Glass articles with infrared reflectivity and methods for making the same are disclosed herein. In one embodiment, glass article having infrared reflectivity includes a first surface, a second surface and a body extending between the first and second surfaces. A plurality of discrete layers of metallic silver are formed in the body creating at least one optical cavity in the body. Each discrete layer may have a thickness T such that 100 nm≤T≤250 nm and may be spaced apart from adjacent layers of metallic silver by a spacing S≤500. The glass article reflects at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 800 nm to 2500 nm and transmits at least a portion of electromagnetic radiation incident on the glass article having a wavelength from 390 nm to 750 nm.

Due to the increased glazed area of modern vehicles, especially the large panoramic glass roofs, we have seen a substantial growth in the use of anti-reflective coatings. Unfortunately, these types of coatings accentuate fingerprints and smudges. The invention provides an automotive glazing which is substantially resistant to fingerprints, and a method of manufacture thereof through the application of an anti-fingerprint coating based on low surface energy silanes.

A colored glass article may include 50-80 mol % SiO.sub.2; 7-20 mol % Al.sub.2O.sub.3; 1-35 mol % R.sub.2O, wherein R.sub.2O comprises at least one of Li.sub.2O, Na.sub.2O, and K.sub.2O; 1×10.sup.−6-10 mol % of a colorant, wherein the colorant comprises at least one of Cr.sub.2O.sub.3, Au, Ag, CuO, NiO, Co.sub.3O.sub.4, TiO.sub.2, CeO.sub.2; and 12-24 mol % of Al.sub.2O.sub.3+MgO+CaO+ZnO. The colored glass article may have a transmittance color coordinate in the CIELAB color space with an L* value of 55 to 96.5. The colored glass article may have a compressive stress profile with a depth of compression ≥0.15t, a thickness t from 0.4 mm-5 mm, a compressive stress ≥200 MPa, and a central tension ≥60 MPa. The colored glass article may have a dielectric constant from 5.6 to 6.4 over the frequency range from 10 GHz to 60 GHz.

Provided is a glass strengthening method including preparing a glass and strengthening the glass by providing the glass with a molten salt, wherein the molten salt has a freezing point of about 220° C. or more and less than 320° C. In addition, the molten salt includes a first salt and a second salt that are different from each other, wherein the first salt is KNO.sub.3, and the second salt includes at least one ion of Li.sup.+, Na.sup.+, K.sup.+, Cs.sup.+, and/or Rb.sup.+.

Glass-based articles are disclosed having a thickness in a range of from about 0.2 mm to about 4.0 mm, a first compressive stress layer extending from a first surface of the glass-based article to a first depth of compression that is in a range of from about 5% to about 20% of the thickness, a second compressive stress layer extending from a second surface of the glass-based article to a second depth of compression that is in a range of from about 5% to about 20% of the thickness, wherein the second surface is opposite the first surface, and a central region extending from the first depth of compression to the second depth of compression and having a maximum tensile stress in a range of from about 0.5 MPa to about 20 MPa. Electronic devices comprising the glass-based articles and methods of making glass-based articles are also disclosed.

A method for treating a lead-containing glass that makes it possible to limit the migration of the lead contained in this glass, the method successively comprising the following distinct steps: a step of placing the lead-containing glass in contact with a solution comprising perchloric acid; a step of heat treatment of the glass at a temperature less than or equal to the glass transition temperature of the glass.

Due to the increased glazed area of modern vehicles, especially the large panoramic glass roofs, we have seen a substantial growth in the use solar control glass and coatings. The solar glass compositions and coatings are expensive to manufacture. While solar coatings are more efficient than compositions, they typically cannot be used on monolithic glazing as they are not durable. They must be applied to one of the surfaces on the inside of a laminate. Most of these products also introduce an undesirable color shift. The invention provides a coating that can be used on glass to produce a laminated or monolithic glazing with a neutral gray solar control coating which also has anti-reflective properties and low emissivity.

Various embodiments disclosed include a method of bending a glass laminate structure, the method can optionally include any one or any combination of: heating the glass laminate structure comprising at least a first ply substrate and a second ply substrate, wherein the first ply substrate has a first composition and a first thickness that differ from a second composition and a second thickness of the second ply substrate; engaging an edge portion of one or both of a first major surface and a second major surface of the glass laminate structure; and sequent to engaging the edge portion, pressing the glass laminate structure to bend the glass laminate structure and obtain a desired curvature of the glass laminate structure along one or both of the first major surface and the second major surface.

Glasses with compressive stress profiles that allow higher surface compression and deeper depth of layer (DOL) than is allowable in glasses with stress profiles that follow the complementary error function at a given level of stored tension. In some instances, a buried layer or local maximum of increased compression, which can alter the direction of cracking systems, is present within the depth of layer. Theses compressive stress profiles are achieved by a three step process that includes a first ion exchange step to create compressive stress and depth of layer that follows the complimentary error function, a heat treatment at a temperature below the strain point of the glass to partially relax the stresses in the glass and diffuse larger alkali ions to a greater depth, and a re-ion-exchange at short times to re-establish high compressive stress at the surface.

A glass-based article including a first surface and a second surface opposing the first surface defining a thickness (t) of about 3 millimeters or less (e.g., about 1 millimeter or less), and a stress profile, wherein all points of the stress profile between a thickness range from about 0.Math.t up to 0.3.Math.t and from greater than about 0.7.Math.t to t, comprise a tangent with a slope having an absolute value greater than about 0.1 MPa/micrometer. In some embodiments, the glass-based article includes a non-zero metal oxide concentration that varies along at least a portion of the thickness (e.g., 0.Math.t to about 0.3.Math.t) and a maximum central tension of less than about 71.5/√(t) (MPa). In some embodiments, the concentration of metal oxide or alkali metal oxide decreases from the first surface to a point between the first surface and the second surface and increases from the point to the second surface. The concentration of the metal oxide may be about 0.05 mol % or greater or about 0.5 mol % or greater throughout the thickness. Methods for forming such glass-based articles are also disclosed.