Patent classifications
C04B7/345
PRODUCTION OF SUPPLEMENTARY CEMENTITIOUS MATERIALS THROUGH WET CARBONATION METHOD
A method of making a supplementary cementitious material is described that includes: forming a slurry comprising water and a carbonatable material powder, wherein a weight ratio of water to the carbonatable material powder is at least 1; and flowing a gas comprising carbon dioxide into the slurry for 0.5 to 24 hours while maintaining the slurry at a temperature of 1° C. to 99° C. to form a carbonated slurry comprising CaCO.sub.3 and amorphous silica. A method of forming cement or concrete using the supplemental cementitious material is also described.
Manufacturing a binder with high β belite content
The present invention relates to a method for manufacturing a binder with high β belite content comprising the steps: a) providing a starting material by selecting one raw material having a Ca/Si molar ratio of 1.5 to 2.5 or by mixing two or more raw materials to obtain a starting material with the Ca/Si molar ratio of 1.5 to 2.5; b) hydrothermal treatment of the starting material produced in step a) in an autoclave at a temperature of 100 to 300° C. and a retention time of 0.1 to 24 h, wherein the water/solids ratio is from 0.1 to 100 to provide an intermediate product; c) annealing the intermediate product obtained in step b) in a flash calciner at 620 to 630° C., wherein the retention time is 1-30 seconds.
COMPOSITE MINERALIZERS/FLUXES FOR THE PRODUCTION OF ALITE/CALCIUM SULFOALUMINATE CLINKERS
A cement clinker composition incorporates calcium fluoride and iron oxide to reduce firing temperatures and increase strength. High fly ash, aluminum dross, aluminum scrap, high aluminum clays and combinations thereof may also be substituted for bauxite in the cement clinker composition
Process for producing a cement clinker at low temperature
The invention provides a process for producing a cement clinker comprising: (i) mixing one or more starting materials providing each at least one or more of CaO, SiO.sub.2, Al.sub.2O.sub.3, and Fe.sub.2O.sub.3; and, optionally, SO.sub.3, to form a raw meal comprising CaO, SiO.sub.2, Al.sub.2O.sub.3, and Fe.sub.2O.sub.3; and, optionally, SO.sub.3, wherein the molar ratios among the aforementioned oxides is given by Formula I: (CaO).sub.1(SiO.sub.2).sub.a(Al.sub.2O.sub.3).sub.b(Fe.sub.2O.sub.3).sub.c(SO.sub.3).sub.d, wherein: a is comprised from 0.05 to 1, b is comprised from 0.01 to 0.6, c is comprised from 0.001 to 0.25, and d is comprised from 0 to 0.3 and wherein at least 35% (p/p) of the starting materials of the raw meal have a critical microwaves absorbance temperature (Tc) comprised from 15 to 650 C. and a critical microwaves absorbance time (tc) comprised from 1 min to 1 h; (ii) heating the raw meal by irradiating with microwaves during 15 min to 3 h to reach a sintering temperature comprised from 300 to 950 C.; (iii) maintaining the microwave sintering temperature of step (ii) during 1 min to 3 h by further irradiating with microwaves; and (iv) cooling the clinker obtained in step (iii).
METHOD FOR MANUFACTURING BINDERS HARDENING BY HYDRATION AND CARBONATION
A method for manufacturing a binder of a hydratable material includes providing a starting material from one or more raw materials convertible by tempering at 600 to 1200 C. into the hydratable material, tempering the starting material to provide the hydratable material containing not more than 10% by weight monocalcium silicate and at least 15% by weight hydratable phases in the form of lime and dicalcium silicate, wherein the residence time and the tempering temperature are adapted to obtain the hydratable material by converting not more than 80% by weight of the starting material, and cooling the hydratable material to provide the binder comprising the hydratable material. The binder can be mixed with water and optionally one or more of aggregate, additives, admixtures to obtain a binder paste that is placed, hydrated and carbonated to produce a building product.
USE OF A HYDRAULIC BINDER COMPOSITION IN A METHOD FOR INERTING POLLUTED SOIL
A method for inerting polluted soil, comprising adding to a polluted soil a composition comprising: from 40% to 99% of a sulfoaluminous clinker comprising as a phase composition, to the overall weight of the clinker: from 5% to 80% of a calcium sulfoaluminate phase possibly iron-doped corresponding to the formula C4AxFy$z in which x varies from 2 to 3; y varies from 0 to 0.5; and z varies from 0.8 to 1.2; from 0 to 25% of a calcium aluminoferrite phase of a composition corresponding to the general formula C.sub.6A.sub.xF.sub.y; x varies from 0 to 1.5; and y varies from 0.5 to 3; and from 10% to 70% of a belite phase C.sub.2S; and from 1% to 60% of a lime.
USE OF A HYDRAULIC BINDER COMPOSITION IN A METHOD FOR INERTING POLLUTED SOIL
A method for inerting polluted soil, comprising adding to a polluted soil a composition comprising: from 40% to 99% of a sulfoaluminous clinker comprising as a phase composition, to the overall weight of the clinker: from 5% to 80% of a calcium sulfoaluminate phase possibly iron-doped corresponding to the formula C4AxFy$z in which x varies from 2 to 3; y varies from 0 to 0.5; and z varies from 0.8 to 1.2; from 0 to 25% of a calcium aluminoferrite phase of a composition corresponding to the general formula C.sub.6A.sub.xF.sub.y; x varies from 0 to 1.5; and y varies from 0.5 to 3; and from 10% to 70% of a belite phase C.sub.2S; and from 1% to 60% of a lime.
COMPOSITE MATERIALS AND BONDING ELEMENTS FROM CARBONATION OF CALCIUM SILICATE AND METHODS THEREOF
The invention provides composite materials comprising novel bonding elements exhibiting unique microstructures and chemical compositions, and methods for their manufacture and uses, for example, in a variety of concrete components with or without aggregates in the infrastructure, construction, pavement and landscaping industries.
COMPOSITE MATERIALS AND BONDING ELEMENTS FROM CARBONATION OF CALCIUM SILICATE AND METHODS THEREOF
The invention provides composite materials comprising novel bonding elements exhibiting unique microstructures and chemical compositions, and methods for their manufacture and uses, for example, in a variety of concrete components with or without aggregates in the infrastructure, construction, pavement and landscaping industries.
Steam-assisted production of metal silicate cements, compositions and methods thereof
The invention provides a novel, steam-assisted production methodology and associated compositions and methods of use in the manufacture of carbonatable or non-carbonatable metal silicate or metal silicate hydrate (e.g., calcium silicate or calcium silicate hydrate) compositions. These metal silicate compositions and related phases are suitable for use hydraulic, partially hydraulic or non-hydraulic cement that sets and hardens by a hydration process, a carbonation process or a combination thereof, and may be applied in a variety of concrete components in the infrastructure, construction, pavement and landscaping industries.