A geopolymeric ink formulation for direct 3D printing containing a geopolymeric formulation whose components are present in such proportions as to be subjected to a geopolymerization reaction and to provide, at the end of the reaction, a solid geopolymer and wherein the formulation, before and during at least a part of the geopolymerization reaction, wherein three-dimensional chemical bonds have not yet been formed, forms a reversible-gel, non-Newtonian, viscoelastic fluid. The formulation is extruded through a 3D printing tool equipped with nozzle into strands according to a geometry such as to create a three-dimensional structure on one or more layers. The extrusion preferably takes place within a hydrophobic liquid, such as oil.

A geopolymeric ink formulation for direct 3D printing containing a geopolymeric formulation whose components are present in such proportions as to be subjected to a geopolymerization reaction and to provide, at the end of the reaction, a solid geopolymer and wherein the formulation, before and during at least a part of the geopolymerization reaction, wherein three-dimensional chemical bonds have not yet been formed, forms a reversible-gel, non-Newtonian, viscoelastic fluid. The formulation is extruded through a 3D printing tool equipped with nozzle into strands according to a geometry such as to create a three-dimensional structure on one or more layers. The extrusion preferably takes place within a hydrophobic liquid, such as oil.

A geopolymeric ink formulation for direct 3D printing containing a geopolymeric formulation whose components are present in such proportions as to be subjected to a geopolymerization reaction and to provide, at the end of the reaction, a solid geopolymer and wherein the formulation, before and during at least a part of the geopolymerization reaction, wherein three-dimensional chemical bonds have not yet been formed, forms a reversible-gel, non-Newtonian, viscoelastic fluid. The formulation is extruded through a 3D printing tool equipped with nozzle into strands according to a geometry such as to create a three-dimensional structure on one or more layers. The extrusion preferably takes place within a hydrophobic liquid, such as oil.

Rapid setting high strength calcium phosphate cements and methods of using the same are provided. Aspects of the cements include fine and coarse calcium phosphate particulate reactants and a cyclodextrin which, upon combination with a setting fluid, produce a flowable composition that rapidly sets into a high strength product. The flowable compositions find use in a variety of different applications, including the repair of hard tissue defects, e.g., bone defects such as fractures.

The present invention provides a dentinal tubule occlusion material excellent in terms of initial degree of dentinal tubule occlusion, resistance of dentinal tubule occlusion to acids, handling properties, and storage stability. The present invention relates to an one-pack type dentinal tubule occlusion material comprising fluorapatite particles (A) having an average particle diameter of 0.6 to 10 μm, inorganic particles (B) having an average particle diameter of 0.6 to 10 μm and reactive with water to form apatite, and a non-aqueous dispersant (C).

The present invention provides a dentinal tubule occlusion material excellent in terms of initial degree of dentinal tubule occlusion, resistance of dentinal tubule occlusion to acids, handling properties, and storage stability. The present invention relates to an one-pack type dentinal tubule occlusion material comprising fluorapatite particles (A) having an average particle diameter of 0.6 to 10 μm, inorganic particles (B) having an average particle diameter of 0.6 to 10 μm and reactive with water to form apatite, and a non-aqueous dispersant (C).

The present invention relates to a cementitous composite specifically engineered to possess self-cleaning abilities while maintaining their unique strain-hardening behaviour and the preparation of the said composite. The cementitious composite comprises a hydraulic cement, a plurality of fibers, in particular polyvinyl alcohol fibers wherein the ratio of the plurality of fibers to the hydraulic cement is in a range from 1 to 3% by volume; a self-cleaning agent, in particular nanoparticulate titanium dioxide (TiO.sub.2) wherein the weight ratio of the self-cleaning agent to the hydraulic cement is in a range from 0.01 to 1.

The present invention relates to a cementitous composite specifically engineered to possess self-cleaning abilities while maintaining their unique strain-hardening behaviour and the preparation of the said composite. The cementitious composite comprises a hydraulic cement, a plurality of fibers, in particular polyvinyl alcohol fibers wherein the ratio of the plurality of fibers to the hydraulic cement is in a range from 1 to 3% by volume; a self-cleaning agent, in particular nanoparticulate titanium dioxide (TiO.sub.2) wherein the weight ratio of the self-cleaning agent to the hydraulic cement is in a range from 0.01 to 1.

The present invention relates to a cementitous composite specifically engineered to possess self-cleaning abilities while maintaining their unique strain-hardening behaviour and the preparation of the said composite. The cementitious composite comprises a hydraulic cement, a plurality of fibers, in particular polyvinyl alcohol fibers wherein the ratio of the plurality of fibers to the hydraulic cement is in a range from 1 to 3% by volume; a self-cleaning agent, in particular nanoparticulate titanium dioxide (TiO.sub.2) wherein the weight ratio of the self-cleaning agent to the hydraulic cement is in a range from 0.01 to 1.

Hexavalent chromium-free slurries are provided that are capable of achieving a full cure at temperatures as low as 330-450 degrees F., thus making the coatings especially suitable for application on temperature sensitive base materials. The slurries are suitable in the production of protective coating systems formed by novel silicate-based basecoats that are sealed with novel phosphate-based topcoats. The coating systems exhibit acceptable corrosion and heat resistance and are capable of replacing traditional chromate-containing coating systems.