An embodiment comprises a method of treating a subterranean formation comprising: providing a treatment fluid comprising a kiln dust, biowaste ash, and water; and introducing the treatment fluid into a subterranean formation. Another embodiment comprises a method of cementing comprising: introducing a cement composition into a subterranean formation, wherein the cement composition comprises a kiln dust, biowaste ash, and water; and allowing the cement composition to set in the subterranean formation. Yet another embodiment comprises a method comprising: providing a spacer fluid comprising biowaste ash and water; introducing the spacer fluid into a well bore to displace at least a portion of a first fluid from the well bore; and introducing a cement composition into the well bore, wherein the spacer fluid separates the cement composition and the first fluid.

An embodiment comprises a method of treating a subterranean formation comprising: providing a treatment fluid comprising a kiln dust, biowaste ash, and water; and introducing the treatment fluid into a subterranean formation. Another embodiment comprises a method of cementing comprising: introducing a cement composition into a subterranean formation, wherein the cement composition comprises a kiln dust, biowaste ash, and water; and allowing the cement composition to set in the subterranean formation. Yet another embodiment comprises a method comprising: providing a spacer fluid comprising biowaste ash and water; introducing the spacer fluid into a well bore to displace at least a portion of a first fluid from the well bore; and introducing a cement composition into the well bore, wherein the spacer fluid separates the cement composition and the first fluid.

The invention provides novel methods and compositions that mitigate the occurrence of hazing of products made from carbonatable calcium silicate-based cements. The methods and compositions of the invention may be applied in a variety of cement and concrete components in the infrastructure, construction, pavement and landscaping industries.

Expansive cement compositions for use in subterranean wellbores that include a monophase amorphous hydraulic binder material (MAHBM). The MAHBM may include a plurality of particles having a silica core and an amorphous coating substantially surrounding the silica core. The coating may comprise, for example, a plurality of amorphous α-dicalcium silicate hydrate nanoparticles or microparticles. The MAHBM may be used as an expansion agent in a cement composition or used as an expansive cement by itself.

The present invention provides calcium sulphate-based product having reduced shrinkage after exposure to high temperatures, the product comprising gypsum, a pozzolan source e.g. in an amount between 4-27 wt %) and a metal salt additive in an amount between 0.5 and 10 wt %). The pozzolan source may be selected from a kaolinitic clay material, fly ash, rice husk ash, diatomaceous earths, volcanic ashes and pumices, micro-silica, silica fume and silicone oil, The metal salt additive may be a metal salt which decomposes between a temperature of 300-500° C. to yield a metal oxide, e.g. magnesium nitrate.

The present invention provides calcium sulphate-based product having reduced shrinkage after exposure to high temperatures, the product comprising gypsum, a pozzolan source e.g. in an amount between 4-27 wt %) and a metal salt additive in an amount between 0.5 and 10 wt %). The pozzolan source may be selected from a kaolinitic clay material, fly ash, rice husk ash, diatomaceous earths, volcanic ashes and pumices, micro-silica, silica fume and silicone oil, The metal salt additive may be a metal salt which decomposes between a temperature of 300-500° C. to yield a metal oxide, e.g. magnesium nitrate.

The present invention provides calcium sulphate-based product having reduced shrinkage after exposure to high temperatures, the product comprising gypsum, a pozzolan source e.g. in an amount between 4-27 wt %) and a metal salt additive in an amount between 0.5 and 10 wt %). The pozzolan source may be selected from a kaolinitic clay material, fly ash, rice husk ash, diatomaceous earths, volcanic ashes and pumices, micro-silica, silica fume and silicone oil, The metal salt additive may be a metal salt which decomposes between a temperature of 300-500° C. to yield a metal oxide, e.g. magnesium nitrate.

A cementitious composition with accelerated curing at low temperatures particularly at temperatures <5° C., especially at temperatures <0° C. The cementitious composition consists of 2 components with a first component A including at least one ordinary Portland cement, at least one cement selected from calcium aluminate cement and/or calcium sulfoaluminate cement, a powder P, selected from the group consisting of carbonates or hydrogen carbonates of alkali and/or alkaline earth metals, optionally aggregates, optionally other additives and a second component B comprising at least one accelerator, an anti-freeze agent, water, and optionally other additives. The composition shows increased development of compressive strength, maintain good workability, and have particularly low shrinkage, also when cured at temperatures <5° C., especially <0° C., and as low as −10° C.

The disclosed subject matter concerns earth based mixtures, methods of preparing mixtures, and a process of forming articles of manufacture, as well as a process of manufacturing articles in molds configured for compression molding of earth based mixtures in accordance with the disclosed subject matter, including mixtures containing one or more of, e.g., sand, silt, clay, minerals, or any combination thereof.

The disclosed subject matter concerns earth based mixtures, methods of preparing mixtures, and a process of forming articles of manufacture, as well as a process of manufacturing articles in molds configured for compression molding of earth based mixtures in accordance with the disclosed subject matter, including mixtures containing one or more of, e.g., sand, silt, clay, minerals, or any combination thereof.