramic substrate having two opposite faces, which in the visible spectral range from 380 nm to 780 nm exhibits light transmittance of at least 1% for visible light that passes from one face to the opposite face; providing an opaque coating on one face where the coating exhibits light transmittance of not more than 5% in the visible spectral range from 380 nm to 780 nm; and directing a pulsed laser beam onto the opaque coating and locally removing the coating by ablation down to the surface of the glass or glass ceramic article, repeatedly at different locations, thereby producing a pattern of a multitude of openings defining a perforated area in the opaque coating, so that the opaque coating becomes semi-transparent in the area.

A method is provided for producing a glass or glass ceramic article that includes: providing a sheet-like glass or glass ceramic substrate having two opposite faces, which in the visible spectral range from 380 nm to 780 nm exhibits light transmittance of at least 1% for visible light that passes from one face to the opposite face; providing an opaque coating on one face where the coating exhibits light transmittance of not more than 5% in the visible spectral range from 380 nm to 780 nm; and directing a pulsed laser beam onto the opaque coating and locally removing the coating by ablation down to the surface of the glass or glass ceramic article, repeatedly at different locations, thereby producing a pattern of a multitude of openings defining a perforated area in the opaque coating, so that the opaque coating becomes semi-transparent in the area.

A ceramic ink may include about 20% to 80% by weight oxide frit, wherein the oxide frit is particles of at least one compound selected from silica, titania, alumina, zirconia, a compound having fluoride ion, bismuth oxide, zinc oxide, boron oxide, potassium oxide, sodium oxide, calcium oxide, barium oxide, lead oxide, lithium oxide, phosphorous oxide, molybdenum oxide, strontium oxide, and magnesium oxide; about 10% to 40% by weight infrared or near-infrared transmissive or reflective inorganic pigment; and about 10% to 40% vehicle.

A ceramic ink may include about 20% to 80% by weight oxide frit, wherein the oxide frit is particles of at least one compound selected from silica, titania, alumina, zirconia, a compound having fluoride ion, bismuth oxide, zinc oxide, boron oxide, potassium oxide, sodium oxide, calcium oxide, barium oxide, lead oxide, lithium oxide, phosphorous oxide, molybdenum oxide, strontium oxide, and magnesium oxide; about 10% to 40% by weight infrared or near-infrared transmissive or reflective inorganic pigment; and about 10% to 40% vehicle.

A method for winding up a glass ribbon is provided, in which, prior to winding up the glass ribbon, the two surfaces of the glass ribbon are each initially treated with a water-containing medium and subsequently dried so as to produce a defined content of water molecules on the two surfaces, by achieving a saturation of the surfaces of the glass ribbon with water, without bringing about an excess of water molecules. A glass roll is produced in which the electrostatic charge of the glass surface is reduced and, as a result, any undesired excess adherence of the glass surface to an interleaf material is prevented and, in this way, glass breakage, in particular during winding up and/or unwinding of the glass roll, can be markedly reduced.