An object of the present invention is to provide a dental glass ionomer cement composition having high safety to a human body and sufficient working time, in which mechanical properties, mixing ability in hand mixing and dischargeability out of a container after mechanical kneading are simultaneously improved with satisfactory balance compared with the prior art. Disclosed is a dental glass ionomer cement composition including 0.001 to 3% by weight of (a) a polysaccharide nanofiber having an aspect ratio of 100 or more and an average fiber diameter of 100 nm or less.

An object of the present invention is to provide a dental glass ionomer cement composition having high safety to a human body and sufficient working time, in which mechanical properties, mixing ability in hand mixing and dischargeability out of a container after mechanical kneading are simultaneously improved with satisfactory balance compared with the prior art. Disclosed is a dental glass ionomer cement composition including 0.001 to 3% by weight of (a) a polysaccharide nanofiber having an aspect ratio of 100 or more and an average fiber diameter of 100 nm or less.

The invention discloses an environment-friendly cement self-repairing system, and its preparation method and application. The preparation method comprises the following steps: adding a shell curing agent into deionized water to prepare solution 1, adding an inorganic nano emulsifier into deionized water, ultrasonically dispersing, then adding polysaccharide-shell, and uniformly stirring to obtain emulsion polymerization aqueous phase; adding epoxy diluent into epoxy resin, and uniformly stirring; obtaining an emulsion polymerization oil phase; mixing the emulsion polymerization aqueous phase and emulsion polymerization oil phase, and stirring to obtain uniform emulsion; dropping the uniform emulsion into solution drop by drop by using pendant drop method, stirring until the droplets are shaped, then filtering, washing with deionized water, and drying to obtain self-repairing capsules; next, mixing with an environment-friendly curing agent to obtain an environment-friendly cement self-repairing system. The environment-friendly cement self-repairing system is green, nontoxic and harmless, has strong water absorption, can block tiny cracks by volume expansion when contacts with water, thus further enhances the cement self-repairing effect.

The invention discloses an environment-friendly cement self-repairing system, and its preparation method and application. The preparation method comprises the following steps: adding a shell curing agent into deionized water to prepare solution 1, adding an inorganic nano emulsifier into deionized water, ultrasonically dispersing, then adding polysaccharide-shell, and uniformly stirring to obtain emulsion polymerization aqueous phase; adding epoxy diluent into epoxy resin, and uniformly stirring; obtaining an emulsion polymerization oil phase; mixing the emulsion polymerization aqueous phase and emulsion polymerization oil phase, and stirring to obtain uniform emulsion; dropping the uniform emulsion into solution drop by drop by using pendant drop method, stirring until the droplets are shaped, then filtering, washing with deionized water, and drying to obtain self-repairing capsules; next, mixing with an environment-friendly curing agent to obtain an environment-friendly cement self-repairing system. The environment-friendly cement self-repairing system is green, nontoxic and harmless, has strong water absorption, can block tiny cracks by volume expansion when contacts with water, thus further enhances the cement self-repairing effect.

The present invention provides a fiber-reinforced cement composition comprising; cement, fiber, silica, filler, expanded perlite, and polymer. The fiber-reinforced cement composition according to the present invention has low density, high toughness and flexural strength, and not contains volatile composition. When it is molded into workpiece, the workpiece is lightweight, easy to be cut and/or lathed into desired shapes, drilled and fixed with screws and/or repeatedly nailed at the same position, tolerant to humidity, termites and insects, inflammable and does not produce powder when cut, drilled and/or lathed that is hazardous to the workers. Therefore, it is suitably applicable for being utilized as a material for manufacturing furniture parts.

The present invention provides a fiber-reinforced cement composition comprising; cement, fiber, silica, filler, expanded perlite, and polymer. The fiber-reinforced cement composition according to the present invention has low density, high toughness and flexural strength, and not contains volatile composition. When it is molded into workpiece, the workpiece is lightweight, easy to be cut and/or lathed into desired shapes, drilled and fixed with screws and/or repeatedly nailed at the same position, tolerant to humidity, termites and insects, inflammable and does not produce powder when cut, drilled and/or lathed that is hazardous to the workers. Therefore, it is suitably applicable for being utilized as a material for manufacturing furniture parts.

Cementitious compositions and methods for the preparation of corresponding cementitious compositions, appropriate oxidatively degraded polysaccharides and methods for producing the same, as well as the use of oxidatively degraded polysaccharides as water reducing agents in cementitious compositions, wherein the compositions include an oxidatively degraded polysaccharide as a water reducing agent to provide similar water reducing properties to cementitious composition formulated with lignosulfonates. The oxidatively degraded polysaccharides have the advantage over lignosulfonates of a lower price and a more consistent quality and are expected to be compatible with polycarboxylatether cement additives.

Cementitious compositions and methods for the preparation of corresponding cementitious compositions, appropriate oxidatively degraded polysaccharides and methods for producing the same, as well as the use of oxidatively degraded polysaccharides as water reducing agents in cementitious compositions, wherein the compositions include an oxidatively degraded polysaccharide as a water reducing agent to provide similar water reducing properties to cementitious composition formulated with lignosulfonates. The oxidatively degraded polysaccharides have the advantage over lignosulfonates of a lower price and a more consistent quality and are expected to be compatible with polycarboxylatether cement additives.

Processes disclosed are capable of converting biomass into high-crystallinity, hydrophobic cellulose. In some variations, the process includes fractionating biomass with an acid (such as sulfur dioxide), a solvent (such as ethanol), and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin; and depositing lignin onto cellulose fibers to produce lignin-coated cellulose materials (such as dissolving pulp). The crystallinity of the cellulose material may be 80% or higher, translating into good reinforcing properties for composites. Optionally, sugars derived from amorphous cellulose and hemicellulose may be separately fermented, such as to monomers for various polymers. These polymers may be combined with the hydrophobic cellulose to form completely renewable composites.

Processes disclosed are capable of converting biomass into high-crystallinity, hydrophobic cellulose. In some variations, the process includes fractionating biomass with an acid (such as sulfur dioxide), a solvent (such as ethanol), and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin; and depositing lignin onto cellulose fibers to produce lignin-coated cellulose materials (such as dissolving pulp). The crystallinity of the cellulose material may be 80% or higher, translating into good reinforcing properties for composites. Optionally, sugars derived from amorphous cellulose and hemicellulose may be separately fermented, such as to monomers for various polymers. These polymers may be combined with the hydrophobic cellulose to form completely renewable composites.