Disclosed are a nanoenergetic material composite-based solid propellant, a method of preparing the same, and a projectile using the same. The propellant includes: potassium nitrate-sucrose (KNSU) composite powder; and nanoenergetic material (nEM) composite powder in a solid powder form mixed with the KNSU composite powder to prepare a KNSU/nEM propellant. The method includes: preparing KNSU composite powder; preparing nEM composite powder; and preparing a KNSU/nEM propellant by mixing the KNSU composite powder and the nEM composite powder in a solid powder form. The projectile includes: a clay block; a clay nozzle responsible for releasing the pressure generated by explosion of a propellant; and a propellant lamination area disposed between the clay block and the clay nozzle. Upon ignition of the KNSU/nEM propellant, the nEM composite powder increases the combustion rate and combustion temperature of a potassium nitrate-sucrose (KNSU) propellant.

A method of forming polymer composites having transition metal oxide nanoparticles dispersed therein includes mixing a transition metal oxide precursor including at least one transition metal, a polymer as a binder, a solvent for the polymer, and water to form a first solution including polymer-transition metal complexes. The polymer-transition metal complexes are hydrolyzed to produce a plurality of transition metal oxide nanoparticles, wherein water is added in the mixing in a stoichiometric excess for the hydrolyzing. The solvent and residual of the water remaining after the hydrolyzing are removed. A polymer composite including a plurality of transition metal oxide nanoparticles dispersed in the polymer results after the removing, where some of the polymer is chemically conjugated to a surface of the transition metal oxide nanoparticles.

The present invention relates to a manufactured graphene/metal or metalloid core-shell composite and manufacturing method thereof. The method comprising: using a modified graphene oxide as a base, then performing concentration and steam drying followed by organic solvent replacement to obtain a modified graphene oxide organic solvent; using a liquid-phase self-assembly method to coat the modified graphene oxide onto a surface of the metal or metalloid to form a graphene/metal or metalloid coated particle solution, then filtering and drying to obtain the graphene metal/metalloid core-shell composite. The method improves upon a conventional organic and inorganic material coating technique, and reduces an impact of a water-based solvent and high temperature on a highly reactive metal and metalloid, thereby expanding the feasibility of the coating technique and addressing a barrier of applicability of graphene and reactive metal or metalloid in the field of energetic materials.

A pyrotechnic composition includes a fuel, an oxidizer, flow and rate control agents and oleoresin capsicum as an irritant. The composition is useful in crowd control products. The composition contains rate control ingredients to maintain combustion at a temperature below the point of degradation of the oleoresin capsicum, balanced with a booster material to maintain combustion.

The invention relates generally to burn rate modifiers and propellants comprising a burn rate modifier. The invention also relates to methods of producing a propellant comprising a burn rate modifier as well as an ammunition cartridge comprising the propellant. The burn rate modifier comprises a compound of formula 1 and the propellant comprises a compound of formula 1 and an energetic material. ##STR00001##

Disclosed herein are energetic compositions and methods of making thereof. A composition includes perchlorate or nitrate containing oxidizer particles, a polymeric binder, and a borylated ferrocene derivative bonding agent bonded to a surface of at least a portion the perchlorate or nitrate containing oxidizer particles to form a Lewis complex.

A precursor formulation comprising, before curing, a hydroxyl-terminated polybutadiene (HTPB) prepolymer or a hydroxyl-terminated polyether (HTPE) prepolymer, an oxidizer, a dimer fatty diol, and an isocyanate curative. A solid propellant comprising a reaction product of the HTPB prepolymer or HTPE prepolymer, the dimer fatty diol, and the isocyanate curative is also disclosed, as is a rocket motor comprising a case and a solid propellant in the case, the solid propellant comprising the reaction product and an oxidizer. A method of reducing a burn rate of a solid propellant is also disclosed.

A high performance composite pyrotechnic product without lead in its composition, and that can be obtained on an industrial scale without encountering a problem of potlife for the intermediate paste, the product containing organic energetic charges and a combustion catalyst in a plasticized binder including a cured energetic polymer and at least one energetic plasticizer. In characteristic manner, the cured energetic polymer consists of a glycidyle azide polymer (GAP) having number average molecular weight (Mn) lying in the range 700 g/mol to 3000 g/mol, cured via its hydroxyl terminal functions with at least one curing agent of polyisocyanate type; and the combustion catalyst consists of bismuth citrate.

The present application generally relates to compositions with solid fuel loaded on graphene foams (GFs) for enhanced burn rates, and methods of making and using the compositions with solid fuel loaded on graphene foam.

The invention relates generally to burn rate modifiers, plasticizers and propellants comprising a burn rate modifier and/or a plasticizer. The invention also relates to methods of producing a propellant comprising a burn rate modifier and/or a plasticizer as well as an ammunition cartridge comprising the propellant. The burn rate modifier and/or plasticiser comprises a compound of formula (1) (Formula (1)) and the propellant comprises a compound of formula 1 and an energetic material. ##STR00001##