A method for recycling CO.sub.2 from CO.sub.2 containing inputs to produce hydrocarbon products includes the steps of (i) capturing CO.sub.2 from at least one CO.sub.2 containing input, at least one of the at least one CO.sub.2 containing input including air; (ii) producing a CO.sub.2 feed stream from the captured CO.sub.2; (iii) reacting the CO.sub.2 feed stream with a H.sub.2 feed stream to produce a methane containing output; and (iv) separating the methane containing output so as to at least provide methane and a first waste output, wherein the first waste output is incinerated or gasified to provide one of the at least one CO.sub.2 containing inputs for step (i).

A method for recycling CO.sub.2 from CO.sub.2 containing inputs to produce hydrocarbon products includes the steps of (i) capturing CO.sub.2 from at least one CO.sub.2 containing input, at least one of the at least one CO.sub.2 containing input including air; (ii) producing a CO.sub.2 feed stream from the captured CO.sub.2; (iii) reacting the CO.sub.2 feed stream with a H.sub.2 feed stream to produce a methane containing output; and (iv) separating the methane containing output so as to at least provide methane and a first waste output, wherein the first waste output is incinerated or gasified to provide one of the at least one CO.sub.2 containing inputs for step (i).

A method for recycling CO.sub.2 from CO.sub.2 containing inputs to produce hydrocarbon products includes the steps of (i) capturing CO.sub.2 from at least one CO.sub.2 containing input, at least one of the at least one CO.sub.2 containing input including air; (ii) producing a CO.sub.2 feed stream from the captured CO.sub.2; (iii) reacting the CO.sub.2 feed stream with a H.sub.2 feed stream to produce a methane containing output; and (iv) separating the methane containing output so as to at least provide methane and a first waste output, wherein the first waste output is incinerated or gasified to provide one of the at least one CO.sub.2 containing inputs for step (i).

Process for the conversion of non-oxidative coupling of methane to ethylene, under non-oxidative conditions, comprising: providing a first stream containing at least 50 vol. % of methane based on the total volume of said first stream; providing a catalyst; putting in contact said first stream with said catalyst at a weight hour space velocity ranging from 0.5 to 100 h.sup.−1, a temperature ranging from 500° C. to 1100° C. and a pressure ranging from 0.1 MPa to 5 Mpa in the absence of oxygen; recovering a second stream containing unconverted methane if any, ethylene and hydrocarbons having at least 2 carbon atoms. Said process is remarkable in that said catalyst is a synthetic zeolite material, containing at least one metal M with silicon to metal M molar ratio Si/M as determined by inductively coupled plasma optical emission spectrometry ranging from 100 to 65440 and in that said metal M is incorporated inside of the zeolite tetrahedral sites.

Process for the conversion of non-oxidative coupling of methane to ethylene, under non-oxidative conditions, comprising: providing a first stream containing at least 50 vol. % of methane based on the total volume of said first stream; providing a catalyst; putting in contact said first stream with said catalyst at a weight hour space velocity ranging from 0.5 to 100 h.sup.−1, a temperature ranging from 500° C. to 1100° C. and a pressure ranging from 0.1 MPa to 5 Mpa in the absence of oxygen; recovering a second stream containing unconverted methane if any, ethylene and hydrocarbons having at least 2 carbon atoms. Said process is remarkable in that said catalyst is a synthetic zeolite material, containing at least one metal M with silicon to metal M molar ratio Si/M as determined by inductively coupled plasma optical emission spectrometry ranging from 100 to 65440 and in that said metal M is incorporated inside of the zeolite tetrahedral sites.

Process for the conversion of non-oxidative coupling of methane to ethylene, under non-oxidative conditions, comprising: providing a first stream containing at least 50 vol. % of methane based on the total volume of said first stream; providing a catalyst; putting in contact said first stream with said catalyst at a weight hour space velocity ranging from 0.5 to 100 h.sup.−1, a temperature ranging from 500° C. to 1100° C. and a pressure ranging from 0.1 MPa to 5 Mpa in the absence of oxygen; recovering a second stream containing unconverted methane if any, ethylene and hydrocarbons having at least 2 carbon atoms. Said process is remarkable in that said catalyst is a synthetic zeolite material, containing at least one metal M with silicon to metal M molar ratio Si/M as determined by inductively coupled plasma optical emission spectrometry ranging from 100 to 65440 and in that said metal M is incorporated inside of the zeolite tetrahedral sites.

The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.

The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.

Disclosed herein are processes for the production of hydrocarbon fuel products from C.sub.2-5 alkanes. Methane is converted to ethylene in a methane thermal olefination reactor operating at a temperature of at least 900° C. and a pressure of at least 150 psig, and without a dehydrogenation catalyst or steam. C.sub.2-5 alkanes are converted to olefins in a C.sub.2-5 thermal olefination reactor operating at a temperature, pressure and space velocity to convert at least 80% of the alkanes to C.sub.2-5 olefins. The ethylene and C.sub.2-5 olefins are passed through an oligomerization reactor containing a zeolite catalyst and operating at a temperature, pressure and space velocity to crack, oligomerize and cyclize the olefins. In one aspect, methane in the effluent of the oligomerization reactor is recycled through the C.sub.2-5 thermal olefination reactor. Methods for the thermal olefination of methane are also disclosed.

Disclosed herein are processes for the production of hydrocarbon fuel products from C.sub.2-5 alkanes. Methane is converted to ethylene in a methane thermal olefination reactor operating at a temperature of at least 900° C. and a pressure of at least 150 psig, and without a dehydrogenation catalyst or steam. C.sub.2-5 alkanes are converted to olefins in a C.sub.2-5 thermal olefination reactor operating at a temperature, pressure and space velocity to convert at least 80% of the alkanes to C.sub.2-5 olefins. The ethylene and C.sub.2-5 olefins are passed through an oligomerization reactor containing a zeolite catalyst and operating at a temperature, pressure and space velocity to crack, oligomerize and cyclize the olefins. In one aspect, methane in the effluent of the oligomerization reactor is recycled through the C.sub.2-5 thermal olefination reactor. Methods for the thermal olefination of methane are also disclosed.