To form, on a ceramic member or a metal member, a thermal spray ceramic coating film which achieves both the quality of a ceramic coating film and gas barrier property, and with which a composite oxide having a melting point lower than the ambient temperature will not form when used as a coating film on a ceramic member or a metal member constituting a glass article manufacturing apparatus.

A ceramic coating film-provided member comprising a ceramic member or a metal member and a thermal spray ceramic coating film formed on at least a part of the surface of the ceramic member or the metal member, wherein the thermal spray ceramic coating film contains Al.sub.2O.sub.3 and 12CaO.7Al.sub.2O.sub.3, and the weight ratio of CaO to Al.sub.2O.sub.3 (CaO/Al.sub.2O.sub.3) is more than 0.11 to 0.50.

Disclosed is a concrete mixture comprising an amount of coarse aggregate, an amount of cement, an amount of crumb rubber, and an amount of steel fibers. Also disclosed are methods for the manufacture of same.

A temperature-sensitive anti-freezing material for asphalt pavement and a method for preparing same. A temperature-sensitive macro molecular organic matter is employed in the anti-freezing material instead of a traditional sustained release agent, and coated on the surface of the chloride particle having an anti-icing anti-freezing effect; and then the temperature-sensitive anti-freezing material for asphalt pavement is prepared by sieving and drying processes. The anti-freezing material can automatically respond to and control the release temperature of the chloride in the anti-freezing material according to the outside temperature, increase the anti-freezing effect duration of the chloride in the asphalt pavement effectively, and extend the service lifetime of the anti-freezing material.

A temperature-sensitive anti-freezing material for asphalt pavement and a method for preparing same. A temperature-sensitive macro molecular organic matter is employed in the anti-freezing material instead of a traditional sustained release agent, and coated on the surface of the chloride particle having an anti-icing anti-freezing effect; and then the temperature-sensitive anti-freezing material for asphalt pavement is prepared by sieving and drying processes. The anti-freezing material can automatically respond to and control the release temperature of the chloride in the anti-freezing material according to the outside temperature, increase the anti-freezing effect duration of the chloride in the asphalt pavement effectively, and extend the service lifetime of the anti-freezing material.

Disclosed are an exterior insulation mortar for cold weather which may prevent freezing and improve strength at temperatures below 0 C., and an exterior insulation system using the same.

An anti-corrosive concrete grouting material for coastal structure connection and a method for preparing the same, belonging to the technical field of anti-corrosion of coastal assembled structure connectors. The grouting material includes the following components: expansible compound cement, slag sand, fly ash (FA), polyvinyl alcohol (PVA) (containing an oxidant and a catalyst), graphene oxide (GO), a water reducer, an adjusting admixture, a defoaming agent, a mineral admixture and water. A shrinkage-free effect of the grouting material is realized through internal curing of GO-PVA hydrogel, micro-expansion of the compound cement and shrinkage reduction effect of the FA; an energy storage effect of a GO-PVA hydrogel micro-capacitor is exerted to avoid formation of a reinforcement corrosion micro-battery in a grouting material sleeve, a reinforcement corrosion self-immune effect is achieved, seawater corrosion resistance of the grouting material is improved by the slag sand, and it has huge economic and environmental protection benefits.

A cement grout material which does not freeze even in an environment where the ambient temperature can be 5 C. or below, and does not require fuel or large-scaled equipment for maintaining curing temperature. Lithium nitrite is added to a cement grout material that contains cement, water and an admixture. By setting the weight ratio of the lithium nitrite to the cement to a value from 3 to 10% by weight, freezing of the grout material is able to be prevented even in an installation environment where the ambient temperature can be 5 C. during the initial stage of installation. By setting the weight ratio of the lithium nitrite to the cement to a value from 4.5 to 8% by weight, freezing of the grout material is able to be prevented even in an installation environment where the ambient temperature can be 10 C. during the initial stage of installation.