A novel engineered concrete binder composition providing overall reduced clinker factor and improved binding properties. The said concrete binder composition includes a primary binder in a ratio of 10-60 weight percent and a secondary binder in a ratio of 40-90 weight percent. The said primary binder is selected from a primary material group having spontaneous hydration property. The said secondary binder is selected from a secondary material group having induced hydration property.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 m. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 m. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

The invention comprises a cementitious material comprising a natural pozzolan selected from hyaloclastite, sideromelane or tachylite, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to 40 m. The cementitious material also comprising an aqueous alkaline activating solution suitable for forming a geopolymer. A method making a cementitious material is also disclosed.

The invention comprises a cementitious material comprising a natural pozzolan selected from hyaloclastite, sideromelane or tachylite, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to 40 m. The cementitious material also comprising an aqueous alkaline activating solution suitable for forming a geopolymer. A method making a cementitious material is also disclosed.

Alkali activated concrete compositions containing natural pozzolan, ground granulated blast furnace slag, alkali activators such as an alkali hydroxide and an alkali silicate, and optionally fine and coarse aggregates. Alkali activated concretes made therefrom and methods of making such concretes are also specified. The inclusion of ground granulated blast furnace slag provides significantly superior mechanical strength (e.g. compressive strength) to the alkali activated concretes within 12-24 hours of curing at 30-60 C.

Alkali activated concrete compositions containing natural pozzolan, ground granulated blast furnace slag, alkali activators such as an alkali hydroxide and an alkali silicate, and optionally fine and coarse aggregates. Alkali activated concretes made therefrom and methods of making such concretes are also specified. The inclusion of ground granulated blast furnace slag provides significantly superior mechanical strength (e.g. compressive strength) to the alkali activated concretes within 12-24 hours of curing at 30-60 C.

It has been unexpectedly discovered that the addition of a natural or other pozzolan to non-spec fly ash significantly improves the properties of the non-spec fly ash to the extent it can be certified under ASTM C618 and AASHTO 295, as either a Class F or Class C fly ash. The natural pozzolan may be a volcanic ejecta, such as pumice or perlite. Other pozzolans may also be used for this beneficiation process. Many pozzolans are experimentally tested and may be used to beneficiate non-spec fly ash into certifiable Class F fly ash. Additionally, this disclosure provides a method of converting a Class C fly ash to a more valuable Class F fly ash. This discovery will extend diminishing Class F fly ash supplies and turn non-spec fly ash waste streams into valuable, certified fly ash pozzolan which will protect and enhance concrete, mortars and grouts.

Alkali activated concrete compositions containing natural pozzolan, ground granulated blast furnace slag, alkali activators such as an alkali hydroxide and an alkali silicate, and optionally fine and coarse aggregates. Alkali activated concretes made therefrom and methods of making such concretes are also specified. The inclusion of ground granulated blast furnace slag provides significantly superior mechanical strength (e.g. compressive strength) to the alkali activated concretes within 12-24 hours of curing at 30-60 C.

Alkali activated concrete compositions containing natural pozzolan, ground granulated blast furnace slag, alkali activators such as an alkali hydroxide and an alkali silicate, and optionally fine and coarse aggregates. Alkali activated concretes made therefrom and methods of making such concretes are also specified. The inclusion of ground granulated blast furnace slag provides significantly superior mechanical strength (e.g. compressive strength) to the alkali activated concretes within 12-24 hours of curing at 30-60 C.