Embodiments of the present disclosure pertain to crystallizable glasses and glass-ceramics that exhibit a black color and are opaque. In one or more embodiments, the crystallizable glasses and glass-ceramics include a precursor glass composition that exhibits a liquidus viscosity of greater than about 20 kPa*s. The glass-ceramics exhibit less than about 20 wt % of one or more crystalline phases, which can include a plurality of crystallites in the Fe.sub.2O.sub.3TiO.sub.2MgO system and an area fraction of less than about 15%. Exemplary compositions used in the crystallizable glasses and glass-ceramics include, in mol %, SiO.sub.2 in the range from about 50 to about 76, Al.sub.2O.sub.3 in the range from about 4 to about 25, P.sub.2O.sub.5+B.sub.2O.sub.3 in the range from about 0 to about 14, R.sub.2O in the range from about 2 to about 20, one or more nucleating agents in the range from about 0 to about 5, and RO in the range from about 0 to about 20.

Photosensitive lithium zinc aluminosilicate glasses that can be selectively irradiated and cerammed to provide patterned regions of glass and lithium-based glass ceramic, and composite glass articles made from such glasses and glass ceramics are provided. Compressive and tensile stress at the interface of the lithium-based glass-ceramic and lithium zinc aluminosilicate glass may be used to frustrate crack propagation in such a composite glass/glass ceramic article. Methods of making composite glass articles comprising such lithium-based glass ceramics and lithium zinc aluminosilicate glasses are also provided.

An opaque gahnite-spinel glass ceramic is provided. The glass ceramic includes a first crystal phase including (Mg.sub.xZn.sub.1-x)Al.sub.2O.sub.4 where x is less than 1 and a second crystal phase includes at least one of tetragonal ZrO.sub.2, MgTa.sub.2O.sub.6, mullite, and cordierite. The glass ceramic has a Young's modulus greater than or equal to 90 GPa, and has a hardness greater than or equal to 7.5 GPa. The glass ceramic may be ion exchanged. Methods for producing the glass ceramic are also provided.

A material system for a surface display unit that includes a first side (i.e., a proximal side) that faces a viewer of the surface display unit and a second side (i.e., a distal side) facing away from the viewer. The material system provides at least three appearance states, including a generally opaque first appearance state when the surface display unit is off (i.e., not used to display images), a second appearance state in which the material system is illuminated from the first (i.e., proximal) side to display a first image (e.g., information and/or decoration) that is perceptible to the viewer, and a third appearance state in which the material system is illuminated from the second (i.e., distal) side to display a second image (e.g., information and/or decoration) that is perceptible to the viewer. Surface display units, systems, and methods comprising the material system are also disclosed.

The disclosure is directed to a chemically strengthened glass having antimicrobial properties and to a method of making such glass. In particular, the disclosure is directed to a chemically strengthened glass with antimicrobial properties and with a low surface energy coating on the glass that does not interfere with the antimicrobial properties of the glass. The antimicrobial has an Ag ion concentration on the surface in the range of greater than zero to 0.047 g/cm.sup.2. The glass has particular applications as antimicrobial shelving, table tops and other applications in hospitals, laboratories and other institutions handling biological substances, where color in the glass is not a consideration.

Aspects of this disclosure pertain to a colorless material that includes a carrier, copper-containing particles, and quaternary ammonium. In one or more embodiments, the material exhibits, in the CIE L*a*b* system, an L* value in the range from about 91 to about 100, and a C* value of less than about 7, wherein C* equals (a*.sup.2+b*.sup.2). In some embodiments, the material exhibits a greater than 3 log reduction in a concentration of Staphylococcus aureus, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing conditions.

Embodiments of the present disclosure pertain to crystallizable glasses and glass-ceramics that exhibit a black color and are opaque. In one or more embodiments, the crystallizable glasses and glass-ceramics include a precursor glass composition that exhibits a liquidus viscosity of greater than about 20 kPa*s. The glass-ceramics exhibit less than about 20 wt % of one or more crystalline phases, which can include a plurality of crystallites in the Fe.sub.2O.sub.3TiO.sub.2MgO system and an area fraction of less than about 15%. Exemplary compositions used in the crystallizable glasses and glass-ceramics include, in mol %, SiO.sub.2 in the range from about 50 to about 76, Al.sub.2O.sub.3 in the range from about 4 to about 25, P.sub.2O.sub.5+B.sub.2O.sub.3 in the range from about 0 to about 14, R.sub.2O in the range from about 2 to about 20, one or more nucleating agents in the range from about 0 to about 5, and RO in the range from about 0 to about 20.

Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit -spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO.sub.2; 10.5-18 Al.sub.2O.sub.3; 5-14 Li.sub.2O; 2-12 B.sub.2O.sub.3; and 0.4-2 Fe.sub.2O.sub.3. Additionally, these glasses and glass-ceramics can exhibit the following criteria: a ratio: $\frac{\left[{\mathrm{Li}}_{2}O+{\mathrm{Na}}_{2}O+K_{2}O+\mathrm{MgO}+\mathrm{ZnO}\right]}{\left[{\mathrm{Al}}_2{O}_3\right]}$ between 0.8 to 1.5. The glass-ceramics also exhibit colors at an observer angle of 10 and a CIE illuminant F02 determined with specular reflectance of a* between 0.5 and 0.5, b* between 2.5 and +2, and L* between 90 and 93.

A method of modifying glass frit involves treating the frit with a grain-boundary-healing compound. The method increases transmission and clarity, and reduces haze of a fired enamel coating made from such modified glass frit as compared to a coating not made from such modified glass frit. The grain-boundary-healing compound influences the chemistry at the grain boundaries to prevent haze. The compound burns out to yield a fluxing material that dissolves alkaline carbonates or bicarbonates on the surface of the glass frit. The dissolved species are incorporated into the enamel coating, thereby promoting the fusion of the glass frit and reducing the amount of haze in the enamel coating. The additives also function to prevent the formation of seed crystals on the surface of the glass frit that may inhibit the fusion of the glass frit.

Disclosed herein are glass-ceramics having crystalline phases including -spodumene ss and either (i) pseudobrookite or (ii) vanadium or vanadium containing compounds so as to be colored and opaque glass-ceramics having coordinates, determined from total reflectancespecular includedmeasurements, in the CIELAB color space of the following ranges: L*=from about 20 to about 45; a*=from about 2 to about +2; and b*=from about 12 to about +1. Such CIELAB color space coordinates can be substantially uniform throughout the glass-ceramics. In each of the proceeding, -quartz ss can be substantially absent from the crystalline phases. If present, -quartz ss can be less than about 20 wt % or, alternatively, less than about 15 wt % of the crystalline phases. Also Further crystalline phases might include spinel ss (e.g., hercynite and/or gahnite-hercynite ss), rutile, magnesium zinc phosphate, or spinel ss (e.g., hercynite and/or gahnite-hercynite ss) and rutile.