C07C7/11

METHOD FOR PROCESSING A GASEOUS COMPOSITION

A process can treat a gaseous material mixture obtained by catalytic conversion of synthesis gas that contains at least alkenes, possibly alcohols and possibly alkanes, and also possibly nitrogen as inert gas and unconverted components of the synthesis gas, comprising hydrogen, carbon monoxide and/or carbon dioxide. After catalytic conversion of synthesis gas, separation of the product mixture obtained in this reaction into a gas phase and a liquid phase is performed by at least partial absorption of the alkenes, possibly of the alcohols and possibly of the alkanes, in a high boiling point hydrocarbon or hydrocarbon mixture as an absorption medium, separation as the gas phase of the gases not absorbed into the absorption medium, separating an aqueous phase from the organic phase of the absorption medium, preferably by decanting, and desorption of the alkenes, possibly of the alcohols and possibly of the alkanes, from the absorption medium.

METHOD FOR PROCESSING A GASEOUS COMPOSITION

A process can treat a gaseous material mixture obtained by catalytic conversion of synthesis gas that contains at least alkenes, possibly alcohols and possibly alkanes, and also possibly nitrogen as inert gas and unconverted components of the synthesis gas, comprising hydrogen, carbon monoxide and/or carbon dioxide. After catalytic conversion of synthesis gas, separation of the product mixture obtained in this reaction into a gas phase and a liquid phase is performed by at least partial absorption of the alkenes, possibly of the alcohols and possibly of the alkanes, in a high boiling point hydrocarbon or hydrocarbon mixture as an absorption medium, separation as the gas phase of the gases not absorbed into the absorption medium, separating an aqueous phase from the organic phase of the absorption medium, preferably by decanting, and desorption of the alkenes, possibly of the alcohols and possibly of the alkanes, from the absorption medium.

METHOD FOR PROCESSING A GASEOUS COMPOSITION

A process can treat a gaseous material mixture obtained by catalytic conversion of synthesis gas that contains at least alkenes, possibly alcohols and possibly alkanes, and also possibly nitrogen as inert gas and unconverted components of the synthesis gas, comprising hydrogen, carbon monoxide and/or carbon dioxide. After catalytic conversion of synthesis gas, separation of the product mixture obtained in this reaction into a gas phase and a liquid phase is performed by at least partial absorption of the alkenes, possibly of the alcohols and possibly of the alkanes, in a high boiling point hydrocarbon or hydrocarbon mixture as an absorption medium, separation as the gas phase of the gases not absorbed into the absorption medium, separating an aqueous phase from the organic phase of the absorption medium, preferably by decanting, and desorption of the alkenes, possibly of the alcohols and possibly of the alkanes, from the absorption medium.

PROCESS OF PREPARING ALCOHOLS

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

PROCESS OF PREPARING ALCOHOLS

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

PROCESS OF PREPARING ALCOHOLS

A process can produce alcohols having at least two carbon atoms by catalytic conversion of synthesis gas into a mixture containing alkanes, alkenes, and alcohols. Alkenes are converted into corresponding alcohols in a subsequent step by hydration of the alkanes. Before the hydration and after the catalytic conversion, gas and liquid phases may be separated. Specific catalysts can be employed that have a markedly higher selectivity for alkenes than for alkanes. These catalysts comprise grains of non-graphitic carbon having cobalt nanoparticles dispersed therein. The cobalt nanoparticles have an average diameter d.sub.p from 1 to 20 nm, and an average distance D between nanoparticles is from 2 to 150 nm. The combined total mass fraction of metal ω in the grains ranges from 30% to 70% by weight of the total mass of the grains of non-graphitic carbon, wherein 4.5 dp/ω>D≥0.25 dp/ω.

Method of producing olefin using circulating fluidized bed process

Disclosed is a method of producing an olefin using a circulating fluidized bed process, including: (a) supplying a hydrocarbon mixture including propane and a dehydrogenation catalyst to a riser which is in a state of a fast fluidization regime, and thus inducing a dehydrogenation reaction; (b) separating an effluent from the dehydrogenation reaction into the catalyst and a propylene mixture; (c) stripping, in which a residual hydrocarbon compound is removed from the catalyst separated in step (b); (d) mixing the catalyst stripped in step (c) with a gas containing oxygen and thus continuously regenerating the catalyst; (e) circulating the catalyst regenerated in step (d) to step (a) and thus resupplying the catalyst to the riser; and (f) cooling, compressing, and separating the propylene mixture, which is a reaction product separated in step (b), and thus producing a propylene product.

Method of producing olefin using circulating fluidized bed process

Disclosed is a method of producing an olefin using a circulating fluidized bed process, including: (a) supplying a hydrocarbon mixture including propane and a dehydrogenation catalyst to a riser which is in a state of a fast fluidization regime, and thus inducing a dehydrogenation reaction; (b) separating an effluent from the dehydrogenation reaction into the catalyst and a propylene mixture; (c) stripping, in which a residual hydrocarbon compound is removed from the catalyst separated in step (b); (d) mixing the catalyst stripped in step (c) with a gas containing oxygen and thus continuously regenerating the catalyst; (e) circulating the catalyst regenerated in step (d) to step (a) and thus resupplying the catalyst to the riser; and (f) cooling, compressing, and separating the propylene mixture, which is a reaction product separated in step (b), and thus producing a propylene product.

METHOD FOR PRODUCING 1,3-BUTADIENE

The present invention has as its object the provision of a method for producing 1,3-butadiene capable of efficiently purifying an absorption solvent while a high productivity is assured.

A method for producing 1,3-butadiene includes: a step (A) of obtaining a produced gas containing 1,3-butadiene; a step (B) of cooling the produced gas; a step (C) of separating the produced gas, which has been subjected to the step (B); a step (D1) of separating the absorption solvent, that has absorbed an absorption component comprising the other gases containing 1,3 -butadiene into an absorption solvent that does not substantially contain the absorption component and an absorption solvent that contains the absorption component; a step (D2) of separating the absorption solvent that contains the absorption component into an absorption solvent that contains a reaction by-product and a 1,3-butadiene liquid; and a step (E) of purifying the absorption solvent, that contains the reaction by-product.

METHOD FOR PRODUCING 1,3-BUTADIENE

The present invention has as its object the provision of a method for producing 1,3-butadiene capable of efficiently purifying an absorption solvent while a high productivity is assured.

A method for producing 1,3-butadiene includes: a step (A) of obtaining a produced gas containing 1,3-butadiene; a step (B) of cooling the produced gas; a step (C) of separating the produced gas, which has been subjected to the step (B); a step (D1) of separating the absorption solvent, that has absorbed an absorption component comprising the other gases containing 1,3 -butadiene into an absorption solvent that does not substantially contain the absorption component and an absorption solvent that contains the absorption component; a step (D2) of separating the absorption solvent that contains the absorption component into an absorption solvent that contains a reaction by-product and a 1,3-butadiene liquid; and a step (E) of purifying the absorption solvent, that contains the reaction by-product.