A metallic laminate shaped flow path member has both a surface roughness of a flow path inner surface and corrosion resistance at such a level as to be utilizable as a flow path member for use in a supply line for a corrosive fluid in a semiconductor device manufacturing apparatus. A metallic substrate constituting the metallic laminate shaped flow path member has surface irregularities, the inner surface of the flow path of the metallic laminate shaped flow path member is formed with a glass coating layer in such a manner as to fill at least recessed regions of the surface irregularities of the metallic substrate, and the glass coating layer includes at least one of a layer of a P.sub.2O.sub.5—ZnO—Al.sub.2O.sub.3 based glass, a layer of a Bi.sub.2O.sub.3—ZnO—B.sub.2O.sub.3 based glass, and a layer of an SiO.sub.2—B.sub.2O.sub.3—Na.sub.2O based glass.

A glass pharmaceutical package having a glass composition of 68.00 mol % to 81.00 mol % SiO.sub.2, from 4.00 mol % to 11.00 mol % Al.sub.2O.sub.3, from 0.10 mol % to 16.00 mol % Li.sub.2O, from 0.10 mol % to 12.00 mol % Na.sub.2O, from 0.00 mol % to 5.00 mol % K.sub.2O, from 0.10 mol % to 8.00 mol % MgO, from 0.10 mol % to 5.00 mol % CaO, from 0.00 mol % to 0.20 mol % fining agent. The glass pharmaceutical package is delamination resistant, and has class 1 or class 2 chemical durability in acid, base, and water. The glass pharmaceutical package may have a surface compressive stress of at least 350 MPa.

A glass pharmaceutical package having a glass composition of 68.00 mol % to 81.00 mol % SiO.sub.2, from 4.00 mol % to 11.00 mol % Al.sub.2O.sub.3, from 0.10 mol % to 16.00 mol % Li.sub.2O, from 0.10 mol % to 12.00 mol % Na.sub.2O, from 0.00 mol % to 5.00 mol % K.sub.2O, from 0.10 mol % to 8.00 mol % MgO, from 0.10 mol % to 5.00 mol % CaO, from 0.00 mol % to 0.20 mol % fining agent. The glass pharmaceutical package is delamination resistant, and has class 1 or class 2 chemical durability in acid, base, and water. The glass pharmaceutical package may have a surface compressive stress of at least 350 MPa.

A glass substrate has a compaction of 0.1 to 100 ppm. An absolute value |Δα.sub.50/100| of a difference between an average coefficient of thermal expansion α.sub.50/100 of the glass substrate and an average coefficient of thermal expansion of single-crystal silicon at 50° C. to 100° C., an absolute value |Δα.sub.100/200| of a difference between an average coefficient of thermal expansion α.sub.100/200 of the glass substrate and an average coefficient of thermal expansion of the single-crystal silicon at 100° C. to 200° C., and an absolute value |Δα.sub.200/300| of a difference between an average coefficient of thermal expansion α.sub.200/300 of the glass substrate and an average coefficient of thermal expansion of the single-crystal silicon at 200° C. to 300° C. are 0.16 ppm/° C. or less.

A glass substrate has a compaction of 0.1 to 100 ppm. An absolute value |Δα.sub.50/100| of a difference between an average coefficient of thermal expansion α.sub.50/100 of the glass substrate and an average coefficient of thermal expansion of single-crystal silicon at 50° C. to 100° C., an absolute value |Δα.sub.100/200| of a difference between an average coefficient of thermal expansion α.sub.100/200 of the glass substrate and an average coefficient of thermal expansion of the single-crystal silicon at 100° C. to 200° C., and an absolute value |Δα.sub.200/300| of a difference between an average coefficient of thermal expansion α.sub.200/300 of the glass substrate and an average coefficient of thermal expansion of the single-crystal silicon at 200° C. to 300° C. are 0.16 ppm/° C. or less.

An enamel composition, a method for preparing an enamel composition, and a cooking appliance including an enamel composition are provided. The enamel composition may include a base glass frit, and a catalytic glass frit. Further, the enamel composition may include 3 to 20 parts by weight of the catalytic glass frit based on 100 parts by weight of the base glass frit.

A chemically strengthened glass sheet is provided that has a thickness of at least 3.3 mm and at most 6.0 mm and a composition, in mol% on an oxide basis, comprising the following components: SiO.sub.2 65 to 85 B.sub.2O.sub.3 3 to 13 .Math. (R.sub.2O + RO) 3 to 19, wherein R.sub.2O represents any of Li.sub.2O, Na.sub.2O, and K.sub.2O, and any combination thereof, and wherein RO represents any of MgO, CaO, SrO and BaO, and any combination thereof.

Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07t to a depth of about 0.26t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18t to about 0.25t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa√m or more as measured according to the double cantilever beam method.

There is disclosed an antibacterial glass composite that may be made of components harmless to the human body and have excellent durability and chemical resistance, thereby maintaining an antibacterial function for a long time, and a manufacturing method thereof.

There is disclosed an antibacterial glass composite that may be made of components harmless to the human body and have excellent durability and chemical resistance, thereby maintaining an antibacterial function for a long time, and a manufacturing method thereof.