A composition for additive manufacturing of an article may include a base material, a functional particulate having at least one of an acicular morphology and a platy morphology, and binder. The functional particulate may increase a strength property of the article manufactured with the composition as compared to the strength property of the article manufactured with the composition being devoid of the functional particulate. A method of manufacturing an article via additive manufacturing may include providing a first layer of a powder composition. The powder composition may include a base material, a functional particulate, and binder. The method may also include binding the first layer of powder composition in a predetermined pattern to form a hardened two-dimensional shape including the powder composition, and successively providing additional layers of the powder composition and binding the respective layers to form the article.

A composition for additive manufacturing of an article may include a base material, a functional particulate having at least one of an acicular morphology and a platy morphology, and binder. The functional particulate may increase a strength property of the article manufactured with the composition as compared to the strength property of the article manufactured with the composition being devoid of the functional particulate. A method of manufacturing an article via additive manufacturing may include providing a first layer of a powder composition. The powder composition may include a base material, a functional particulate, and binder. The method may also include binding the first layer of powder composition in a predetermined pattern to form a hardened two-dimensional shape including the powder composition, and successively providing additional layers of the powder composition and binding the respective layers to form the article.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 m. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

The invention comprises a composition comprising a natural pozzolan selected from hyaloclastite, sideromelane or tachylite, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to 40 m. The invention also comprises a cementitious material comprising a hydraulic cement and a natural pozzolan selected from hyaloclastite, sideromelane, tachylite or combination or mixtures thereof, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to approximately 40 m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and a natural pozzolan selected from hyaloclastite, sideromelane, tachylite or combination or mixtures thereof, wherein the natural pozzolan has a volume-based mean particle size of less than or equal to approximately 40 m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

Self-consolidating geopolymer compositions utilizing fly ash and inorganic mineral including alkaline earth metal oxide as cementitious reactive components and include cement set retarder. The alkaline earth metal oxide is preferably calcium oxide (also known as lime or quicklime) and/or magnesium oxide. The inorganic minerals including alkaline earth metal oxide have an alkaline earth metal oxide content preferably greater than 50 wt. %, more preferably greater than 60 wt. %, even more preferably greater than 70 wt. %, and most preferably greater than 80 wt. %, for example greater than 90 wt. %. The cementitious reactive powder may optionally also include one or more aluminous cements and one or more source of calcium sulfates. The cementitious reactive powders are activated with an alkali metal chemical activator selected from alkali metal salt and/or alkali metal base. Methods for making the compositions are also disclosed.

Self-consolidating geopolymer compositions utilizing fly ash and inorganic mineral including alkaline earth metal oxide as cementitious reactive components and include cement set retarder. The alkaline earth metal oxide is preferably calcium oxide (also known as lime or quicklime) and/or magnesium oxide. The inorganic minerals including alkaline earth metal oxide have an alkaline earth metal oxide content preferably greater than 50 wt. %, more preferably greater than 60 wt. %, even more preferably greater than 70 wt. %, and most preferably greater than 80 wt. %, for example greater than 90 wt. %. The cementitious reactive powder may optionally also include one or more aluminous cements and one or more source of calcium sulfates. The cementitious reactive powders are activated with an alkali metal chemical activator selected from alkali metal salt and/or alkali metal base. Methods for making the compositions are also disclosed.

The present invention relates to a method of preparing a geopolymer using a coal bottom ash. In the method, an alkali activating agent is used in a relatively smaller amount than in a conventional technology so that the mixture of the coal bottom ash and the alkali activating agent does not become a gel state, and a process for radiating a microwave is further provided after curing of a geopolymer specimen in an oven.

A method of producing a material. The material is produced by the steps of: providing a geopolymer mixture or solution comprising an aluminosilicate and an alkali material; allowing the geopolymer mixture or solution to partially set to form an at least partially set geopolymer including pore spaces; and exposing the at least partially set geopolymer to a metal silicate solution or mixture containing a metal silicate to allow the metal silicate to enter the pore spaces and react to form additional material within the pore spaces. The material may be used in well-cementing and as an abandonment plug.

The invention comprises a composition comprising hyaloclastite having a volume-based mean particle size of less than or equal to 40 m. The invention also comprises a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m. The invention further comprises a cementitious-based material comprising aggregate, a cementitious material comprising a hydraulic cement and hyaloclastite, wherein the hyaloclastite has a volume-based mean particle size of less than or equal to approximately 40 m and water sufficient to hydrate the cementitious material. A method of using the composition of the present invention is also disclosed.

A method for making geopolymer cementitious binder compositions for cementitious products such as concrete, precast construction elements and panels, mortar and repair materials, and the like is disclosed. The geopolymer cementitious compositions of some embodiments are made by mixing a synergistic mixture of thermally activated aluminosilicate mineral, calcium aluminate cement, a calcium sulfate and a chemical activator with water.