Disclosed are a carbon nanotube (CNT)-based three-dimensional ordered macroporous (3DOM) carbon material and a preparation method thereof. The CNT-based 3DOM carbon material comprises a honeycomb network structure having a 3DOM structure formed by overlapping CNTs, wherein ordered macropores each have a diameter of 270 nm to 360 nm, and the CNTs each have an outer diameter of 8 nm to 20 nm

Disclosed are a carbon nanotube (CNT)-based three-dimensional ordered macroporous (3DOM) carbon material and a preparation method thereof. The CNT-based 3DOM carbon material comprises a honeycomb network structure having a 3DOM structure formed by overlapping CNTs, wherein ordered macropores each have a diameter of 270 nm to 360 nm, and the CNTs each have an outer diameter of 8 nm to 20 nm

Provided is a C/C composite having a long life in an environment including a heating process and a cooling process and having less adverse effects on surrounding facilities and the quality of treatment objects. A C/C composite in which, in measurement for open pores by mercury porosimetry, an open porosity for open pores with a radius of not less than 0.4 μm and less than 10 μm in the C/C composite is 2.0% or less.

Provided is a C/C composite having a long life in an environment including a heating process and a cooling process and having less adverse effects on surrounding facilities and the quality of treatment objects. A C/C composite in which, in measurement for open pores by mercury porosimetry, an open porosity for open pores with a radius of not less than 0.4 μm and less than 10 μm in the C/C composite is 2.0% or less.

The present invention concerns a process for the preparation of a porous carbon structure comprising the steps: a) providing a template comprising voids, b) filling of at least part of the voids with a precursor for the formation of the porous carbon structure, c) carbonizing the precursor for the formation of the porous carbon structure and d) removing at least part of the template. In preferred embodiments the precursor for the formation of the porous carbon structure is a formaldehyde-phenol resin, especially a cross-linked resorcinol-formaldehyde resin. The template further preferably comprises a block copolymer and an amphiphilic molecule, wherein the block copolymer comprises polymeric units of at least one lipophilic monomer and polymeric units of at least one hydrophilic monomer. Further preferred is a process wherein the template comprises a bimodal mixture of particles of silicon dioxide.

The present invention concerns a process for the preparation of a porous carbon structure comprising the steps: a) providing a template comprising voids, b) filling of at least part of the voids with a precursor for the formation of the porous carbon structure, c) carbonizing the precursor for the formation of the porous carbon structure and d) removing at least part of the template. In preferred embodiments the precursor for the formation of the porous carbon structure is a formaldehyde-phenol resin, especially a cross-linked resorcinol-formaldehyde resin. The template further preferably comprises a block copolymer and an amphiphilic molecule, wherein the block copolymer comprises polymeric units of at least one lipophilic monomer and polymeric units of at least one hydrophilic monomer. Further preferred is a process wherein the template comprises a bimodal mixture of particles of silicon dioxide.

Methods of forming a carbon fiber reinforced carbon foam are provided. Such a method may comprise heating a porous body composed of a solid material comprising covalently bound carbon atoms and heteroatoms and having a surface defining pores distributed throughout the solid material, in the presence of an added source of gaseous hydrocarbons. The heating generates free radicals in the porous body from the heteroatoms and induces reactions between the free radicals and the gaseous hydrocarbons to form covalently bound carbon nanofibers extending from the surface of the solid material and a network of entangled carbon microfibers within the pores the porous body, thereby forming a carbon fiber reinforced carbon foam. Carbon fiber reinforced carbon foams and ballistic barriers incorporating the foams are also provided.

Methods of forming a carbon fiber reinforced carbon foam are provided. Such a method may comprise heating a porous body composed of a solid material comprising covalently bound carbon atoms and heteroatoms and having a surface defining pores distributed throughout the solid material, in the presence of an added source of gaseous hydrocarbons. The heating generates free radicals in the porous body from the heteroatoms and induces reactions between the free radicals and the gaseous hydrocarbons to form covalently bound carbon nanofibers extending from the surface of the solid material and a network of entangled carbon microfibers within the pores the porous body, thereby forming a carbon fiber reinforced carbon foam. Carbon fiber reinforced carbon foams and ballistic barriers incorporating the foams are also provided.

Provided is a method of producing an integral 3D humic acid-carbon hybrid foam, comprising: (A) forming a solid shape of humic acid-polymer particle mixture; and (B) pyrolyzing the solid shape of humic acid-polymer particle mixture to thermally reduce humic acid into reduced humic acid sheets and thermally convert polymer into pores and carbon or graphite that bonds the reduced humic acid sheets to form the integral 3D humic acid-carbon hybrid foam.

Provided is a method of producing an integral 3D humic acid-carbon hybrid foam, comprising: (A) forming a solid shape of humic acid-polymer particle mixture; and (B) pyrolyzing the solid shape of humic acid-polymer particle mixture to thermally reduce humic acid into reduced humic acid sheets and thermally convert polymer into pores and carbon or graphite that bonds the reduced humic acid sheets to form the integral 3D humic acid-carbon hybrid foam.