Patent classifications
C07C1/20
METHOD FOR REGULATING THE GAS VELOCITY OF THE EMPTY BED IN A FLUIDIZED BED
The invention relates to a method for regulating the gas velocity of the empty bed in a fluidized bed, wherein solid catalysts are used as fluidized particles or as a part of fluidized particles, characterized in that the gas velocity of the empty bed μ of the reaction zone of the fluidized bed is measured, compared with the bed average catalyst density ρ of the solid catalysts in the reaction zone of the fluidized bed, the gas velocity of the empty bed μ being adjusted as required such that the gas velocity of the empty bed μ and the bed average catalyst density ρ satisfy the formula (I) below: ρ=0.356μ.sup.3−4.319μ.sup.2−35.57μ+M; wherein M=250−; where μ is provided in m/s and ρ is provided in kg/m.sup.3. The method can be used for the industrial production of lower olefin.
METHOD FOR REGULATING THE GAS VELOCITY OF THE EMPTY BED IN A FLUIDIZED BED
The invention relates to a method for regulating the gas velocity of the empty bed in a fluidized bed, wherein solid catalysts are used as fluidized particles or as a part of fluidized particles, characterized in that the gas velocity of the empty bed μ of the reaction zone of the fluidized bed is measured, compared with the bed average catalyst density ρ of the solid catalysts in the reaction zone of the fluidized bed, the gas velocity of the empty bed μ being adjusted as required such that the gas velocity of the empty bed μ and the bed average catalyst density ρ satisfy the formula (I) below: ρ=0.356μ.sup.3−4.319μ.sup.2−35.57μ+M; wherein M=250−; where μ is provided in m/s and ρ is provided in kg/m.sup.3. The method can be used for the industrial production of lower olefin.
Process for the production of renewable distillate-range hydrocarbons
A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.
Process for the production of renewable distillate-range hydrocarbons
A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.
PROCESSES AND APPARATUSES FOR PRODUCTION OF POLYPROPYLENE
Processes and apparatuses for the production of propylene are provided. In an embodiment, a process is provided for production of propylene from an oxygenate feed comprising passing the oxygenate feed to an oxygenate-to-olefin reactor to contact the oxygenate feed with a catalyst to provide an effluent stream comprising olefins comprising ethylene, propylene and butylene. The effluent stream is separated in a product separation zone to generate a propylene product stream, an ethylene stream and a C.sub.4+ stream. The ethylene stream is reacted in an ethylene dimerization or oligomerization reactor in presence of a dimerization or oligomerization catalyst to provide a first process stream. The C.sub.4+ stream and the first process stream are cracked in a cracking reactor under cracking conditions to provide a cracked stream comprising additional amounts of ethylene and propylene. Finally, the cracked stream is passed to the product separation zone to recover additional amounts of propylene.
PROCESSES AND APPARATUSES FOR PRODUCTION OF POLYPROPYLENE
Processes and apparatuses for the production of propylene are provided. In an embodiment, a process is provided for production of propylene from an oxygenate feed comprising passing the oxygenate feed to an oxygenate-to-olefin reactor to contact the oxygenate feed with a catalyst to provide an effluent stream comprising olefins comprising ethylene, propylene and butylene. The effluent stream is separated in a product separation zone to generate a propylene product stream, an ethylene stream and a C.sub.4+ stream. The ethylene stream is reacted in an ethylene dimerization or oligomerization reactor in presence of a dimerization or oligomerization catalyst to provide a first process stream. The C.sub.4+ stream and the first process stream are cracked in a cracking reactor under cracking conditions to provide a cracked stream comprising additional amounts of ethylene and propylene. Finally, the cracked stream is passed to the product separation zone to recover additional amounts of propylene.
PROCESSES AND APPARATUSES FOR PRODUCTION OF POLYPROPYLENE
Processes and apparatuses for the production of propylene are provided. In an embodiment, a process is provided for production of propylene from an oxygenate feed comprising passing the oxygenate feed to an oxygenate-to-olefin reactor to contact the oxygenate feed with a catalyst to provide an effluent stream comprising olefins comprising ethylene, propylene and butylene. The effluent stream is separated in a product separation zone to generate a propylene product stream, an ethylene stream and a C.sub.4+ stream. The ethylene stream is reacted in an ethylene dimerization or oligomerization reactor in presence of a dimerization or oligomerization catalyst to provide a first process stream. The C.sub.4+ stream and the first process stream are cracked in a cracking reactor under cracking conditions to provide a cracked stream comprising additional amounts of ethylene and propylene. Finally, the cracked stream is passed to the product separation zone to recover additional amounts of propylene.
Structured catalyst for methanol reforming, methanol reforming device, method for producing structured catalyst for methanol reforming, and method for producing at least one of olefin or aromatic hydrocarbon
To provide a highly active structured catalyst for methanol reforming that suppresses the decline in catalytic function and has excellent catalytic function, and a methanol reforming device. A structured catalyst for methanol reforming, including: a support of a porous structure composed of a zeolite-type compound; and a catalytic substance present in the support, in which the support has channels communicating with each other, and the catalytic substance is present at least in the channels of the support.
PLANT AND PROCESS FOR PRODUCING PROPYLENE FROM METHANOL
The present invention relates to a plant and a process for producing propylene at least one oxygenate, comprising a reactor for converting the reactant mixture into a product mixture which comprises propylene and also aliphatic and aromatic C.sub.5+ hydrocarbons, at least one distillation column for removing a C.sub.5+ stream, the C.sub.5+ stream comprising at least 90 wt % of the aliphatic and aromatic C.sub.5+ hydrocarbons of the product mixture, an extractive distillation column for separating the C.sub.5+ stream into an aromatics stream and an aliphatics stream, the aliphatics stream comprising at least 90 wt % of the aliphatics of the C.sub.5+ stream, and the aromatics stream comprising at least 90 wt % of the aromatics of the C.sub.5+ stream, and an aliphatics recycle line for at least partial recycling of the aliphatics stream to the reactor. According to the invention, an aromatics recycle line is provided which returns the aromatics stream at least partially as extractant into the extractive distillation column.
PLANT AND PROCESS FOR PRODUCING PROPYLENE FROM METHANOL
The present invention relates to a plant and a process for producing propylene at least one oxygenate, comprising a reactor for converting the reactant mixture into a product mixture which comprises propylene and also aliphatic and aromatic C.sub.5+ hydrocarbons, at least one distillation column for removing a C.sub.5+ stream, the C.sub.5+ stream comprising at least 90 wt % of the aliphatic and aromatic C.sub.5+ hydrocarbons of the product mixture, an extractive distillation column for separating the C.sub.5+ stream into an aromatics stream and an aliphatics stream, the aliphatics stream comprising at least 90 wt % of the aliphatics of the C.sub.5+ stream, and the aromatics stream comprising at least 90 wt % of the aromatics of the C.sub.5+ stream, and an aliphatics recycle line for at least partial recycling of the aliphatics stream to the reactor. According to the invention, an aromatics recycle line is provided which returns the aromatics stream at least partially as extractant into the extractive distillation column.