Patent classifications
C07C1/20
FLUIDIZED BED REACTOR, DEVICE AND METHOD FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND
A fluidized bed reactor, a device, and a method for producing low-carbon olefins from oxygen-containing compound are provided. The fluidized bed reactor includes a reactor shell, a reaction zone, a coke control zone and a delivery pipe, where there are n baffles arranged in the coke control zone, and the n baffles divide the coke control zone into n sub-coke control zones which include a first sub-coke control zone, a second sub-coke control zone, and an nth sub-coke control zone; at least one catalyst circulation hole is provided on each of the n-1 baffles, so that the catalyst flows in an annular shape in the coke control zone, where n is an integer. The device and method can be adapted to a new generation of DMTO catalyst, and the unit consumption of production ranges from 2.50 to 2.58 tons of methanol/ton of low-carbon olefins.
FLUIDIZED BED REACTOR, DEVICE AND METHOD FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND
A fluidized bed reactor, a device, and a method for producing low-carbon olefins from oxygen-containing compound are provided. The fluidized bed reactor includes a reactor shell, a reaction zone, a coke control zone and a delivery pipe, where there are n baffles arranged in the coke control zone, and the n baffles divide the coke control zone into n sub-coke control zones which include a first sub-coke control zone, a second sub-coke control zone, and an nth sub-coke control zone; at least one catalyst circulation hole is provided on each of the n-1 baffles, so that the catalyst flows in an annular shape in the coke control zone, where n is an integer. The device and method can be adapted to a new generation of DMTO catalyst, and the unit consumption of production ranges from 2.50 to 2.58 tons of methanol/ton of low-carbon olefins.
FLUIDIZED BED REACTOR, DEVICE, AND USE THEREOF
A fluidized bed reactor includes a main shell and a coke control zone shell; the main shell includes an upper shell and a lower shell; the upper shell encloses a gas-solid separation zone, and the lower shell encloses a reaction zone; the reaction zone axially communicates with the gas-solid separation zone; the coke control zone shell is circumferentially arranged on an outer wall of the main shell; the coke control zone shell and the main shell enclose an annular cavity, and the annular cavity is a coke control zone; n baffles are radially arranged in the coke control zone, and the n baffles divide the coke control zone into n coke control zone subzones, where n is an integer; the coke control zone subzones are provided with a coke control raw material inlet; and a catalyst circulation hole is formed in each of n-1 of the baffles.
FLUIDIZED BED REACTOR, DEVICE, AND USE THEREOF
A fluidized bed reactor includes a main shell and a coke control zone shell; the main shell includes an upper shell and a lower shell; the upper shell encloses a gas-solid separation zone, and the lower shell encloses a reaction zone; the reaction zone axially communicates with the gas-solid separation zone; the coke control zone shell is circumferentially arranged on an outer wall of the main shell; the coke control zone shell and the main shell enclose an annular cavity, and the annular cavity is a coke control zone; n baffles are radially arranged in the coke control zone, and the n baffles divide the coke control zone into n coke control zone subzones, where n is an integer; the coke control zone subzones are provided with a coke control raw material inlet; and a catalyst circulation hole is formed in each of n-1 of the baffles.
COKE CONTROL REACTOR, AND DEVICE AND METHOD FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND
A coke control reactor, and a device and method for preparing low-carbon olefins from an oxygen-containing compound are provided. The coke control reactor includes a coke control reactor shell, a reaction zone I, and a coke controlled catalyst settling zone; a cross-sectional area at any position of the reaction zone I is less than that of the coke controlled catalyst settling zone; n baffles are arranged in a vertical direction in the reaction zone I; the n baffles divide the reaction zone I into m reaction zone I subzones; and a catalyst circulation hole is formed in each of the baffles, such that a catalyst flows in the reaction zone I in a preset manner. A catalyst charge in the present coke control reactor can be automatically adjusted, and an average residence time of a catalyst in the coke control reactor can be controlled by changing process operating conditions.
COKE CONTROL REACTOR, AND DEVICE AND METHOD FOR PREPARING LOW-CARBON OLEFINS FROM OXYGEN-CONTAINING COMPOUND
A coke control reactor, and a device and method for preparing low-carbon olefins from an oxygen-containing compound are provided. The coke control reactor includes a coke control reactor shell, a reaction zone I, and a coke controlled catalyst settling zone; a cross-sectional area at any position of the reaction zone I is less than that of the coke controlled catalyst settling zone; n baffles are arranged in a vertical direction in the reaction zone I; the n baffles divide the reaction zone I into m reaction zone I subzones; and a catalyst circulation hole is formed in each of the baffles, such that a catalyst flows in the reaction zone I in a preset manner. A catalyst charge in the present coke control reactor can be automatically adjusted, and an average residence time of a catalyst in the coke control reactor can be controlled by changing process operating conditions.
HIGH PURITY ISOAMYLENE PRODUCTION FROM TERTIARY AMYL METHYL ETHER DECOMPOSITION
Systems and methods for the production of a high purity isoamylene product. The isoamylene in a mixed hydrocarbon stream may initially be converted to TAME via etherification, and a subsequent decomposition of the TAME may result in a high purity isoamylene stream with very low impurities that is suitable for a variety of petrochemical applications, such as for use in the production of fragrances, pesticides, peroxides, polymer antioxidants, UV stabilizers and hydrocarbon resins.
HIGH PURITY ISOAMYLENE PRODUCTION FROM TERTIARY AMYL METHYL ETHER DECOMPOSITION
Systems and methods for the production of a high purity isoamylene product. The isoamylene in a mixed hydrocarbon stream may initially be converted to TAME via etherification, and a subsequent decomposition of the TAME may result in a high purity isoamylene stream with very low impurities that is suitable for a variety of petrochemical applications, such as for use in the production of fragrances, pesticides, peroxides, polymer antioxidants, UV stabilizers and hydrocarbon resins.
HIGH PURITY ISOAMYLENE PRODUCTION FROM TERTIARY AMYL METHYL ETHER DECOMPOSITION
Systems and methods for the production of a high purity isoamylene product. The isoamylene in a mixed hydrocarbon stream may initially be converted to TAME via etherification, and a subsequent decomposition of the TAME may result in a high purity isoamylene stream with very low impurities that is suitable for a variety of petrochemical applications, such as for use in the production of fragrances, pesticides, peroxides, polymer antioxidants, UV stabilizers and hydrocarbon resins.
Methods to produce zeolites with the GME topology and compositions derived therefrom
The present disclosure is directed to microporous crystalline aluminosilicate structures with GME topologies having pores containing organic structure directing agents (OSDAs) comprising at least one piperidinium cation, the compositions useful for making these structures, and methods of using these structures. In some embodiments, the crystalline zeolite structures have a molar ratio of Si:Al that is greater than 3.5.