Provided herein is a film and methods of producing the same. The film includes a substrate and a layer adjacent to the substrate, wherein a surface of the layer comprises spaced apart protrusions. The methods include providing a substrate, depositing a layer on at least a portion of the substrate, decomposing the layer to form at least a first phase of material and a second phase of material, and removing at least a portion of the second phase from the decomposed layer to form a structured layer.

A scratch resistant alkali aluminoborosilicate glass. The glass is chemically strengthened and has a surface layer that is rich in silica with respect to the remainder of the glass article. The chemically strengthened glass is then treated with an aqueous solution of a mineral acid other than hydrofluoric acid, such as, for example, HCl, HNO.sub.3, H.sub.2SO.sub.4, or the like, to selective leach elements from the glass and leave behind a silica-rich surface layer. The silica-rich surface layer improves the Knoop scratch threshold of the ion exchanged glass compared to ion exchanged glass that are not treated with the acid solution as well as the post-scratch retained strength of the glass.

A scratch resistant alkali aluminoborosilicate glass. The glass is chemically strengthened and has a surface layer that is rich in silica with respect to the remainder of the glass article. The chemically strengthened glass is then treated with an aqueous solution of a mineral acid other than hydrofluoric acid, such as, for example, HCl, HNO.sub.3, H.sub.2SO.sub.4, or the like, to selective leach elements from the glass and leave behind a silica-rich surface layer. The silica-rich surface layer improves the Knoop scratch threshold of the ion exchanged glass compared to ion exchanged glass that are not treated with the acid solution as well as the post-scratch retained strength of the glass.

A porous silicon composition, a porous alloy composition, or a porous silicon containing cermet composition, as defined herein. A method of making: the porous silicon composition; the porous alloy composition, or the porous silicon containing cermet composition, as defined herein. Also disclosed is an electrode, and an energy storage device incorporating the electrode and at least one of the disclosed compositions, as defined herein.

Provided herein are methods for preparing nano-macroporous glass articles, such as bioscaffolds, from starting materials such as phosphosilicate glasses made by melt-quench methods, mixed with a soluble pore former such as a sugar, followed by steps of dissolving, heating, and leaching to yield a glass composition having a highly interconnected system of both macropores and large scale nanoporosity.

The invention relates to an optical scattering element suitable for dispersing or scattering light transmitted by optical device by Mie scattering. The optical scattering element comprises a phase-separated or porous borosilicate glass having dispersed phase particles with a particle size of 200 to 500 nanometers or pores with a size of 200 to 500 nanometers, at a number density of 10.sup.8 to 10.sup.12 mm.sup.3. The optical scattering element can be prepared by subjecting a borosilicate glass to a controlled heat treatment to induce phase separation, and then optionally leaching out one of the phases with an acid leach. The optical scattering element can be, for example, attached to an end of an optical fiber or bundle of optical fibers. The invention also relates to a method of dispersing or scattering light by transmitting the light through the optical scattering element.

A method of forming a glass laminate includes providing a substrate having a core layer and at least one cladding layer; heat treating the substrate at a temperature such that the at least one cladding layer is phase-separated after the heat treating; and etch treating the substrate for at least 10 sec. A phase-separated glass laminate includes a substrate having a core layer and at least one phase-separated cladding layer, such that the glass laminate has a % transmission of at least 96%, and the at least one cladding layer comprises a grain size in a range of 10 nm to 1 m, or a graded glass index of greater than 5 nm.

A method of forming a glass laminate includes providing a substrate having a core layer and at least one cladding layer; heat treating the substrate at a temperature such that the at least one cladding layer is phase-separated after the heat treating; and etch treating the substrate for at least 10 sec. A phase-separated glass laminate includes a substrate having a core layer and at least one phase-separated cladding layer, such that the glass laminate has a % transmission of at least 96%, and the at least one cladding layer comprises a grain size in a range of 10 nm to 1 m, or a graded glass index of greater than 5 nm.

A method of forming a shaped glass laminate having improved anti-reflection (AR) and anti-glare (AG) characteristics, including preheating a substrate including a core layer and at least one cladding layer, the at least one cladding layer including a phase-separable glass composition, simultaneously heat treating and thermal forming the substrate such that the at least one cladding layer is phase-separated and at least a portion of the substrate is deformed to form the shaped glass laminate, the simultaneous heat treating and thermal forming of the substrate including heating the substrate and pressing the substrate at the same time, and etch treating the substrate.

A glass container includes a glass body comprising an external surface, an internal surface opposite the external surface, a thickness T extending between the external surface and the internal surface, and an external surface layer extending from the external surface into the thickness of the glass body, wherein the external surface layer has a porosity greater than a porosity of a remainder of the glass body extending from the external surface layer to the internal surface.