A method for manufacturing a pillar-shaped honeycomb structure filter including; attaching ceramic particles to a surface of the first cells by ejecting an aerosol including the ceramic particles toward the inlet side end surface from a direction perpendicular to the inlet side end surface while applying a suction force to the outlet side end surface to suck the ejected aerosol from the inlet side end surface, wherein the ejection of the aerosol is carried out using an aerosol generator including a drive gas flow path for flowing a pressurized drive gas, a supply port provided on the way of the drive gas flow path and capable of sucking the ceramic particles from an outer peripheral side of the drive gas flow path toward an inside of the drive gas flow path, and a nozzle attached to a tip of the drive gas flow path and capable of ejecting the aerosol.

A method for manufacturing a pillar-shaped honeycomb structure filter including; attaching ceramic particles to a surface of the first cells by ejecting an aerosol including the ceramic particles toward the inlet side end surface from a direction perpendicular to the inlet side end surface while applying a suction force to the outlet side end surface to suck the ejected aerosol from the inlet side end surface, wherein the ejection of the aerosol is carried out using an aerosol generator including a drive gas flow path for flowing a pressurized drive gas, a supply port provided on the way of the drive gas flow path and capable of sucking the ceramic particles from an outer peripheral side of the drive gas flow path toward an inside of the drive gas flow path, and a nozzle attached to a tip of the drive gas flow path and capable of ejecting the aerosol.

A honeycomb structure includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells, which serving as fluid through channels extending from a first end face to a second end face, wherein the plurality of cells includes: large opening cells having a large opening area on the first end face and the second end face; and small opening cells having an opening area smaller than that of the large opening cells on the first end face and the second end face, a ratio of an opening diameter of the large opening cells to an opening diameter of the small opening cells is larger than 1.11 and smaller than 1.28, and the opening diameter of the small opening cells is larger than 0.78 mm, and a cell density of the honeycomb structure body is larger than 93 pcs/cm.sup.2 and smaller than 104 pcs/cm.sup.2.

A honeycomb structure includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells, which serving as fluid through channels extending from a first end face to a second end face, wherein the plurality of cells includes: large opening cells having a large opening area on the first end face and the second end face; and small opening cells having an opening area smaller than that of the large opening cells on the first end face and the second end face, a ratio of an opening diameter of the large opening cells to an opening diameter of the small opening cells is larger than 1.11 and smaller than 1.28, and the opening diameter of the small opening cells is larger than 0.78 mm, and a cell density of the honeycomb structure body is larger than 93 pcs/cm.sup.2 and smaller than 104 pcs/cm.sup.2.

A ceramic honeycomb structure comprising large numbers of cells partitioned by porous cell walls, the cell walls having (a) porosity of 50-80%, and when measured by mercury porosimetry, (b) a median pore diameter being 25-50 μm, (c) (i) a cumulative pore volume in a pore diameter range of 20 μm or less being 25% or less of the total pore volume, (ii) a cumulative pore volume in a pore diameter range of more than 20 μm and 50 μm or less being 50% or more of the total pore volume, and (iii) a cumulative pore volume in a pore diameter range of more than 50 μm being 12% or more of the total pore volume.

A ceramic honeycomb structure comprising large numbers of cells partitioned by porous cell walls, the cell walls having (a) porosity of 50-80%, and when measured by mercury porosimetry, (b) a median pore diameter being 25-50 μm, (c) (i) a cumulative pore volume in a pore diameter range of 20 μm or less being 25% or less of the total pore volume, (ii) a cumulative pore volume in a pore diameter range of more than 20 μm and 50 μm or less being 50% or more of the total pore volume, and (iii) a cumulative pore volume in a pore diameter range of more than 50 μm being 12% or more of the total pore volume.

A particulate filter and method of manufacture. The particulate filter includes intersecting walls that define longitudinally extending channels The intersecting walls comprise a porous ceramic material having a bare microstructure that comprises an interconnected network of porous spheroidal ceramic beads that has an open intrabead porosity within the beads and an interbead porosity defined by interstices between the beads. Catalyst particles are deposited at least partially within the intrabead porosity within the interbead porosity. The bare microstructure has a bimodal pore size distribution in which an intrabead median pore size of the intrabead porosity is less than an interbead median pore size of the interbead porosity. The filter has a trimodal pore size distribution comprising a first peak corresponding to the interbead porosity, a second peak corresponding to the intrabead porosity, and a third peak corresponding to the intrabead porosity as blocked by the catalyst particles.

A particulate filter and method of manufacture. The particulate filter includes intersecting walls that define longitudinally extending channels The intersecting walls comprise a porous ceramic material having a bare microstructure that comprises an interconnected network of porous spheroidal ceramic beads that has an open intrabead porosity within the beads and an interbead porosity defined by interstices between the beads. Catalyst particles are deposited at least partially within the intrabead porosity within the interbead porosity. The bare microstructure has a bimodal pore size distribution in which an intrabead median pore size of the intrabead porosity is less than an interbead median pore size of the interbead porosity. The filter has a trimodal pore size distribution comprising a first peak corresponding to the interbead porosity, a second peak corresponding to the intrabead porosity, and a third peak corresponding to the intrabead porosity as blocked by the catalyst particles.

The disclosure provides for a mixture suitable for extrusion and firing to form a ceramic honeycomb substrate, said mixture comprising a batch composition selected from the group consisting of a cordierite batch composition and an aluminum titanate batch composition, an optional pore former material; a binder material and water; wherein said binder is a methyl ether of cellulose binder having a count of less than 300 water-insoluble fibers per gram of binder material.

The disclosure provides for a mixture suitable for extrusion and firing to form a ceramic honeycomb substrate, said mixture comprising a batch composition selected from the group consisting of a cordierite batch composition and an aluminum titanate batch composition, an optional pore former material; a binder material and water; wherein said binder is a methyl ether of cellulose binder having a count of less than 300 water-insoluble fibers per gram of binder material.