C07C7/10

INTEGRATED PROCESS FOR MAXIMIZING PRODUCTION OF PARA-XYLENE FROM FULL REFORMATE
20200262768 · 2020-08-20 ·

A method of producing p-xylene, the method comprising the steps of converting the C9+ aromatic hydrocarbons and the hydrogen gas in the presence of a dealkylation catalyst to produce a dealkylation effluent, separating the dealkylation effluent to produce a carbon-nine (C9) aromatics stream, a xylene stream, and a toluene stream, separating the p-xylenes from the xylene stream in the p-xylene separation unit to produce a p-xylene product and a p-xylene depleted stream, converting the m-xylene and o-xylene in the p-xylene depleted stream in the isomerization unit to produce an isomerization effluent, reacting the C9 aromatics stream and the hydrogen stream in the presence of a transalkylation catalyst in the transalkylation reactor to produce a transalkylation effluent, separating the C6 to C9+ aromatic hydrocarbons in the isomerization effluent and the transalkylation effluent in the splitter column to produce a benzene recycle, a toluene recycle, a xylene recycle and a C9+ recycle.

Process and plant for producing olefins
20200231522 · 2020-07-23 ·

Proposed is a process (100) for producing ethylene in which ethane in a reaction input is partly catalytically converted by oxidative dehydrogenation (1) in the presence of oxygen to obtain a gaseous first component mixture containing at least ethane, ethylene, acetic acid and water. It is provided that at least a portion of the gaseous first component mixture is subjected to a scrubbing operation with a scrubbing liquid to obtain a liquid second component mixture containing water and acetic acid, that a first proportion of the second component mixture is used for forming the scrubbing liquid, that a second proportion of the second component mixture is subjected to a solvent extraction to obtain a liquid third component mixture containing at least one organic solvent and acetic acid and that at least a portion of the liquid third component mixture is heated and subjected to a distillation to obtain a liquid containing predominantly or exclusively acetic acid. The heating of the third component mixture or the portion thereof subjected to the distillation is performed at least partly in heat exchange with the first component mixture and/or with the first and/or with the second proportion of the second component mixture. A corresponding plant likewise forms part of the subject matter of the present invention.

Process and plant for producing olefins
20200231522 · 2020-07-23 ·

Proposed is a process (100) for producing ethylene in which ethane in a reaction input is partly catalytically converted by oxidative dehydrogenation (1) in the presence of oxygen to obtain a gaseous first component mixture containing at least ethane, ethylene, acetic acid and water. It is provided that at least a portion of the gaseous first component mixture is subjected to a scrubbing operation with a scrubbing liquid to obtain a liquid second component mixture containing water and acetic acid, that a first proportion of the second component mixture is used for forming the scrubbing liquid, that a second proportion of the second component mixture is subjected to a solvent extraction to obtain a liquid third component mixture containing at least one organic solvent and acetic acid and that at least a portion of the liquid third component mixture is heated and subjected to a distillation to obtain a liquid containing predominantly or exclusively acetic acid. The heating of the third component mixture or the portion thereof subjected to the distillation is performed at least partly in heat exchange with the first component mixture and/or with the first and/or with the second proportion of the second component mixture. A corresponding plant likewise forms part of the subject matter of the present invention.

Waste stream upgrading in a propylene oxide/styrene coproduction process

A method including contacting an organic stream with water and carbon dioxide, whereby sodium is extracted from the organic stream, and separating an aqueous sodium salt-containing phase from an organic phase comprising a reduced sodium content. The organic stream can be a heavy residue formed in the co-production of propylene oxide and styrene. Contacting can include combining the carbon dioxide with the water to form a CO.sub.2-saturated water stream and contacting the CO.sub.2-saturated water stream with the organic stream, and/or combining the organic stream and the water to form a mixture and injecting the carbon dioxide as a gas thereinto. The method can further include repeating the contacting and the separating one or more times on the organic phase, subjecting the organic phase to ion exchange, or both, to obtain an organic phase having a further reduced sodium content. A system for carrying out the method is also provided.

