Various embodiments disclosed relate to a curable composition and resin for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in a subterranean formation a curable composition. The curable composition can include an epoxy silane monomer, a hardener, and carrier fluid. The curable composition can include an epoxy monomer, an amine silane hardener, and carrier fluid. The method can also include curing the curable composition to form an epoxy silane resin.

The present disclosure relates to a liquid agent that mitigates shrinkage of cement, particularly cement used in a hydrocarbon-producing well. The anti-shrinkage agent includes a slow-setting calcium aluminate cement as well as gypsum and may exhibit shelf-life stability, physical stability, or both. The present disclosure further relates to methods of cementing a hydrocarbon-producing well using the anti-shrinkage agent and to cements containing the anti-shrinkage agent.

The present disclosure relates to a liquid agent that mitigates shrinkage of cement, particularly cement used in a hydrocarbon-producing well. The anti-shrinkage agent includes a slow-setting calcium aluminate cement as well as gypsum and may exhibit shelf-life stability, physical stability, or both. The present disclosure further relates to methods of cementing a hydrocarbon-producing well using the anti-shrinkage agent and to cements containing the anti-shrinkage agent.

A manufacturing process of a cement product includes: (1) incorporating at least one additive into a high-alumina cement composition, wherein the at least one additive is selected from nitrate-containing salts, nitrite-containing salts, carbonate-containing salts, sulfate-containing salts, chloride-containing salts, and hydroxide-containing salts; and (2) curing the high-alumina cement composition to form the cement product.

Capsules with a cement additive covered by a polymeric outer shell are added to wellbore cement. The additive is released from the shells by osmosis or shell ruptures. Capillary forces draw the additive into micro-annuli or cracks present in the cement, where the additive seals the micro-annuli and cracks to define a self-sealing material. The empty shells remain in the cement and act as an additive that modifies cement elasticity. The capsules are formed by combining immiscible liquids, where one of the liquids contains a signaling substance, and each of the liquids contains a reagent. When combined, the liquids segregate into a dispersed phase and a continuous phase, with the dispersed phase having the signaling agent. The reagents react at interfaces between dispersed and continuous phases and form polymer layers encapsulating the signaling agent to form the capsules. Adjusting relative concentrations of the reagents varies membrane strength and permeability.

Capsules with a cement additive covered by a polymeric outer shell are added to wellbore cement. The additive is released from the shells by osmosis or shell ruptures. Capillary forces draw the additive into micro-annuli or cracks present in the cement, where the additive seals the micro-annuli and cracks to define a self-sealing material. The empty shells remain in the cement and act as an additive that modifies cement elasticity. The capsules are formed by combining immiscible liquids, where one of the liquids contains a signaling substance, and each of the liquids contains a reagent. When combined, the liquids segregate into a dispersed phase and a continuous phase, with the dispersed phase having the signaling agent. The reagents react at interfaces between dispersed and continuous phases and form polymer layers encapsulating the signaling agent to form the capsules. Adjusting relative concentrations of the reagents varies membrane strength and permeability.

The disclosed subject matter concerns earth based mixtures, methods of preparing mixtures, and a process of forming articles of manufacture, as well as a process of manufacturing articles in molds configured for compression molding of earth based mixtures in accordance with the disclosed subject matter, including mixtures containing one or more of, e.g., sand, silt, clay, minerals, or any combination thereof.

The disclosed subject matter concerns earth based mixtures, methods of preparing mixtures, and a process of forming articles of manufacture, as well as a process of manufacturing articles in molds configured for compression molding of earth based mixtures in accordance with the disclosed subject matter, including mixtures containing one or more of, e.g., sand, silt, clay, minerals, or any combination thereof.

Various embodiments disclosed relate to a weighted composition for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in a subterranean formation a weighted composition. The weighted composition can include a weighting agent and an inorganic coating material on the weighting agent. The inorganic coating material can be a crystalline inorganic coating material. The inorganic coating material can be an amorphous inorganic coating material.

Various embodiments disclosed relate to a weighted composition for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in a subterranean formation a weighted composition. The weighted composition can include a weighting agent and an inorganic coating material on the weighting agent. The inorganic coating material can be a crystalline inorganic coating material. The inorganic coating material can be an amorphous inorganic coating material.