Disclosed is a superalloy gas turbine engine component including a glass coating. The glass coating is configured for resistance to hot corrosion caused by molten salts of sodium, magnesium, vanadium, and/or sulfur dioxide. The glass coating includes a mixture of two or more metal oxides, which are preferably selected from: barium oxide, silicon oxide, strontium oxide, aluminum oxide, magnesium oxide, calcium oxide, cobalt oxide, boron oxide, iron oxide, zirconium oxide, nickel oxide, and titanium oxide. The glass coating is in fully crystalline form and/or a mixture of crystalline and glass phases, and it has a coefficient of thermal expansion of from about 10 to about 18 μm/m-° C. The glass coating has a thickness over the superalloy gas turbine engine component of about 0.5 mils to about 10 mils.

Provided is a glass composition comprising a glass frit containing P.sub.2O.sub.5, BaO, ZnO, group I-based oxide and group II-based oxide, wherein the P.sub.2O.sub.5 is contained in an amount of 20 wt % to 55 wt % based on a total weight of the glass frit, wherein each of the BaO and ZnO is contained in an amount of 2 to 30% by weight based on the total weight of the glass frit, wherein the group I-based oxide is contained in an amount of 5 to 20% by weight based on the total weight of the glass frit, wherein the group II-based oxide is contained in an amount of 1 to 15% by weight based on the total weight of the glass frit.

A particle mixture for forming an enamel comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises greater than 5 wt % silicon oxide (SiO.sub.2) and less than 5 wt % boron oxide (B.sub.2O.sub.3); wherein the second glass frit comprises boron oxide (B.sub.2O.sub.3) and less than 5 wt % of silicon oxide (SiO.sub.2); and wherein both the particles of the first glass frit and the particles of the second glass frit have a D90 particle size of less than 5 microns. Also described is an ink comprising the particle mixture, methods of preparing the ink, an article formed using the ink, and a kit comprising particles of the first and second glass frit.

A particle mixture for forming an enamel comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises greater than 5 wt % silicon oxide (SiO.sub.2) and less than 5 wt % boron oxide (B.sub.2O.sub.3); wherein the second glass frit comprises boron oxide (B.sub.2O.sub.3) and less than 5 wt % of silicon oxide (SiO.sub.2); and wherein both the particles of the first glass frit and the particles of the second glass frit have a D90 particle size of less than 5 microns. Also described is an ink comprising the particle mixture, methods of preparing the ink, an article formed using the ink, and a kit comprising particles of the first and second glass frit.

An enamel paste composition includes glass frit; a pigment; and an organic carrier medium; wherein the glass frit includes at least two glass frits including a first glass frit and a second glass frit, and wherein the first glass frit has a larger particle size and a higher glass transition temperature than the second glass frit. Also described is a method of forming an enamel coating by depositing the enamel paste composition on a substrate; and firing the enamel paste to form an enamel coating on the substrate, the enamel coating having a heterogeneous frit microstructure with particles of the first frit embedded in a matrix of second frit.

An enamel paste composition includes glass frit; a pigment; and an organic carrier medium; wherein the glass frit includes at least two glass frits including a first glass frit and a second glass frit, and wherein the first glass frit has a larger particle size and a higher glass transition temperature than the second glass frit. Also described is a method of forming an enamel coating by depositing the enamel paste composition on a substrate; and firing the enamel paste to form an enamel coating on the substrate, the enamel coating having a heterogeneous frit microstructure with particles of the first frit embedded in a matrix of second frit.

The invention involves a silky, fine-grained matte ceramic tile and its preparation method. A blank material for the ceramic tile consists of the following components: nepheline powder: 10%-15%; high-carbon mud: 10%-15%; low-carbon mud: 15%-22%; medium-high-carbon mud: 10%-15%; recycled waste blank: 5%-10%; feldspar powder: 5%-10%; albite powder for paving: 12%-20%; waste porcelain powder: 5%-10%; desulfurized waste: 0%-7%; waste from edging and polishing: 15%-26%; liquid gel remover: 0.3%-1.0%; liquid reinforcing agent: 0.2%-0.8%. Its preparation method comprises the following steps: preparing raw materials for a blank body and ball milling.fwdarw.spray drying.fwdarw.aging.fwdarw.pressing and molding of the blank body.fwdarw.drying.fwdarw.polishing the blank body.fwdarw.spraying water.fwdarw.applying a glaze.fwdarw.applying a decorative pattern.fwdarw.firing.

The present invention relates to a silver coated glass frit used in a paste composition for forming a solar cell electrode, a method for preparing the same, and a silver paste composition using a silver coated glass frit for a solar cell. More specifically, the present invention relates to: a method for preparing a silver-coated glass frit wherein a silver coated glass frit, in which silver (Ag) is coated on a surface of the glass frit, is prepared through a reduction reaction occurring by adding, to a first solution containing silver nitrate (AgNO3) mixed with a glass frit and an amine, a second solution containing a reductant, and during the preparation process, a silver (Ag) coating layer is more uniformly formed on the surface of the glass frit by controlling the acidity of the first solution and the reaction temperature in the reduction reaction, thereby achieving an improved specific surface area; a silver-coated glass frit prepared by the method; and a silver paste composition for a solar cell wherein the composition is prepared by using the sliver-coated glass frit, and thus has significantly improved sintering characteristics and electrical conductivity.

A particle mixture comprising particles of a first glass frit and particles of a second glass frit; wherein the first glass frit comprises ≥10 to ≤25 mol. % BaO; and ≥0 to ≤10 mol. % Bi.sub.2O.sub.3; and wherein the second glass frit comprises: ≥35 to ≤55 mol. % Bi.sub.2O.sub.3; ≥2 to ≤20 mol. % ZnO; and ≥10 to ≤40 mol. % B.sub.2O.sub.3.

The present invention relates to glass composites, including filled glass composites and uses thereof. In particular examples, the composites provide improved thermal expansion characteristics. Also described are methods of forming such composites, such as by adding a particle filler to a glass mixture.