Waste stream upgrading in a propylene oxide/styrene coproduction process

A method including contacting an organic stream with water and carbon dioxide, whereby sodium is extracted from the organic stream, and separating an aqueous sodium salt-containing phase from an organic phase comprising a reduced sodium content. The organic stream can be a heavy residue formed in the co-production of propylene oxide and styrene. Contacting can include combining the carbon dioxide with the water to form a CO.sub.2-saturated water stream and contacting the CO.sub.2-saturated water stream with the organic stream, and/or combining the organic stream and the water to form a mixture and injecting the carbon dioxide as a gas thereinto. The method can further include repeating the contacting and the separating one or more times on the organic phase, subjecting the organic phase to ion exchange, or both, to obtain an organic phase having a further reduced sodium content. A system for carrying out the method is also provided.

Waste stream upgrading in a propylene oxide/styrene coproduction process

A method including contacting an organic stream with water and carbon dioxide, whereby sodium is extracted from the organic stream, and separating an aqueous sodium salt-containing phase from an organic phase comprising a reduced sodium content. The organic stream can be a heavy residue formed in the co-production of propylene oxide and styrene. Contacting can include combining the carbon dioxide with the water to form a CO.sub.2-saturated water stream and contacting the CO.sub.2-saturated water stream with the organic stream, and/or combining the organic stream and the water to form a mixture and injecting the carbon dioxide as a gas thereinto. The method can further include repeating the contacting and the separating one or more times on the organic phase, subjecting the organic phase to ion exchange, or both, to obtain an organic phase having a further reduced sodium content. A system for carrying out the method is also provided.

Integrated process for maximizing production of para-xylene from full reformate
10696609 · 2020-06-30 · ·

A method of producing p-xylene, the method comprising the steps of converting the C9+ aromatic hydrocarbons and the hydrogen gas in the presence of a dealkylation catalyst to produce a dealkylation effluent, separating the dealkylation effluent to produce a carbon-nine (C9) aromatics stream, a xylene stream, and a toluene stream, separating the p-xylenes from the xylene stream in the p-xylene separation unit to produce a p-xylene product and a p-xylene depleted stream, converting the m-xylene and o-xylene in the p-xylene depleted stream in the isomerization unit to produce an isomerization effluent, reacting the C9 aromatics stream and the hydrogen stream in the presence of a transalkylation catalyst in the transalkylation reactor to produce a transalkylation effluent, separating the C6 to C9+ aromatic hydrocarbons in the isomerization effluent and the transalkylation effluent in the splitter column to produce a benzene recycle, a toluene recycle, a xylene recycle and a C9+ recycle.

Integrated process for maximizing production of para-xylene from full reformate
10696609 · 2020-06-30 · ·

A method of producing p-xylene, the method comprising the steps of converting the C9+ aromatic hydrocarbons and the hydrogen gas in the presence of a dealkylation catalyst to produce a dealkylation effluent, separating the dealkylation effluent to produce a carbon-nine (C9) aromatics stream, a xylene stream, and a toluene stream, separating the p-xylenes from the xylene stream in the p-xylene separation unit to produce a p-xylene product and a p-xylene depleted stream, converting the m-xylene and o-xylene in the p-xylene depleted stream in the isomerization unit to produce an isomerization effluent, reacting the C9 aromatics stream and the hydrogen stream in the presence of a transalkylation catalyst in the transalkylation reactor to produce a transalkylation effluent, separating the C6 to C9+ aromatic hydrocarbons in the isomerization effluent and the transalkylation effluent in the splitter column to produce a benzene recycle, a toluene recycle, a xylene recycle and a C9+ recycle.

OXIDIZED DISULFIDE OIL SOLVENT COMPOSITIONS

Oxidized disulfide oil (ODSO) solvent compositions are derived from by-product disulfide oil (DSO) compounds produced as by-products from the generalized mercaptan oxidation (MEROX) processing of a refinery feedstock. The oxidized disulfide oil (ODSO) solvent compositions comprise at least a primary oxidized disulfide oil (ODSO) compound selected from either water soluble or water insoluble oxidized disulfide oil (ODSO) compounds and in some embodiments at least 0.1 ppmw of a secondary oxidized disulfide oil (ODSO) compound that is a water soluble oxidized disulfide oil (ODSO) compound.

Flowable microbial oil

Provided herein is a method for obtaining flowable oil comprising the steps of providing a population of oil-producing microorganisms; recovering oil from the microorganisms, wherein the oil is at a first temperature; reducing the first temperature over a first period of time to a second temperature; and applying mechanical energy to the oil during the first period of time thereby producing the flowable oil.