Solid-fuel rocket propellants comprising an oxidizer, an oxophilic metal-halophilic metal formulation, and a binder are described herein. Further described are processes for preparing such propellants and methods of reducing hydrogen chloride production via the combustion of such propellants. Non-limiting examples of such formulations include aluminum-lithium alloys.

Provided are devices for generating a desired gas or mixture of gases by thermally decomposing a gas-generating composition (e.g. a metal hydride or polymer) using the thermal energy generated by reaction of a heat-generating composition (e.g. a thermite mixture), and methods of making and using such devices. The devices include phase-changing separators, i.e. separators that at least partially melt, vaporize, or sublimate as a result of the thermal energy generated by the heat-generating composition.

Provided are devices for generating a desired gas or mixture of gases by thermally decomposing a gas-generating composition (e.g. a metal hydride or polymer) using the thermal energy generated by reaction of a heat-generating composition (e.g. a thermite mixture), and methods of making and using such devices. The devices include phase-changing separators, i.e. separators that at least partially melt, vaporize, or sublimate as a result of the thermal energy generated by the heat-generating composition.

Cool burning gas generant compositions for an automotive inflatable restraint system are provided that include a bismuth-containing compound selected from the group consisting of: bismuth citrate, bismuth subsalicylate, bismuth hydroxide, copper bismuth hydroxy nitrate, bismuth subcarbonate, bismuth suboxalate, and combinations thereof. The gas generant comprises at least one copper-containing component. The gas generant includes at least one oxidizer, fuel, and optional coolant. The maximum flame temperature at combustion (T.sub.c) of less than or equal to about 1700K (1,427° C.). The cool burning gas generant composition generates liquid phase combustion products making it suitable for use in a filterless inflatable restraint system. Copper and bismuth present in the cool burning gas generant composition react to form an alloy having a melting point at or near the maximum flame temperature at combustion (T.sub.c).

Cool burning gas generant compositions for an automotive inflatable restraint system are provided that include a bismuth-containing compound selected from the group consisting of: bismuth citrate, bismuth subsalicylate, bismuth hydroxide, copper bismuth hydroxy nitrate, bismuth subcarbonate, bismuth suboxalate, and combinations thereof. The gas generant comprises at least one copper-containing component. The gas generant includes at least one oxidizer, fuel, and optional coolant. The maximum flame temperature at combustion (T.sub.c) of less than or equal to about 1700K (1,427° C.). The cool burning gas generant composition generates liquid phase combustion products making it suitable for use in a filterless inflatable restraint system. Copper and bismuth present in the cool burning gas generant composition react to form an alloy having a melting point at or near the maximum flame temperature at combustion (T.sub.c).

Provided is a gas-generating agent composition containing the components (a) to (d) below, in which a content of the following (d) calcium carbonate is 5 mass % or less: (a) guanidine nitrate; (b) a basic metal nitrate; (c) a binder; and (d) calcium carbonate.

A method of treating a subterranean formation by contacting the formation with the following: (a) an ammonium compound; (b) an oxidizing agent selected from a perchlorate or a nitrite or combinations thereof; and (c) one or more acids, at least one of which is a bisulfate salt.

A method of treating a subterranean formation by contacting the formation with the following: (a) ammonium compound; (b) an oxidizing agent selected from a perchlorate or a nitrite or combinations thereof; and (c) sulfamic acid.

Gas generating devices and methods of manufacturing and using such gas generating devices are described herein. A gas generator device may be manufactured to include a heat-generating composition that is substantially dimensionally stable during and after a gas generation reaction. The heat-generating composition may comprise one or more binding agents, a structural, physical support, or both. The gas generator device additionally includes a gas generating composition, and in some implementations, may include at least one protective layer. In some embodiments, at least a portion of the at least one protective layer is configured to undergo thermal decomposition or disintegration, using heat generated by a reaction of the heat-generating composition to allow the heat-generating and gas-generating composition to come into contact.

Gas generating devices and methods of manufacturing and using such gas generating devices are described herein. A gas generator device may be manufactured to include a heat-generating composition that is substantially dimensionally stable during and after a gas generation reaction. The heat-generating composition may comprise one or more binding agents, a structural, physical support, or both. The gas generator device additionally includes a gas generating composition, and in some implementations, may include at least one protective layer. In some embodiments, at least a portion of the at least one protective layer is configured to undergo thermal decomposition or disintegration, using heat generated by a reaction of the heat-generating composition to allow the heat-generating and gas-generating composition to come into contact.