A ceramic article and method of manufacturing. The ceramic article comprises a porous ceramic material having a microstructure comprising an interconnected network of porous spheroidal ceramic beads. The microstructure has a total open porosity defined as the sum of an open intrabead porosity of the beads and an interbead porosity defined by interstices between the beads in the interconnected network. The microstructure has a bimodal pore size distribution having an intrabead peak corresponding to the open intrabead porosity and an interbead peak corresponding to the interbead porosity. An intrabead median pore size of the intrabead porosity is less than an interbead median pore size of the interbead porosity.

Herein is disclosed a method of producing a ceramic support suitable for a catalyst, the method comprising providing a porous ceramic structure, comprising a body portion with a monomodal macropore structure, wherein the macropores comprises a first mean pore size; washcoating the porous ceramic structure using a suspension comprising oxide and/or hydroxide nanoparticles and drying and calcinating the washcoated porous ceramic structure at a temperature below the melting point of the nanoparticles. In addition, the ceramic support and its structure is disclosed.

Herein is disclosed a method of producing a ceramic support suitable for a catalyst, the method comprising providing a porous ceramic structure, comprising a body portion with a monomodal macropore structure, wherein the macropores comprises a first mean pore size; washcoating the porous ceramic structure using a suspension comprising oxide and/or hydroxide nanoparticles and drying and calcinating the washcoated porous ceramic structure at a temperature below the melting point of the nanoparticles. In addition, the ceramic support and its structure is disclosed.

A particulate filter and method of manufacture. The particulate filter comprises a ceramic honeycomb body comprising a plurality of intersecting walls that define a plurality of channels extending longitudinally though the ceramic honeycomb body. The intersecting walls comprise a porous ceramic material having a microstructure that comprises an interconnected network of porous spheroidal ceramic beads. The microstructure has a total porosity defined as the sum of an open intrabead porosity of the beads and an interbead porosity defined by interstices between the beads in the interconnected network. The microstructure has a bimodal pore size distribution in which an intrabead median pore size of the intrabead porosity is from 1.5 μm to 4 μm and an interbead median pore size of the interbead porosity is from 6 μm to 20 μm.

A particulate filter and method of manufacture. The particulate filter comprises a ceramic honeycomb body comprising a plurality of intersecting walls that define a plurality of channels extending longitudinally though the ceramic honeycomb body. The intersecting walls comprise a porous ceramic material having a microstructure that comprises an interconnected network of porous spheroidal ceramic beads. The microstructure has a total porosity defined as the sum of an open intrabead porosity of the beads and an interbead porosity defined by interstices between the beads in the interconnected network. The microstructure has a bimodal pore size distribution in which an intrabead median pore size of the intrabead porosity is from 1.5 μm to 4 μm and an interbead median pore size of the interbead porosity is from 6 μm to 20 μm.

A manufacturing method of a honeycomb structure including: a dry mixing step of dry-mixing raw materials to form the honeycomb structure by a batch treatment, a wet mixing step of adding a liquid including at least one selected from the group consisting of water, a surfactant, a lubricant and a plasticizer to a dry mixture obtained in the dry mixing step, to perform wet mixing, a kneading step of kneading a wet mixture obtained in the wet mixing step, and a forming step of extruding a forming material prepared in the kneading step, wherein in the dry mixing step, a used forming material passed through the forming step is added as a part of the raw material, to perform dry mixing, and the kneading step includes a liquid re-adding step of further adding the liquid in a process of kneading the wet mixture.

A manufacturing method of a honeycomb structure including: a dry mixing step of dry-mixing raw materials to form the honeycomb structure by a batch treatment, a wet mixing step of adding a liquid including at least one selected from the group consisting of water, a surfactant, a lubricant and a plasticizer to a dry mixture obtained in the dry mixing step, to perform wet mixing, a kneading step of kneading a wet mixture obtained in the wet mixing step, and a forming step of extruding a forming material prepared in the kneading step, wherein in the dry mixing step, a used forming material passed through the forming step is added as a part of the raw material, to perform dry mixing, and the kneading step includes a liquid re-adding step of further adding the liquid in a process of kneading the wet mixture.

An extrudable ceramic precursor mixture and method of use includes: an inorganic ceramic-forming component, a first siloxane prepolymer, a second siloxane prepolymer with a different composition than the first siloxane prepolymer, a catalyst adapted to catalyze polymerization of the first siloxane prepolymer with the second siloxane prepolymer into a siloxane-based polymer, and a thermally curable siloxane-based cross-linking agent adapted to crosslink the siloxane-based polymer. Comprised is a polydimethylsiloxane having a vinyl functional group and a polydimethylsiloxane having a silicon hydride functional group.

An extrudable ceramic precursor mixture and method of use includes: an inorganic ceramic-forming component, a first siloxane prepolymer, a second siloxane prepolymer with a different composition than the first siloxane prepolymer, a catalyst adapted to catalyze polymerization of the first siloxane prepolymer with the second siloxane prepolymer into a siloxane-based polymer, and a thermally curable siloxane-based cross-linking agent adapted to crosslink the siloxane-based polymer. Comprised is a polydimethylsiloxane having a vinyl functional group and a polydimethylsiloxane having a silicon hydride functional group.

A method of making a porous cordierite ceramic article using chlorite raw material is described herein. The method includes mixing materials to form a cordierite-forming mixture. The cordierite-forming mixture includes a chlorite raw material in an amount of about 5% to about 60% by weight and a platy aluminum silicate raw material in an amount of 0% to about 30% by weight of the total inorganic content of the cordierite-forming mixture. The cordierite-forming mixture is then formed into a green body and fired to form the porous cordierite ceramic article. In some cases, the porous cordierite ceramic article exhibits a low coefficient of thermal expansion (CTE), which provides the article with high thermal shock resistance.