The present invention relates to a laminate for preparing a wavelength converting member and a process for preparing a wavelength converting member. More particularly, the present invention relates to a laminate for preparing a wavelength converting member, which can be calcined at a temperature of 800 C. or lower, preferably 700 C. or lower and has a high light transmittance, a high refractive index, and a good shape upon the calcination, whereby it can be advantageously used for LEDs, and a process for efficiently preparing the wavelength converting member using a confining layer comprised of specific components.

An optical nanocomposite containing optically active crystals (rare earth or transition metal doped) in a suitably index-, dispersion-, thermo-optically matched matrix enables creation of a glass ceramic with unique optical properties. By further tuning the viscosity of the composite, it can be drawn into fiber form, dissolved into solution and subsequently deposited as a thin film, or used as a bulk optical component. Critical to achieving a viable material is closely matching the attributes needed to not only achieve optical function but to enable fabrication under elevated temperatures (i.e., during fiber drawing) or in unique chemical or thermal environments, such as during deposition as a thin film. This invention uses nanosized crystalline powders (nanocrystalsNC), blended with multicomponent chalcogenide glass (ChG) to form an optical nanocomposite. The blended NC:glass integrates compositional tailoring to enable matching of optical properties (index, dispersion, dn/dT), specialized dispersion methods to ensure homogeneous physical dispersion of NCs within the glass matrix during preparation, while minimizing agglomeration and mismatch of coefficient of thermal expansion. The latter attributes are critical to maintaining low loss (optical scatter) and induced stress birefringence due to mismatch between the NC and glass' parent properties. By tailoring the base glass composition's viscosity versus temperature profile, the resulting bulk nanocomposite can be further formed to create an optical fiber, while maintaining physical dispersion on NCs, avoiding segregation of the NCs. This enables low loss conditions suitable for lasing within the material.

A glass substrate and a method for manufacturing the glass substrate are provided. The glass substrate may include a base glass including SiO.sub.2, Al.sub.2O.sub.3, and Li.sub.2O, and nanocrystals having an average diameter in a range from about 5 nm to about 10 nm, thereby exhibiting enhanced surface strength properties while maintaining good transmittance properties. The method may include a step of heat-treating a base glass, thereby providing a glass substrate having enhanced strength properties.

The present invention discloses a glass ceramic for excitation of high-power semiconductor light source. An expression of constitution of the glass ceramic is (1x)A: xB, wherein x as a weight percentage of B, is ranging from 1% to 30%; A as a precursor glass, has a composition of aSb.sub.2O.sub.3-bB.sub.2O.sub.3-cZnO-dM.sub.2O, a, b, c, d being molar percentages, a+b+c+d=100%, M among M.sub.2O represents an alkali metal, and M.sub.2O is an alkali metallic oxide or an alkali metallic carbonate; and B is a YAG:Ce.sup.3+ fluorescent powder. The precursor glass provided by the present invention has a relatively low remelting temperature, without devitrification during the process of preparing the final products or absorption of blue light. The product glass ceramic has a luminous efficiency of 300 lm/W to 400 lm/W. A white light semiconductor light source is prepared by the product glass ceramic in combination with the high-power blue light semiconductor light source. A preparation method provided by the present invention has advantages such as low cost, excellent performances, and being green, pollution-free and suitable for the large-scale industrial production. The present invention can be applied in the field of illumination light source and display light source, such as head-lights of vehicles, searchlights, projectors and laser cinemas.

Disclosed herein are glass-ceramics having crystalline phases including -spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectancespecular includedmeasurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about 2 to about +2; and b*=from about 12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, -quartz ss can be substantially absent from the crystalline phases. If present, -quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.

Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P.sub.2O.sub.5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.

An optoelectronic component and a method for producing an optoelectronic component are disclosed. In an embodiment an optoelectronic component includes at least one laser source configured to emit at least one laser beam during operation and a self-supporting conversion element arranged in a beam path of the laser beam, wherein the self-supporting conversion element comprises a substrate followed by a first layer, the first layer being directly bonded to the substrate and comprising at least one conversion material embedded in a glass matrix, wherein the glass matrix has a proportion of 50 vol % to 80 vol % inclusive in the first layer, wherein the substrate is free of the glass matrix and of the conversion material and mechanically stabilize the first layer, and wherein the first layer has a layer thickness of less than 200 m.

Provided is a ceramic complex having high luminous characteristics. Proposed is a ceramic complex including a rare earth aluminate fluorescent material, glass, and calcium fluoride, wherein, when the total amount of the rare earth aluminate fluorescent material, the glass, and the calcium fluoride is taken as 100% by volume, the content of the rare earth aluminate fluorescent material is in a range of 15% by volume or more and 60% by volume or less, the content of the glass is in a range of 3% by volume or more and 84% by volume or less, and the content of the calcium fluoride is in a range of 1% by volume or more and 60% by volume of less.

A lithium aluminum silicate (LAS) glass-ceramic has an average coefficient of thermal expansion (CTE) in a range from 0 to 50? C. of at most 0?0.1?10.sup.?6/K and a thermal hysteresis at least in a temperature range from 15? C. to 35? C. of <0.1 ppm. The LAS glass-ceramic includes (in mol % based on oxide): SiO.sub.2 60-<70; Li.sub.2O 7-9.6; MgO+ZnO>0.5-1.5; R.sub.2O>0.5, where R.sub.2O is Na.sub.2O and/or K.sub.2O and/or Cs.sub.2O and/or Rb.sub.2O; and nucleating agent with a content of 1.5 to 6 mol %. The nucleating agent is at least one component selected from the group consisting of TiO.sub.2, ZrO.sub.2, Ta.sub.2O.sub.5, Nb.sub.2O.sub.5, SnO.sub.2, MoO.sub.3, WO.sub.3 and HfO.sub.2.

A tinted glass composition and glass article including the same, the composition including: about 45 mol % to about 80 mol % SiO.sub.2; about 6 mol % to about 22 mol % Al.sub.2O.sub.3; 0 mol % to about 25 mol % B.sub.2O.sub.3; about 7 mol % to about 25 mol % of at least one alkaline earth oxide selected from MgO, CaO, SrO, BaO, and combinations thereof, about 0.5 mol % to about 20 mol % CuO; 0 mol % to about 6 mol % SnO.sub.2, SnO, or a combination thereof, 0 mol % to about 1.0 mol % C; 0 mol % to about 5 mol % La.sub.2O.sub.3; and 0 mol % to about 10 mol % PbO, and that is substantially free of alkali metal.